Citation: WANG Chuan-liang, YANG Qing-yang, ZHOU Shan-ke, PAN Xin, ZHAN Dong-wu, WANG Xu-zhen. Preparation of coal derived nitrogen-doped mesoporous carbon for the catalytic oxidation of H₂S at room temperature[J]. Journal of Fuel Chemistry and Technology, ;2018, 46(1): 110-119. shu

Preparation of coal derived nitrogen-doped mesoporous carbon for the catalytic oxidation of H₂S at room temperature

School of Chemistry, Faculty of Chemical, Environmental and Biological Science and Technology, Dalian University of Technology, Dalian 116024, China

Corresponding author: WANG Xu-zhen, xzwang@dlut.edu.cn
Received Date: 7 June 2017
Revised Date: 18 October 2017

Fund Project: the Natural Science Foundation of Liaoning province 201602170the Research and Innovation Training Program Project for Undergraduate Students of Dalian University of Technology 2017101410101040320the National Natural Science Foundation of China-Shanxi Coal-based low-carbon Joint Foundation U1610105the Large Equipment Open and Sharing Test Foundation Project of Dalian University of Technology 2016054The project was supported by the National Natural Science Foundation of China-Shanxi Coal-based low-carbon Joint Foundation (U1610105), National Natural Science Foundation of China-Shanxi Coal-based low-carbon Joint Foundation Key project (U1610255), the Natural Science Foundation of Liaoning province (201602170), the Research and Innovation Training Program Project for Undergraduate Students of Dalian University of Technology (2017101410101040320) and the Large Equipment Open and Sharing Test Foundation Project of Dalian University of Technology (2016054)National Natural Science Foundation of China-Shanxi Coal-based low-carbon Joint Foundation Key project U1610255

Figures(6)

Nitrogen-doped mesoporous carbon (NMCs) with high N doping level and developed mesoporous structure were prepared by a nanoscale-size SiO₂ template-assisted blend carbonization process, using anthracene oil (AO), one of distillates of coal tar, as carbon source and melamine (M) as nitrogen source. With the assistance of elemental analysis, FESEM/TEM, N₂ adsorption-desorption and XPS characterizations, the effects of various synthesis parameters on the chemical composition, pore structure and the catalytic performance of NMCs in H₂S oxidation at room temperature were investigated. The results show that NMC sample with suitable nitrogen doping level, abundant pyridinic/pyrrolic configurations, uniform large mesopore size, as well as high pore volume and specific surface area can be prepared by using appropriate amount of template agent, carbon/nitrogen source ratio and carbonization temperature (700℃), which exhibits high efficiency in the removal of H₂S through catalytic oxidation at room temperature.
- mesoporous carbon,
- coal tar,
- nitrogen-doping,
- hydrogen sulfide,
- catalytic oxidation
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Preparation of coal derived nitrogen-doped mesoporous carbon for the catalytic oxidation of H2S at room temperature

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Preparation of coal derived nitrogen-doped mesoporous carbon for the catalytic oxidation of H₂S at room temperature