Citation: Pan Yingying, Hu Xi, Lin Xiaoming, Xu Xuan, Luo Yifan. The Application of Core-Shell MOFs and Their Derivatives as Anode Materials in Lithium-Ion Batteries[J]. Chemistry, ;2020, 83(10): 883-890. shu

The Application of Core-Shell MOFs and Their Derivatives as Anode Materials in Lithium-Ion Batteries

School of Chemistry, South China Normal University, Guangzhou, 510006

Corresponding author: Lin Xiaoming, linxm@scnu.edu.cn; xuxuan@scnu.edu.cn Xu Xuan, xuxuan@scnu.edu.cn
Received Date: 28 May 2020
Accepted Date: 29 June 2020

Figures(5)

Metal-organic frameworks (MOFs) materials are widely used in the field of electrochemical energy conversion and storage, with the advantages of large specific surface area, adjustable pore size, easy preparation, structural and functional diversity. Among them, the unique core-shell materials often show more synergy between the core and shell due to the surface modification. This article introduces the development status of core-shell MOFs as anode materials for lithium-ion batteries, and focuses on the preparation methods of their derivatives (porous carbon, metal oxides, metal sulfur/selenide, metal/metal oxides) and their applications. MOFs can produce traditional inorganic electrode materials with adjustable structure and exhibit more excellent electrochemical performance by calcining at high temperature or changing the chemical reaction conditions. Finally, the problems and challenges of core-shell MOFs as anode materials for lithium-ion battery are summarized, and possible solutions and future application prospects are proposed.
- Metal-organic frameworks,
- Lithium-ion battery,
- Core-shell,
- Anode
1. [1]
  Gao F, Liu H, Yang K, et al. Int. J. Electrochem. Sci., 2020, 15: 1391-1411.
2. [2]
  Shrivastav V, Sundriyal S, Goel P, et al. Coord. Chem. Rev., 2019, 393: 48-78.
3. [3]
  Atashrouz S, Rahmani M. Neural. Comput. Appl., 2020, 1-14.
4. [4]
  Gao J, Mao H, Jin H, et al. Micropor. Mesopor. Mater., 2020, 297: 110030.
5. [5]
  Li K, Lin Y Z, Wang K, et al. Appl. Catal. B, 2020, 268: 118402.
6. [6]
  Liu Y, Zhao W, Li X, et al. Appl. Surf. Sci., 2020, 512: 145710.
7. [7]
  Chowdhuri A R, Laha D, Chandra S, et al. Chem. Eng. J., 2017, 319: 200-211.
8. [8]
  Li G L, Möhwald H, Shchukin D G. Chem. Soc. Rev., 2013, 42(8): 3628-3646.
9. [9]
  Lu W, Guo X, Luo Y, et al. Chem. Eng. J., 2019, 355: 208-237.
10. [10]
  Zhu W, Chen Z, Pan Y, et al. Adv. Mater., 2019, 31(38): 1800426.
11. [11]
  Zhang L, Liu H, Shi W, et al. Coord. Chem. Rev., 2019, 388: 293-309.
12. [12]
  Sun X, Gao G, Yan D, et al. Appl. Surf. Sci., 2017, 405: 52-59.
13. [13]
  Zhou Y, Huang Q, Low C T J, et al. New J. Chem., 2019, 43(14): 5632-5641.
14. [14]
  Wang B, Wang Z, Cui Y, et al. RSC Adv., 2015, 5(103): 84662-84665.
15. [15]
  Zheng X, Li Y, Xu Y, et al. CrystEngComm, 2012, 14(6): 2112-2116.
16. [16]
  Huang G, Yin D M, Wang L M. J. Mater. Chem. A, 2016, 4(39): 15106-15116.
17. [17]
  Geng H, Peng Y, Qu L, et al. Adv. Energy Mater., 2020, 10(10): 190330.
18. [18]
