Citation: Li Xin WANG, Ming Hua XU, Yao Zeng SHI, Hong Wen HU. ULTRASONICALLY DISPERSED POTASSIUM AS DEPROTONATING AND COUPLING AGENT——SYNTHESIS OF 1,6-DINITRILES IN SITU[J]. Chinese Chemical Letters, ;1996, 7(8): 709-712. shu

ULTRASONICALLY DISPERSED POTASSIUM AS DEPROTONATING AND COUPLING AGENT——SYNTHESIS OF 1,6-DINITRILES IN SITU

Department of Chemistry, Nanjing University, Nanjing 210093

Received Date: 15 March 1996

Fund Project: This project was financed by the National Natural Science Foundation of China and the Ph.D Student Training Fund of the State Educational Comission of China.

Ultrasonically dispersed potassium (UDP) in toluene was found to be an effective deprotonating and coupling agent in the condensation of phenylacetonitrile with aldehydes;α, β-Unsaturated nitriles and their dimers 1, 6-dinitriles may be obtained by one-pot synthesis within few minutes.
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