Citation: Yun Xing YAN, Qi FANG, Duo Rong YUAN, Yu Peng TIAN, Zhi LIU, Xiao MeiWANG, Min Hua JIANG, D.WILLIAMS, A.SIU, Zhi Gang CAI. Synthesis, Structure and Non-linear Optical Properties of Manganese Mercury Tetrathiocyanate[J]. Chinese Chemical Letters, ;1999, 10(3): 257-260. shu

Synthesis, Structure and Non-linear Optical Properties of Manganese Mercury Tetrathiocyanate

a Institute of Crystal Materials and State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100;
b Department of Chemistry, The Hong Kong University of Science and Technology, Hong Kong;
c Institute of Laser Spectroscopy and Stake Key Laboratory of Ultrafast Laser Spectroscopy, Zhongshan University, Guangzhou 510275

Received Date: 12 November 1998

Fund Project: This work was supported by the National Natural Science Foundation of China, the Scientific Research Foundation for Outstanding Young Scientist of Shangdong Province of China, and the Kev Research Project in Climbing Program from the State Science and Technology Comission of China.

The title copound Manganese Mercury Tetrathiocyanate (MnHg (SCN)₄) has been synthesized and its structure has been determined.It belongs to tetragonal system, 4 space group.The cell dimensions are:a=1.1324 (3)nm, c=0.4270 (2) nm.V=0.5475 (3)nm³, Z=2, D_c= 2.959 g/cm³, R=0.028, R_w = 0.037.The structure feature of the crystal is the Hg-S-C N-Mn bridge which leads to the formation of an infinite three dimensional network.Irradiated by a 1064 nm Nd:YAG laser beam.MnHg (SCN)₄ shows a 532 nm second harmonic intensity which is 18 times as that of organic nonlinear optical crystal urea, and therefore shows a quite promising application value as a useful nonliear optical material.
- MnHg (SCN)₄,
- synthesis,
- structure,
- nonlinear optical property
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