Citation: ZHANG Qing-ling, GUO He-qin, HOU Bo, WANG Jun-gang, LI De-bao, JIA Li-tao. Effects of Mn and Zr promoters on the performance of ordered mesoporous carbon supported Co catalyst in Fischer-Tropsch synthesis[J]. Journal of Fuel Chemistry and Technology, ;2017, 45(6): 682-688. shu

Effects of Mn and Zr promoters on the performance of ordered mesoporous carbon supported Co catalyst in Fischer-Tropsch synthesis

ZHANG Qing-ling ^1,2 ,
GUO He-qin ¹ ,
HOU Bo ¹ ,
WANG Jun-gang ¹ ,
LI De-bao ¹ ,
JIA Li-tao ^1,*,,

1.
State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China
2.
University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: JIA Li-tao, jialitao910@163.com
Received Date: 3 March 2017
Revised Date: 20 April 2017

Fund Project: the ShanXi Provincial Research Foundation for Basic Research 2014021014-6the "Strategic Priority Research Program"Demonstration of Key Technologies for Clean and Efficient Utilization of Low-rank Coal XDA07070700the Coal Base Key Technologies R & D Program of ShanXi Province MH2014-13the National Natural Science Foundation of China 21503252the National Natural Science Foundation of China 21273265the ShanXi Provincial Research Foundation for Basic Research 201601D021044

Figures(5)

Cobalt-based catalysts supported on ordered mesoporous carbon (Co/OMC) were modified with Mn and Zr promoters by the co-impregnation method. The cobalt-based catalysts were characterized by XRD, N₂ sorption, H₂-TPR, H₂/CO-TPD and XPS; the promoting effects of Mn and Zr on the catalytic performance of Co/OMC in Fischer-Tropsch synthesis (FTS) were investigated in a fixed-bed reactor. The results indicate that the addition of either Mn or Zr can greatly reduce the selectivity to CH₄ for FTS over Co/OMC. Moreover, Mn as a promoter can enhance the selectivity to C_2-4 hydrocarbons and the olefin/paraffin ratio, whereas Zr promotes the dispersion of cobalt species and increases the number of active Co sites, leading to a significant increase in the FTS activity and selectivity to C₅₊ hydrocarbons.
- Fischer-Tropsch synthesis,
- cobalt-based catalyst,
- mesoporous carbon,
- Mn promoter,
- Zr promoter
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