  Dai C, Sun G, Hu L, et al. InfoMat, 2020, 2(3): 509-526.
19. [19]
  Sun J K, Xu Q. Energy Environ. Sci., 2014, 7(7): 2071-2100.
20. [20]
  Liu B, Shioyama H, Akita T, et al. J. Am. Chem. Soc., 2008, 130(16): 5390-5391.
21. [21]
  Liu Y, Xu X, Shao Z. Energy Storage Mater., 2020, 26: 1-22.
22. [22]
  Zeng X R, Jin W W, Li H J, et al. Nanotechnology, 2020, 31(15): 155602.
23. [23]
  Eddaoudi M, Kim J, Rosi N, et al. Science, 2002, 295(5554): 469-472.
24. [24]
  Ahnfeldt T, Gunzelmann D, Loiseau T, et al. Inorg. Chem., 2009, 48(7): 3057-3064.
25. [25]
  Wang X, Zhong W, Li Y. Catal. Sci. Technol., 2015, 5(2): 1014-1020.
26. [26]
  Shi Y, Zhang X, Wang L, et al. AIChE J., 2014, 60(8): 2747-2751.
27. [27]
  Zuo L, Chen S, Wu J, et al. RSC Adv., 2014, 4(106): 61604-61610.
28. [28]
  Liu N, Liu J, Jia D, et al. Energy Storage Mater., 2019, 18: 165-173.
29. [29]
  Wang K, Pei S, He Z, et al. Chem. Eng. J., 2019, 356: 272-281.
30. [30]
  Zhang W, Wang B, Luo H, et al. J. Alloy. Compd., 2019, 803: 664-670.
31. [31]
  Pei X, Chen Y, Li S, et al. Chin. J. Chem., 2016, 34(2): 157-174.
32. [32]
  Huang X C, Lin Y Y, Zhang J P, et al. Angew. Chem. Int. Ed., 2006, 45(10): 1557-1559.
33. [33]
  Jeon J W, Sharma R, Meduri P, et al. ACS Appl. Mater. Interf., 2014, 6(10): 7214-7222.
34. [34]
  Majeed M K, Ma G, Cao Y, et al. Chem. Eur. J., 2019, 25(51): 11991-11997.
35. [35]
  Chen D, Chen G, Pei J, et al. New J. Chem., 2017, 41(15): 6973-6976.
36. [36]
  Guo W, Sun W, Wang Y. ACS Nano, 2015, 9(11): 11462-11471.
37. [37]
  Lu Y, Yu L, Wu M, et al. Adv. Mater., 2018, 30(1): 1702875.
38. [38]
  Wang D P, Fu M, Ha Y, et al. J. Colloid Interf. Sci., 2018, 529: 265-272.
39. [39]
  Wang B, Wang Z, Cui Y, et al. Micropor. Mesopor. Mater., 2015, 203: 86-90.
40. [40]
  Huang G, Zhang F, Zhang L, et al. J. Mater. Chem. A, 2014, 2(21): 8048-8053.
41. [41]
  Huang G, Zhang L, Zhang F, et al. Nanoscale, 2014, 6(10): 5509-5515.
42. [42]
  Wu Y, Meng J, Li Q, et al. Nano Res., 2017, 10(7): 2364-2376.
43. [43]
  Liu L, Guo H, Liu J, et al. Chem. Commun., 2014, 50(67): 9485-9488.
44. [44]
  Zhang J, Chu R, Chen Y, et al. J. Alloy. Compd., 2019, 797: 83-91.
45. [45]
  Guo Y, Wang Z, Lu X, et al. Chem. Commun., 2020, 56(13): 1980-1983.
46. [46]
  Zhang G, Hou S, Zhang H, et al. Adv. Mater., 2015, 27(14): 2400-2405.
47. [47]
  Ge X, Li Z, Wang C, et al. ACS Appl. Mater. Interf., 2015, 7(48): 26633-26642.
48. [48]
  Wu M, Chen H, Lv L P, et al. Chem. Eng. J., 2019, 373: 985-994.
49. [49]
  Yin X, Zhi C, Sun W, et al. J. Mater. Chem. A, 2019, 7(13): 7800-7814.
50. [50]
  He Z, Wang K, Zhu S, et al. ACS Appl. Mater. Interf., 2018, 10(13): 10974-10985.
51. [51]
  Zhao Y, Li X, Liu J, et al. ACS Appl. Mater. Interf., 2016, 8(10): 6472-6480.
52. [52]
  Zhong M, Kong L, Li N, et al. Coord. Chem. Rev., 2019, 388: 172-201.
53. [53]
  Yin W, Li W, Wang K, et al. Electrochim. Acta, 2019, 318: 673-682.
54. [54]
  Xu X, Liu W, Kim Y, et al. Nano Today, 2014, 9(5): 604-630.
55. [55]
  Huang W, Li S, Cao X, et al. ACS Sustain. Chem. Eng., 2017, 5(6): 5039-5048.
