Citation: JI Xue-wei, GE Qing-jie, SUN Jian. Construction of synergistic and efficient iron-based catalysts for hydrogenation of CO₂ to higher hydrocarbons[J]. Journal of Fuel Chemistry and Technology, ;2019, 47(4): 438-445. shu

Construction of synergistic and efficient iron-based catalysts for hydrogenation of CO₂ to higher hydrocarbons

JI Xue-wei ^1,2 ,
GE Qing-jie ¹ ,
SUN Jian ^1,,

1.
Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China
2.
University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: SUN Jian, sunj@dicp.ac.cn
Received Date: 13 November 2018
Revised Date: 16 February 2019

Fund Project: The project was supported by the National Natural Science Foundation of China (91745107)National Natural Science Foundation of China 91745107

Figures(6)

A series of fused iron (FI) catalysts promoted with biomass ash were prepared by physical mixing method and characterized by X-ray diffraction, transmission electron microscopy and Mossbauer spectroscopy. The catalytic performance of CO₂ hydrogenation to higher hydrocarbons was evaluated in a fixed bed reactor. The results show that compared with the catalyst without biomass ash (B-ash), the fused iron catalysts promoted with biomass ash have smaller particle size and narrower size distribution, and the four phases of Fe₃O₄, Fe₅C₂, Fe₃C as well as α-Fe coexist in synergy. Thus, the tandem reaction of reverse water gas shift (RWGS) and C-C coupling proceed efficiently, and the selectivity of higher hydrocarbons is significantly improved while methane formation is effectively suppressed. Among the products, C_4-18 hydrocarbons are dominant. The C_4-18 hydrocarbons' selectivity in all hydrocarbons reaches 73.9% at the conditions of 300℃, 1.0 MPa, 4800 h^-1, H₂/CO₂=3.0 as well as the additive amount of the promoter is 5% (mass ratio).
- CO₂ hydrogenation,
- high hydrocarbons,
- Fe-based catalyst,
- biomass,
- synergism
1. [1]
  DATTAS J, KHUMNOONC , LEEZ H, MOON W K, DOCAO S, NGUYEN T H, HWANG I C, MOON D, OLEYNIKOV P, TERASAKI O, YOON K B. CO₂ capture from humid flue gases and humid atmosphere using a microporous coppersilicate[J]. Science, 2015,350(6258):302-306. doi: 10.1126/science.aab1680
2. [2]
  WANG W, WANG S P, MA X B, GONG J L. Recent advances in catalytic hydrogenation of carbon dioxide[J]. Chem Soc Rev, 2011,40(7):3703-3727. doi: 10.1039/c1cs15008a
3. [3]
  DORNER R W, HARDY D R, WILLIAMS F W, WILLAUER H D. Heterogeneous catalytic CO₂ conversion to value-added hydrocarbons[J]. Energy Environ Sci, 2010,3(7):884-890. doi: 10.1039/c001514h
4. [4]
  ARAKAWA H, ARESTA M, ARMOR J N, BARTEAU M A, BECKMAN E J, BELL A T, BERCAW J E, CREUTZ C, DINJUS E, DIXON D A, DOMEN K, DUBOIS D L, ECKERT J, FUJITA E, GIBSON D H, GODDARD W A, GOODMAN D W, KELLER J, KUBAS G J, KUNG H H, LYONS J E, MANZER L E, MARKS T J, MOROKUMA K, NICHOLAS K M, PERIANA R, QUE L, ROSTRUP-NIELSON J, SACHTLER W M H, SCHMIDT L D, SEN A, SOMORJAI G A, STAIR P C, STULTS B R, TUMAS W. Catalysis research of relevance to carbon management progress, challenges, and opportunities[J]. Chem Rev, 2001,101(4):953-996. doi: 10.1021/cr000018s
