Advanced Search

Home

Citation: Peng Lichong, Li Suqin. Preparation of Na-X Zeolite from Chlorite[J]. Chemistry, ;2018, 81(8): 713-719. shu

Preparation of Na-X Zeolite from Chlorite

Peng Lichong ,
Li Suqin ^,

School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing, Beijing 100083

Corresponding author: Li Suqin, lisuqin@metall.ustb.edu.cn
Received Date: 12 January 2018
Accepted Date: 16 April 2018

Figures(16)

The chemical components of chlorite are mainly SiO₂、Fe₂O₃ and Al₂O₃, which are the main materials to prepare zeolite. Because of the higher Fe and Mg content of chlorite, in order to reduce the influence of impurities on the synthesis of zeolite, chlorite were activated with Na₂CO₃ by calcination, then silicon and aluminum ions in activated chlorite were leached by water and alkaline solution. ICP detection results showed that silicon and aluminum extraction rates of chlorite after pretreatment with Na₂CO₃ reach 71% and 67%, respectively. In addition, SEM, XRD, and FTIR analyses showed that the self-prepared Na-X zeolite has high purity, complete crystal form, good thermal stability, and uniform particle size (about 1~2μm). The as-prepared Na-X zeolite is a microporous adsorbent with average pore size range of 0.4~0.8 nm. In addition, the prepared Na-X zeolite meets the requirements of the Chinese chemical industry (HG/T2690-95) (water absorption rate is greater than 23%).
- Chlorite tailings,
- Na-X zeolite,
- Pre-treated,
- Hydrothermal synthesis
1. [1]
2. [2]
  J S Sun, Y M Dou, Z X Chen et al. Experimental Study on the Performances of Cement Stabilized Iron Ore Tailing Gravel in Highway Application//Applied Mechanics and Materials. Trans Tech Publications, 2011, 97:425~428.
3. [3]
  Y Cao, W Z Yin, S Dong. Powder Technol. Appl. V, 2013, 826:253~259.
4. [4]
  Y M Nie, M H Xia, J X Zhang et al. Experimental Study of Mineral Polymer Made from Iron Tailing//Advanced Materials Research. Trans Tech Publications, 2011, 168:730~733.
5. [5]
6. [6]
  Y H Fang, Y M Cu, Q B Kang et al. Constr. Build. Mater., 2011, 25(2):867~872.
7. [7]
  S Chandrasekhar, P N Pramada. Porous Mater., 1999, 6:283~297.
8. [8]
9. [9]
  J F M Denayer, A R Ocakoglu, J A Martenset al. J. Catal., 2004, 226(1):240~244.
10. [10]
11. [11]
  X Querol, J C Umana, F Plana et al. Fuel, 2001, 80(6):857~865.
12. [12]
  A Arafat, J C Jansen, A R Ebaid et al. Zeolites, 1993, 13(3):162~165.
13. [13]
  U D Joshi, P N Joshi, S S Tamhankar et al. Therm. Chim. Acta, 2002, 387(2):121~130.
14. [14]
  D Chen, X Hu, L Shi et al. Appl. Clay Sci., 2012, 59:148~151.
1. [1]
  Han ZHANG , Jianfeng SUN , Jinsheng LIANG . Hydrothermal synthesis and luminescent properties of broadband near-infrared Na₃CrF₆ phosphor. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 349-356. doi: 10.11862/CJIC.20240098
2. [2]
  Zhengzheng LIU , Pengyun ZHANG , Chengri WANG , Shengli HUANG , Guoyu YANG . Synthesis, structure, and electrochemical properties of a sandwich-type {Co₆}-cluster-added germanotungstate. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1173-1179. doi: 10.11862/CJIC.20240039
3. [3]
  Juan CHEN , Guoyu YANG . A porous-layered aluminoborate built by mixed oxoboron clusters and AlO₄ tetrahedra. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 193-200. doi: 10.11862/CJIC.20240341
4. [4]
  Yuhao SUN , Qingzhe DONG , Lei ZHAO , Xiaodan JIANG , Hailing GUO , Xianglong MENG , Yongmei GUO . Synthesis and antibacterial properties of silver-loaded sod-based zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 761-770. doi: 10.11862/CJIC.20230169
5. [5]
  Yufang GAO , Nan HOU , Yaning LIANG , Ning LI , Yanting ZHANG , Zelong LI , Xiaofeng LI . Nano-thin layer MCM-22 zeolite: Synthesis and catalytic properties of trimethylbenzene isomerization reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1079-1087. doi: 10.11862/CJIC.20240036
6. [6]
