Citation: CHEN Ying, LIU Tian-cong, GAO Yan-hua, LIANG Yu-ning. In situ co-precipitation of NiMg(Al)O on γ-Al₂O₃ and its catalytic performance in the transesterification[J]. Journal of Fuel Chemistry and Technology, ;2018, 46(1): 59-66. shu

In situ co-precipitation of NiMg(Al)O on γ-Al₂O₃ and its catalytic performance in the transesterification

Provincial Key Laboratory of Oil & Gas Chemical Technology, Northeast Petroleum University, Daqing 163318, China

Corresponding author: GAO Yan-hua, shiyoudaxue0521@163.com
Received Date: 6 August 2017
Revised Date: 30 September 2017

Fund Project: The project was supported by the National Natural Science Foundation of China (50476091)the National Natural Science Foundation of China 50476091

Figures(10)

NiMgAl-LDHs/γ-Al₂O₃ was first synthesized by in-situ co-precipitation method with γ-Al₂O₃ as support, which was further transformed to the NiMg(Al)O/γ-Al₂O₃ catalyst through calcination. The NiMg(Al)O/γ-Al₂O₃ catalyst was characterized by TG-DTG, XRD, SEM, N₂ physisorption, FT-IR and CO₂-TPD and its performance in the transesterification was investigated, for the production of biodiesel with microalgae oil and methanol as raw materials. The results show that NiMgAl-LDHs and NiMg(Al)O are successfully developed on the surface and pores of γ-Al₂O₃ with high binding strength. The NiMg(Al)O/γ-Al₂O₃ catalyst exhibits high activity in transesterification; with a methanol/oil molar ratio of 12:1, the yield of biodiesel oil reaches 95% after reaction for 3 h. Moreover, the yield of biodiesel is still above 82% after using seven times.
- biodiesel,
- γ-Al₂O₃,
- transesterification,
- hydrotalcite
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In situ co-precipitation of NiMg(Al)O on γ-Al2O3 and its catalytic performance in the transesterification

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通讯作者: 陈斌, bchen63@163.com

In situ co-precipitation of NiMg(Al)O on γ-Al₂O₃ and its catalytic performance in the transesterification