Citation:
Hu Ziqiao, Liu Guichuan, Kong Yong, Lin Yongxue, Jin Junbin. Syntheses and Catalytic Applications of Palladacycles Complexes[J]. Chemistry,
;2019, 82(1): 32-36.
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Due to their abundant structures, high stability and excellent catalytic properties, palladacycles complexes have become one of the hotspots in the research of palladium chemistry. A number of synthesis methods have been developed, such as C-H bond activation, oxidation addition, metal transfer, nucleophilic addition, and ligand exchange. The CY type palladacycles complexes from ternary ring to eleven-membered ring and YCY type palladacycles complexes have been afforded. Palladacycles complexes have been utilized in olefin hydrogenation, coupling reaction, asymmetric catalysis, and other reactions. In this article, the types of palladacycles complexes were briefly introduced. The synthesis methods and application for catalytic reactions of palladacycles complexes were focused on. The development suggestions of palladacycles complexes for synthesis and catalytic application were proposed.
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Keywords:
- Palladacycles,
- Synthesis,
- Catalysis
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