  Jiali CHEN , Guoxiang ZHAO , Yayu YAN , Wanting XIA , Qiaohong LI , Jian ZHANG . Machine learning exploring the adsorption of electronic gases on zeolite molecular sieves. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 155-164. doi: 10.11862/CJIC.20240408
7. [7]
  Yiping HUANG , Liqin TANG , Yufan JI , Cheng CHEN , Shuangtao LI , Jingjing HUANG , Xuechao GAO , Xuehong GU . Hollow fiber NaA zeolite membrane for deep dehydration of ethanol solvent by vapor permeation. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 225-234. doi: 10.11862/CJIC.20240224
8. [8]
  Pei Li , Yuenan Zheng , Zhankai Liu , An-Hui Lu . Boron-Containing MFI Zeolite: Microstructure Control and Its Performance of Propane Oxidative Dehydrogenation. Acta Physico-Chimica Sinica, 2025, 41(4): 2406012-0. doi: 10.3866/PKU.WHXB202406012
9. [9]
  Yue Zhang , Bao Li , Lixin Wu . GO-Assisted Supramolecular Framework Membrane for High-Performance Separation of Nanosized Oil-in-Water Emulsions. Acta Physico-Chimica Sinica, 2024, 40(5): 2305038-0. doi: 10.3866/PKU.WHXB202305038
10. [10]
  Shanghua Li , Malin Li , Xiwen Chi , Xin Yin , Zhaodi Luo , Jihong Yu . High-Stable Aqueous Zinc Metal Anodes Enabled by an Oriented ZnQ Zeolite Protective Layer with Facile Ion Migration Kinetics. Acta Physico-Chimica Sinica, 2025, 41(1): 100003-0. doi: 10.3866/PKU.WHXB202309003
11. [11]
  Jing Wang , Pingping Li , Yuehui Wang , Yifan Xiu , Bingqian Zhang , Shuwen Wang , Hongtao Gao . Treatment and Discharge Evaluation of Phosphorus-Containing Wastewater. University Chemistry, 2024, 39(5): 52-62. doi: 10.3866/PKU.DXHX202309097
12. [12]
  Shule Liu . Application of SPC/E Water Model in Molecular Dynamics Teaching Experiments. University Chemistry, 2024, 39(4): 338-342. doi: 10.3866/PKU.DXHX202310029
13. [13]
  Zhaohu Li , Weidong Wang , Yuhao Liu , Mingzhe Han , Lingling Wei , Huan Jiao . Research on the Safety Management and Disposal of Chemical Laboratory Waste. University Chemistry, 2024, 39(10): 128-136. doi: 10.3866/PKU.DXHX202312090
14. [14]
  Xi YANG , Chunxiang CHANG , Yingpeng XIE , Yang LI , Yuhui CHEN , Borao WANG , Ludong YI , Zhonghao HAN . Co-catalyst Ni₃N supported Al-doped SrTiO₃: Synthesis and application to hydrogen evolution from photocatalytic water splitting. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 440-452. doi: 10.11862/CJIC.20240371
15. [15]
  Lisen Sun , Yongmei Hao , Zhen Huang , Yongmei Liu . Experimental Teaching Design for Viscosity Measurement Serves the Optimization of Operating Conditions for Kitchen Waste Treatment Equipment. University Chemistry, 2024, 39(2): 52-56. doi: 10.3866/PKU.DXHX202307063
16. [16]
  Kun Xu , Xinxin Song , Zhilei Yin , Jian Yang , Qisheng Song . Comprehensive Experimental Design of Preferential Orientation of Zinc Metal by Heat Treatment for Enhanced Electrochemical Performance. University Chemistry, 2024, 39(4): 192-197. doi: 10.3866/PKU.DXHX202309050
17. [17]
  Yuena Yang , Xufang Hu , Yushan Liu , Yaya Kuang , Jian Ling , Qiue Cao , Chuanhua Zhou . The Realm of Smart Hydrogels. University Chemistry, 2024, 39(5): 172-183. doi: 10.3866/PKU.DXHX202310125
18. [18]
  Hongyun Liu , Jiarun Li , Xinyi Li , Zhe Liu , Jiaxuan Li , Cong Xiao . Course Ideological and Political Design of a Comprehensive Chemistry Experiment: Constructing a Visual Molecular Logic System Based on Intelligent Hydrogel Film Electrodes. University Chemistry, 2024, 39(2): 227-233. doi: 10.3866/PKU.DXHX202309070
19. [19]
  Yaping Li , Sai An , Aiqing Cao , Shilong Li , Ming Lei . The Application of Molecular Simulation Software in Structural Chemistry Education: First-Principles Calculation of NiFe Layered Double Hydroxide. University Chemistry, 2025, 40(3): 160-170. doi: 10.12461/PKU.DXHX202405185
20. [20]
  Chunai Dai , Yongsheng Han , Luting Yan , Zhen Li , Yingze Cao . Preparation of Superhydrophobic Surfaces and Their Application in Oily Wastewater Treatment: Design of a Comprehensive Physical Chemistry Innovation Experiment. University Chemistry, 2024, 39(2): 34-40. doi: 10.3866/PKU.DXHX202307081