Citation: LI Chao, WANG Hui, ZHU Shan-shan, LIU Guang-bo, WU Jin-hu. Research on butene oligomerization reaction over the hemicellulose modified HZSM-5[J]. Journal of Fuel Chemistry and Technology, ;2017, 45(9): 1088-1094. shu

Research on butene oligomerization reaction over the hemicellulose modified HZSM-5

LI Chao ^1,2 ,
WANG Hui ^1,, ,
ZHU Shan-shan ^1,2 ,
LIU Guang-bo ¹ ,
WU Jin-hu ¹

1.
Key Laboratory of Biofuels, Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao 266101, China
2.
University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: WANG Hui, huiwangsun@gmail.com
Received Date: 28 March 2017
Revised Date: 5 June 2017

Fund Project: the Applied Basic Research Programs of Qingdao 15-9-1-72-jchThe project was supported by the Chinese Academy of Sciences Research Program (No. XDA07070302), the Applied Basic Research Programs of Qingdao(Grant No. 15-9-1-72-jch) and the Foundation of state Key Laboratory of high-efficiency Utilization of Coal and Green Chemical Engineering (Grant No.2016-11)the Chinese Academy of Sciences Research Program XDA07070302the Foundation of state Key Laboratory of high-efficiency Utilization of Coal and Green Chemical Engineering 2016-11

Figures(5)

The HZSM-5 synthesized with modifying by different contents of hemicellulose.The morphology, texture and acidity were characterized with XRD, SEM, N₂ adsorption-desorption, NH₃-TPD and Py-FTIR. Butene oligomerization over the modified HZSM-5 was tested. The results indicate that the HZSM-5 with the 1.6% hemicellulose exhibits the best activity and stability on the butene oligomerization reaction, the conversion can maintain about 80% after 140 h on stream, with the highest selectivities of the trimer, tetramer and diesel component in the products. These may be related with its high BET surface and mesoporous volume, and the strongest acidity.
- hemicellulose,
- modified,
- HZSM-5,
- butene oligomerization
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