5. [5]
  DIMITRIOU I, GARCÍA-GUTIÉRREZ P, ELDER R H, CUÉLLAR-FRANCA R M, AZAPAGIC A, ALLEN R W K. Carbon dioxide utilisation for production of transport fuels:Process and economic analysis[J]. Energy Environ Sci, 2015,8(6):1775-1789. doi: 10.1039/C4EE04117H
6. [6]
  ROY S C, VARGHESE O K, PAULOSE M, GRIMES C A. Toward solar fuels:Photocatalytic conversion of carbon dioxide to hydrocarbons[J]. ACS Nano, 2010,4(3):1259-1278. doi: 10.1021/nn9015423
7. [7]
  LI W H, WANG H Z, JIANG X, ZHU J, LIU Z M, GUO X W, SONG C S. A short review of recent advances in CO₂ hydrogenation to hydrocarbons over heterogeneous catalysts[J]. Rsc Adv, 2018,8(14):7651-7669. doi: 10.1039/C7RA13546G
8. [8]
  CENTI G, QUADRELLI E A, PERATHONER S. Catalysis for CO₂ conversion:A key technology for rapid introduction of renewable energy in the value chain of chemical industries[J]. Energy Environ Sci, 2013,6(6):1711-1731. doi: 10.1039/c3ee00056g
9. [9]
  YANG H Y, ZHANG C, GAO P, WANG H, LI X P, ZHONG L S, WEI W, SUN Y H. A review of the catalytic hydrogenation of carbon dioxide into value-added hydrocarbons[J]. Catal Sci Technol, 2017,7(20):4580-4598. doi: 10.1039/C7CY01403A
10. [10]
  WEI J, GE Q J, YAO R W, WEN Z Y, FANG C Y, GUO L S, XU H Y, SUN J. Directly converting CO₂ into a gasoline fuel[J]. Nat Commun, 2017(8)15174.
11. [11]
  GAO P, LI S G, BU X N, DANG S S, LIU Z Y, WANG H, ZHONG L S, QIU M H, YANG C G, CAI J, WEI W, SUN Y H. Direct conversion of CO₂ into liquid fuels with high selectivity over a bifunctional catalyst[J]. Nat Chem, 2017,9(10):1019-1024. doi: 10.1038/nchem.2794
12. [12]
  LIU J H, ZHANG A F, JIANG X, LIU M, SUN Y W, SONG C S, GUO X W. Selective CO₂ hydrogenation to hydrocarbons on Cu-promoted Fe-based catalysts:Dependence on Cu-Fe interaction[J]. ACS Sustainable Chem Eng, 2018,6(8):10182-10190. doi: 10.1021/acssuschemeng.8b01491
13. [13]
  NI Y M, CHEN Z Y, FU Y, LIU Y, ZHU W L, LIU Z M. Selective conversion of CO₂ and H₂ into aromatics[J]. Nat Commun, 2018,9(1)3457. doi: 10.1038/s41467-018-05880-4
14. [14]
  NIEMELÄ , NOKKOSMÄKI M. Activation of carbon dioxide on Fe-catalysts[J]. Catal Today, 2005,100(3/4):269-274.
15. [15]
  GUO L S, SUN J, JI X W, WEN Z Y, YAO R W, XU H Y, GE Q J. Directly converting carbon dioxide to linear α-olefins on bio-promoted catalysts[J]. Commun Chem, 2018,1(1).
16. [16]
  ZHANG J L, LU S P, SU X J, FAN S B, MA Q X, ZHAO T S. Selective formation of light olefins from CO₂hydrogenation over Fe-Zn-K catalysts[J]. J CO₂ Util, 2015,12:95-100. doi: 10.1016/j.jcou.2015.05.004
17. [17]
  YOU Z Y, DENG W P, ZHANG Q H, WANG Y. Hydrogenation of carbon dioxide to light olefins over non-supported iron catalyst[J]. Chin J Catal, 2013,34(5):956-963. doi: 10.1016/S1872-2067(12)60559-2
18. [18]
  SUN B, XU K, LUAN N, QIAO M H, FRANKLIN (FENG) T. Preparation and catalysis of carbon-supported iron catalysts for Fischer-Tropsch synthesis[J]. ChemCatChem, 2012,4(10):1498-1511. doi: 10.1002/cctc.v4.10
