Citation: LIU Yu-juan, WANG Dong-zhe, ZHANG Lei, WANG Hong-hao, CHEN Lin, LIU Dao-sheng, HAN Jiao, ZHANG Cai-shun. Effect of support calcination atmospheres on the activity of CuO/CeO₂ catalysts for methanol steam reforming[J]. Journal of Fuel Chemistry and Technology, ;2018, 46(8): 992-999. shu

Effect of support calcination atmospheres on the activity of CuO/CeO₂ catalysts for methanol steam reforming

1.
College of Chemistry, Chemical Engineering and Environmental Engineering, Liaoning Shihua University, Fushun 113001, China
2.
Department of Chemistry and Materials Engineering, Yingkou Institute of Technology, Yingkou 115014, China

Corresponding author: ZHANG Lei, lnpuzhanglei@163.com LIU Dao-sheng, dsliu05@126.com
Received Date: 2 April 2018
Revised Date: 25 June 2018

Fund Project: the National Natural Science Foundation of China 21671092The project was supported by the National Natural Science Foundation of China (21671092, 21376237) and the Doctoral Scientific Research Foundation of Liaoning Province (2016013022)the Doctoral Scientific Research Foundation of Liaoning Province 2016013022the National Natural Science Foundation of China 21376237

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In this paper, CeO₂ nanomaterials with oxygen vacancies and CuO/CeO₂ catalysts for hydrogen production from methanol steam reforming were prepared by precipitation and impregnation methods.The influence of different calcination atmosphere on the structure and properties of CeO₂ nanomaterials and the hydrogen production performance of methanol steam reforming was investigated.SEM, XRD, BET, H₂-TPR, N₂O titration and XPS were adopted to characterize the catalyst materials.The results showed that the catalytic activity of CuO/CeO₂ catalyst was closely related to the surface area of copper, the strength of Cu-Ce interaction, the number of surface defects and surface oxygen vacancies.When the reaction temperature was 250℃, the molar ratio of water to methanol was 1.2 and the gas hourly space velocity was 800 h^-1, the methanol conversion was 100% and the CO concentration in the offgas was 0.87%.
- ceria,
- carbon monoxide,
- methanol steam reforming,
- hydrogen
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Effect of support calcination atmospheres on the activity of CuO/CeO2 catalysts for methanol steam reforming

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通讯作者: 陈斌, bchen63@163.com

Effect of support calcination atmospheres on the activity of CuO/CeO₂ catalysts for methanol steam reforming