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Citation: Jiang Jinhe, Liu Fangwang, Zhang Yunchen. Study on Lithium Ion Exchange Performance of Composite Metal Oxide Mg_1.5Mn_0.5Ti_0.75O₄[J]. Chemistry, ;2017, 80(9): 880-883. shu

Study on Lithium Ion Exchange Performance of Composite Metal Oxide Mg_1.5Mn_0.5Ti_0.75O₄

1.
Department of Chemistry and Chemical Engineering, Weifang University, Weifang 261061
2.
Department of Chemical Engineering, Qingdao University of Science and Technology, Qingdao 266000

Received Date: 11 January 2017
Accepted Date: 21 May 2017

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The substance with spinel type structure can insert a large number of alternative ions and change the stoichiometric number in lithium and oxygen, meanwhile, it can keep the stability of spinel type structure. This characteristic can be used for ion exchange study to meet the requirement of extracting lithium. The characteristics of spinel type composite metal oxide can be measured by the value of saturation exchange capacity and distribution coefficient. The spinel type composite Mg_1.5Mn_0.5Ti_0.75O₄ was synthesized by the method of co-precipitation/solid state reaction thermal crystallization. The experimental results showed that Mg_1.5Mn_0.5Ti_0.75O₄ which was treated by nitric acid can extract more than 72% of Mg²⁺, while the dissolutions of Mn⁴⁺ and Ti⁴⁺ were less than 8.2%. The results also indicated that Mg_1.5Mn_0.5Ti_0.75O₄ has a good ion-sieve effect on Li⁺. Its ion exchange capacity for Li⁺ is up to 10.6 mmol·g^-1.
- Spinel type structure,
- Combined metal oxide,
- Synthesis,
- Ion exchange capability
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Study on Lithium Ion Exchange Performance of Composite Metal Oxide Mg_1.5Mn_0.5Ti_0.75O₄