19. [19]
  YAN S R, JUN K W, HONG J S, CHOI M J, LEE K W. Promotion effect of Fe-Cu catalyst for the hydrogenation of CO₂ and application to slurry reactor[J]. Appl Catal A:Gen, 2000,194/195:63-70. doi: 10.1016/S0926-860X(99)00354-3
20. [20]
  GUO L S, SUN J, WEI J, WEN Z Y, XU H Y, GE Q J. Fischer-Tropsch synthesis over iron catalysts with corncob-derived promoters[J]. Energy Chem, 2017,26(4):632-638. doi: 10.1016/j.jechem.2017.03.017
21. [21]
  SUN J, XU H Y, LIU G G, ZHU P F, FAN R G, YONEYAMA Y, TSUBAKI N. Green synthesis of rice bran microsphere catalysts containing natural biopromoters[J]. ChemCatChem, 2015,7(11):1642-1645. doi: 10.1002/cctc.v7.11
22. [22]
  LIAO Xiao-yuan. Theoretical Study of F-T Reaction Mechanism on Fe₃C surfaces[D]. Taiyuan: Shanxi Institute of Coal Chemistry, Chinese Academy of Sciences, 2007.
23. [23]
  CHEN Yun-hong. Quantum chemical study of CO adsorption on the Fe(111) and Fe(100) surfaces[D]. Guangzhou: Jinan University, 2005.
24. [24]
  GNANAMANI M K, HAMDEH H H, JACOBS G, SHAFER W D, SPARKS D E, KEOGH R A, DAVIS B H. Fischer-Tropsch synthesis:Activity and selectivity of chi-Fe₅C₂ and circle minus-Fe₃C carbides[J]. Abstracts of Papers of the American Chemical Society, 2014,248.
25. [25]
  WEI Jian, MA Xian-gang, FANG Chuan-yan, GE Qing-jie, XU Heng-yong. Iron-silica nanocomposites as a catalyst for the selective conversion of syngas to light olefins[J]. J Fuel Chem Technol, 2014,42(7):827-832.
26. [26]
  POUR A N, SHAHRI S M K, BOZORGZADEH H R, ZAMANI Y, TAVASOLI A, MARVAST M A. Effect of Mg, La and Ca promoters on the structure and catalytic behavior of iron-based catalysts in Fischer-Tropsch synthesis[J]. Appl Catal A:Gen, 2008,348:201-208. doi: 10.1016/j.apcata.2008.06.045
27. [27]
  SATTHAWONG R, KOIZUMI N, SONG C S, PRASASSARAKICH P. Light olefin synthesis from CO₂ hydrogenation over K-promoted Fe-Co bimetallic catalysts[J]. Catal Today, 2015,251:34-40. doi: 10.1016/j.cattod.2015.01.011
28. [28]
  GALVIS H M T, BITTER J H, KHARE C B, RUITENBEEK M, DUGULAN A I, DE JONG K P. Supported iron nanoparticles as catalysts for sustainable production of lower olefins[J]. Science, 2012,335:835-838. doi: 10.1126/science.1215614
29. [29]
  YANG Y, XIANG H W, XU Y Y, BAI L, LI Y W. Effect of potassium promoter on precipitated iron-manganese catalyst for Fischer-Tropsch synthesis[J]. Appl Catal A:Gen, 2004,266(2):181-194. doi: 10.1016/j.apcata.2004.02.018
30. [30]
  SATTHAWONG R, KOIZUMI N, SONG C S, PRASASSARAKICH P. Light olefin synthesis from CO₂hydrogenation over K-promoted Fe-Co bimetallic catalysts[J]. Catal Today, 2015,251:34-40. doi: 10.1016/j.cattod.2015.01.011
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沈阳化工大学材料科学与工程学院沈阳 110142

Construction of synergistic and efficient iron-based catalysts for hydrogenation of CO2 to higher hydrocarbons

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通讯作者: 陈斌, bchen63@163.com

Construction of synergistic and efficient iron-based catalysts for hydrogenation of CO₂ to higher hydrocarbons