Citation: Tian Qingqiang, Wang Huajun, Yuan Jianyong. Oxidation of Aromatic Aldehydes by Sodium Chlorite and Hydrogen Peroxide under Neutral Conditions[J]. Chemistry, ;2017, 80(12): 1143-1147. shu

Oxidation of Aromatic Aldehydes by Sodium Chlorite and Hydrogen Peroxide under Neutral Conditions

Pharmacy college, Chongqing medical university, Chongqing 400016

Corresponding author: Yuan Jianyong, enediyne90@163.com
Received Date: 11 May 2017
Accepted Date: 30 August 2017

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In this paper, the reaction conditions for the oxidation of aldehydes with sodium chlorite and hydrogen peroxide in neutral environment were optimized. The effects of solvent, amounts of sodium chlorite and hydrogen peroxide and reaction temperature on the yield of acids were investigated by orthogonal experimental design. The optimum conditions were as follows:ethanol as solvent, the molar ratio of sodium chlorite, hydrogen peroxide and aldehyde was 1.1:2:1. The adaptability of aldehydes was verified, and the industrial applicability was demonstrated by amplification experiments. It was proved that the method has the characteristics of high yield, simple post-processing, green by-products without pollution, etc.
- Sodium chlorite,
- Hydrogen peroxide,
- Neutral condition,
- Oxidation,
- Aldehyde
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