56. [56]
  Jiang T, Bu F, Liu B, et al. New J. Chem., 2017, 41(12): 5121-5124.
57. [57]
  Xue H, Yue S, Wang J, et al. J. Electroanal. Chem., 2019, 840: 230-236.
58. [58]
  Shao J, Gao T, Qu Q, et al. J. Power Sources, 2016, 324: 1-7.
59. [59]
  Yuan D, Huang G, Yin D, et al. ACS Appl. Mater. Interf., 2017, 9(21): 18178-18186.
60. [60]
  Han Y, Li J, Zhang T, et al. Chem. Eur. J., 2018, 24(7): 1651-1656.
61. [61]
  Zhong M, He W W, Shuang W, et al. Inorg. Chem., 2018, 57(8): 4620-4628.
62. [62]
  Chen S, Zhou R, Chen Y, et al. Int. J. Electrochem. Sci., 2016, 11: 10522-10535.
63. [63]
  Mandi Z, Shihua Q. Mater. Lett., 2016, 171: 18-22
64. [64]
  Guan B Y, Yu L, Li J, et al. Sci. Adv., 2016, 2(3): e1501554.
65. [65]
  Zhang S, Zhang Z, Kang J, et al. Electrochim. Acta, 2019, 320: 134542.
66. [66]
  Song X, Chen S, Guo L, et al. Adv. Energy Mater., 2018, 8(27): 1801101.
67. [67]
  Yue H, Shi Z, Wang L, et al. J. Alloy. Compd., 2017, 723: 1018-1025.
68. [68]
  Cao Y, Lu Y, Ang E H, et al. Nanoscale, 2019, 11(32): 15112-15119.
1. [1]
  Fan Yang , Zheng Liu , Da Wang , KwunNam Hui , Yelong Zhang , Zhangquan Peng . Preparation and Properties of P-Bi₂Te₃/MXene Superstructure-based Anode for Potassium-Ion Battery. Acta Physico-Chimica Sinica, 2024, 40(2): 2303006-0. doi: 10.3866/PKU.WHXB202303006
2. [2]
  Chen Pu , Daijie Deng , Henan Li , Li Xu . Fe_0.64Ni_0.36@Fe₃NiN Core-Shell Nanostructure Encapsulated in N-Doped Carbon Nanotubes for Rechargeable Zinc-Air Batteries with Ultralong Cycle Stability. Acta Physico-Chimica Sinica, 2024, 40(2): 2304021-0. doi: 10.3866/PKU.WHXB202304021
3. [3]
  Xintong Zhu , Bin Cao , Chong Yan , Cheng Tang , Aibing Chen , Qiang Zhang . Advances in coating strategies for graphite anodes in lithium-ion batteries. Acta Physico-Chimica Sinica, 2025, 41(9): 100096-0. doi: 10.1016/j.actphy.2025.100096
4. [4]
  Jingshuo Zhang , Yue Zhai , Ziyun Zhao , Jiaxing He , Wei Wei , Jing Xiao , Shichao Wu , Quan-Hong Yang . Research Progress of Functional Binders in Silicon-Based Anodes for Lithium-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(6): 2306006-0. doi: 10.3866/PKU.WHXB202306006
5. [5]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
6. [6]
  Xuechen Hu , Qiuying Xia , Fan Yue , Xinyi He , Zhenghao Mei , Jinshi Wang , Hui Xia , Xiaodong Huang . Electrochemical Characteristics of LiNbO₃ Anode Film and Its Applications in All-Solid-State Thin-Film Lithium-Ion Battery. Acta Physico-Chimica Sinica, 2024, 40(2): 2309046-0. doi: 10.3866/PKU.WHXB202309046
7. [7]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-0. doi: 10.3866/PKU.WHXB202311030
8. [8]
  Xueyu Lin , Ruiqi Wang , Wujie Dong , Fuqiang Huang . Rational Design of Bimetallic Oxide Anodes for Superior Li⁺ Storage. Acta Physico-Chimica Sinica, 2025, 41(3): 2311005-0. doi: 10.3866/PKU.WHXB202311005
9. [9]
  Xiangyu CAO , Jiaying ZHANG , Yun FENG , Linkun SHEN , Xiuling ZHANG , Juanzhi YAN . Synthesis and electrochemical properties of bimetallic-doped porous carbon cathode material. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 509-520. doi: 10.11862/CJIC.20240270
