Citation: CAO Yue-ling, WANG Jun-wei, KANG Mao-qing, ZHU Yu-lei. Catalytic conversion of glucose and cellobiose into ethylene glycol over various tungsten-based catalysts[J]. Journal of Fuel Chemistry and Technology, ;2016, 44(7): 845-852. shu

Catalytic conversion of glucose and cellobiose into ethylene glycol over various tungsten-based catalysts

1.
Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China
2.
University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: WANG Jun-wei, wangjw@sxicc.ac.cn
Received Date: 28 December 2015
Revised Date: 28 April 2016

Fund Project: The projeet was supporred by the Major State Basic Research Development Program of China 2012CB215305

Figures(2)

Glucose and cellobiose were used as model compounds to investigate the effect of retro-aldol condensation and hydrogenation rates on the product distribution of cellulose conversion. It was shown that the product distribution obtained over the physical mixture of Ni/SBA-15 and WO₃/SBA-15 in the glucose and cellobiose conversions were different from that attained on the Ni-WO₃/SBA-15 prepared by the co-impregnation method. The ethylene glycol (EG) yield depended on the structures of tungstic compounds, and it increased in the order of WO₃ < WO₃/SBA-15 < (NH₄)₆W₇O₂₄·6H₂O (AMT), while the particle sizes of them decreased in such an order. Regardless of the types of tungstic compounds, the EG yield obtained in the glucose conversion is lower than that attained in the cellobiose conversion at the same amount of catalyst.
- glucose,
- cellobiose,
- hydrogenolysis,
- tungsten-based catalysts,
- ethylene glycol
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沈阳化工大学材料科学与工程学院沈阳 110142