Citation: Liang Chuxin, Liu Zheng, Han Jiaxing, Guo Chenyu, Zhang Shufen. Syntheses, Characterizations and Properties of Metal-Organic Frameworks Based on Heterocyclic Carboxylate Ligands[J]. Chemistry, ;2018, 81(11): 1006-1014. shu

Syntheses, Characterizations and Properties of Metal-Organic Frameworks Based on Heterocyclic Carboxylate Ligands

1.
College of Chemical and Biological Engineering, Guilin University of Technology, Guangxi Key Laboratory of Electrochemical and Magneto-chemical Functional Materials, Guilin 541004
2.
Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116024

Corresponding author: Liu Zheng, lisa4.6@163.com
Received Date: 25 April 2018
Accepted Date: 23 July 2018

Figures(12)

Three kinds of MOFs, namely[Cd(tdc)(bpy)]_n, [Zn(tdc)(bpy)]_n and [Co(tdc)(phen)(OH)]_n, were synthesized using thiophene-2, 5-dicarboxylic acid (tdc) as the main ligand and 4, 4-dipyridyl (bpy) or phenanthroline (phen) as the second ligand by hydrothermal method. Their structures were characterized and analyzed by X-ray single crystal diffractometer and infrared spectrometer. At the same time, the fluorescence properties and thermal stabilities of these three MOFs were measured by fluorescence spectrometer and thermogravimetric analyzer. Co-MOFs was modified to the surface of glassy carbon electrode (GCE), and its electrochemical behavior were studies through cyclic voltammetry (CV). The results indicated that these three kinds of MOFs have stronger fluorescence intensity and better thermal stability than ligands. The prepared Co-MOFs modified GCE showed stronger CV response than the bare GCE for potassium cyanide solution and pH 5 PBS solution containing 1.0mmol/L NaNO₂. It is expected to be used as a modifier in modified GCE.
- Metal-organic frameworks compounds,
- Thiophene-2,
- 5-dicarboxylic acid,
- Characterization,
- Properties
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沈阳化工大学材料科学与工程学院沈阳 110142