10. [10]
  Yifeng Xu , Jiquan Liu , Bin Cui , Yan Li , Gang Xie , Ying Yang . “Xiao Li’s School Adventures: The Working Principles and Safety Risks of Lithium-ion Batteries”. University Chemistry, 2024, 39(9): 259-265. doi: 10.12461/PKU.DXHX202404009
11. [11]
  Siyu Zhang , Kunhong Gu , Bing'an Lu , Junwei Han , Jiang Zhou . Hydrometallurgical Processes on Recycling of Spent Lithium-lon Battery Cathode: Advances and Applications in Sustainable Technologies. Acta Physico-Chimica Sinica, 2024, 40(10): 2309028-0. doi: 10.3866/PKU.WHXB202309028
12. [12]
  Ying Li , Yushen Zhao , Kai Chen , Xu Liu , Tingfeng Yi , Li-Feng Chen . Rational Design of Cross-Linked N-Doped C-Sn Nanofibers as Free-Standing Electrodes towards High-Performance Li-Ion Battery Anodes. Acta Physico-Chimica Sinica, 2024, 40(3): 2305007-0. doi: 10.3866/PKU.WHXB202305007
13. [13]
  Aoyu Huang , Jun Xu , Yu Huang , Gui Chu , Mao Wang , Lili Wang , Yongqi Sun , Zhen Jiang , Xiaobo Zhu . Tailoring Electrode-Electrolyte Interfaces via a Simple Slurry Additive for Stable High-Voltage Lithium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 2408007-0. doi: 10.3866/PKU.WHXB202408007
14. [14]
  Yuting ZHANG , Zunyi LIU , Ning LI , Dongqiang ZHANG , Shiling ZHAO , Yu ZHAO . Nickel vanadate anode material with high specific surface area through improved co-precipitation method: Preparation and electrochemical properties. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2163-2174. doi: 10.11862/CJIC.20240204
15. [15]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
16. [16]
  Liangliang Song , Haoyan Liang , Shunqing Li , Bao Qiu , Zhaoping Liu . Challenges and strategies on high-manganese Li-rich layered oxide cathodes for ultrahigh-energy-density batteries. Acta Physico-Chimica Sinica, 2025, 41(8): 100085-0. doi: 10.1016/j.actphy.2025.100085
17. [17]
  Xue Xiao , Jiachun Li , Xiangtong Meng , Jieshan Qiu . Sulfur-Doped Carbon-Coated Fe_0.95S_1.05 Nanospheres as Anodes for High-Performance Sodium Storage. Acta Physico-Chimica Sinica, 2024, 40(6): 2307006-0. doi: 10.3866/PKU.WHXB202307006
18. [18]
  Tao Xu , Wei Sun , Tianci Kong , Jie Zhou , Yitai Qian . Stable Graphite Interface for Potassium Ion Battery Achieving Ultralong Cycling Performance. Acta Physico-Chimica Sinica, 2024, 40(2): 2303021-0. doi: 10.3866/PKU.WHXB202303021
19. [19]
  Chenyue Huang , Hongfei Zheng , Ning Qin , Canpei Wang , Liguang Wang , Jun Lu . Single-Crystal Nickel-Rich Cathode Materials: Challenges and Strategies. Acta Physico-Chimica Sinica, 2024, 40(9): 2308051-0. doi: 10.3866/PKU.WHXB202308051
20. [20]
  Jie XIE , Hongnan XU , Jianfeng LIAO , Ruoyu CHEN , Lin SUN , Zhong JIN . Nitrogen-doped 3D graphene-carbon nanotube network for efficient lithium storage. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1840-1849. doi: 10.11862/CJIC.20240216

Get Citation

PDF

XML

Metrics

PDF Downloads(19)
Abstract views(1503)
HTML views(445)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142