Citation: Bai Qingqing, Wu Xiaoning, Wang Qian, Li Rong, Wang Xiaofei. Research Progress in Enlargement of pH in Fenton Reaction[J]. Chemistry, ;2018, 81(3): 217-222. shu

Research Progress in Enlargement of pH in Fenton Reaction

1.
School of Civil Engineering and Architecture, Xi'an University of Technology, Xi'an 710021
2.
School of Materials and Chemical Engineering, Xi'an University of Technology, Xi'an 710021
3.
School of Materials Science and Engineering, Shannxi University of Science and Technology, Xi'an 710021

Corresponding author: Wang Qian, xatutougao@163.com
Received Date: 26 October 2017
Accepted Date: 18 December 2017

Fenton technology is an effective method for the treatment of non-biodegradable organic pollutants. It can be carried out under mild conditions, but with the disadvantage of narrow pH range. In this paper, different methods of improving the catalyst and oxidant to expand the pH range were discussed, and the reaction mechanism of broadening the pH range was summarized. The catalyst modification includes the use of supported catalysts, iron and iron mineral catalysts, modified catalysts, non-ferrous metal active sites, etc. These catalysts can broaden the Fenton reaction pH range for their high catalytic activity over the wide pH range. Improvements to oxidants include the use of H₂O₂-containing solid oxidants such as percarbonates and persulfates, etc., using their own properties to achieve the purpose of broadening the pH range. Through the simultaneous improvement of the catalyst and the oxidant, the pH range of the Fenton reaction can be effectively broadened, and the formation of iron sludge can be avoided at the same time.
- Fenton oxidation technology,
- Catalyst,
- Oxidant,
- Broadening pH
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沈阳化工大学材料科学与工程学院沈阳 110142