Citation: HUANG Xin, JIAO Xi, LIN Ming-gui, JIA Li-tao, HOU Bo, LI De-bao. Research progress in the direct nonoxidative dehydroaromatization of methane to aromatics[J]. Journal of Fuel Chemistry and Technology, ;2018, 46(9): 1087-1100. shu

Research progress in the direct nonoxidative dehydroaromatization of methane to aromatics

HUANG Xin ¹ ,
JIAO Xi ² ,
LIN Ming-gui ^1,, ,
JIA Li-tao ¹ ,
HOU Bo ¹ ,
LI De-bao ^1,,

1.
State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China
2.
Taiyuan University of Technology, Taiyuan 030024, China

Corresponding author: LIN Ming-gui, linmg@sxicc.ac.cn LI De-bao, dbli@sxicc.ac.cn
Received Date: 17 April 2018
Revised Date: 3 July 2018

Fund Project: the Coal Base Key Technologies R & D Program of Shanxi Province MH2014-13the National Natural Science Foundation of China 21273265The project was supported by the National Natural Science Foundation of China(21273265)and the Coal Base Key Technologies R & D Program of Shanxi Province(MH2014-13)

Figures(12)

The direct, nonoxidative conversion of methane to aromatics and hydrogen is a challenging research topic in the field of C₁ chemistry due to the high carbon-atom utilization efficiency, zero CO₂ emissions and short process flow. In the present paper, the advance of methane dehydroaromatization (MDA) is reviewed based on the research works of our group and the pertinent literatures from 2013 to 2017. The reaction mechanism and coking formation for the MDA process, the catalyst modification and regeneration, the application of the membrane reactor, as well as the non-Mo-based catalyst system were considered, the future prospect was given for the MDA reaction.
- methane,
- nonoxidative dehydroaromatization,
- reaction mechanism,
- coking,
- molybdenum
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沈阳化工大学材料科学与工程学院沈阳 110142