Home

Citation: Lv Yun, Fu Shiguo, Tian Chunrong, Yuan Baoyan, Duan Aihong, Yuan Liming. Biomimetic Mesoporous Silica for High Performance Liquid Chromatography Resolution of Chiral Compounds[J]. Chemistry, ;2019, 82(2): 175-178. shu

Biomimetic Mesoporous Silica for High Performance Liquid Chromatography Resolution of Chiral Compounds

Faculty of Chemistry and Chemical Engineering, Yunnan Normal University, Kunming 650500

Corresponding author: Yuan Liming, yuan_limingpd@126.com
Received Date: 23 August 2018
Accepted Date: 1 November 2018

Figures(3)

The biomimetic mesoporous silica is a mesoporous silica, which using organic silicane as a template that can effectively reproduce the unique morphology of the template, thereby obtaining the same or similar mesoporous structure with mesoporous silica. In this paper, bionic mesoporous silica was prepared from the biomimetic point of view, and the bionic chiral nematic mesoporous silica was prepared by extracted the chitin film from the crab shell as a template, and then the bionic chiral nematic mesoporous silica was used to prepare liquid chromatography column. The prepared column was used for the separation of chiral compounds in the high performance liquid chromatograph. The experimental results showed that the chromatographic stationary phase has a certain chiral separation effect to 10 chiral compounds.
- Biomimetic mesoporous silica,
- High performance liquid chromatography,
- Chiral stationary phase,
- Chiral separation
1. [1]
2. [2]
  U Woiwode, R J Reischl, S Buckenmaier et al. Anal. Chem., 2018, 90(13).
3. [3]
4. [4]
  T Wang, H Yang, R Qiu et al. Anal. Chim. Acta, 2016, 944: 70~77.
5. [5]
6. [6]
  Q Yue, Q Huang, Y Y Gao et al. Inorg. Chim. Acta, 2016, 443: 110~117.
7. [7]
8. [8]
9. [9]
10. [10]
  J Shen, Y Okamoto. Chem. Rev., 2016, 116(3): 1094~1138.
11. [11]
  X Yao, H Zheng, Y Zhang et al. Anal. Chem., 2016, 88(9): 4955~4964.
12. [12]
  P Ding, B S Chang, G Y Qing et al. Sci. China Chem., 2014, 57(11): 1492~1506.
13. [13]
14. [14]
15. [15]
16. [16]
17. [17]
  K Todoroki, Y Ishii, T Ide et al. Anal. Chim. Acta, 2015, 882: 101~111.
18. [18]
  Y Ke, L L Ong, W M Shih et al. Science, 2012, 338(6111): 1177~1183.
19. [19]
  H O Fabritius, C Sachs, P R Triguero et al. Adv. Mater., 2014, 21(4): 391~400.
20. [20]
  T D Nguyen, M J Maclachlan. Adv. Opt. Mater., 2015, 2(11): 1031~1037.
21. [21]
  R N Tharanathan, F S Kittur. Crit. Rev. Food Technol., 2003, 43(1): 61~87.
1. [1]
  Fan Wu , Wenchang Tian , Jin Liu , Qiuting Zhang , YanHui Zhong , Zian Lin . Core-Shell Structured Covalent Organic Framework-Coated Silica Microspheres as Mixed-Mode Stationary Phase for High Performance Liquid Chromatography. University Chemistry, 2024, 39(11): 319-326. doi: 10.12461/PKU.DXHX202403031
2. [2]
  Qiuting Zhang , Fan Wu , Jin Liu , Zian Lin . Chromatographic Stationary Phase and Chiral Separation Using Frame Materials. University Chemistry, 2025, 40(4): 291-298. doi: 10.12461/PKU.DXHX202405174
3. [3]
  Siming Bian , Sijie Luo , Junjie Ou . Application of van Deemter Equation in Instrumental Analysis Teaching: A New Type of Core-Shell Stationary Phase. University Chemistry, 2025, 40(3): 381-386. doi: 10.12461/PKU.DXHX202406087
4. [4]
  Runjie Li , Hang Liu , Xisheng Wang , Wanqun Zhang , Wanqun Hu , Kaiping Yang , Qiang Zhou , Si Liu , Pingping Zhu , Wei Shao . 氨基酸的衍生及手性气相色谱分离创新实验. University Chemistry, 2025, 40(6): 286-295. doi: 10.12461/PKU.DXHX202407059
5. [5]
  Guilan He , Yaofeng Yuan . 手性二茂铁双膦配体Xyliphos的合成及应用. University Chemistry, 2025, 40(8): 130-137. doi: 10.12461/PKU.DXHX202409122
6. [6]
  Dongheng WANG , Si LI , Shuangquan ZANG . Construction of chiral alkynyl silver chains and modulation of chiral optical properties. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 131-140. doi: 10.11862/CJIC.20240379
7. [7]
  Jin Tong , Shuyan Yu . Crystal Engineering for Supramolecular Chirality. University Chemistry, 2024, 39(3): 86-93. doi: 10.3866/PKU.DXHX202308113
8. [8]
  Renxiao Liang , Zhe Zhong , Zhangling Jin , Lijuan Shi , Yixia Jia . A Palladium/Chiral Phosphoric Acid Relay Catalysis for the One-Pot Three-Step Synthesis of Chiral Tetrahydroquinoline. University Chemistry, 2024, 39(5): 209-217. doi: 10.3866/PKU.DXHX202311024
9. [9]
  Haiying Wang , Andrew C.-H. Sue . How to Visually Identify Homochiral Crystals. University Chemistry, 2024, 39(3): 78-85. doi: 10.3866/PKU.DXHX202309004
10. [10]
  Keying Qu , Jie Li , Ziqiu Lai , Kai Chen . Unveiling the Mystery of Chirality from Tartaric Acid. University Chemistry, 2024, 39(9): 369-378. doi: 10.12461/PKU.DXHX202310091
11. [11]
  Xilin Zhao , Xingyu Tu , Zongxuan Li , Rui Dong , Bo Jiang , Zhiwei Miao . Research Progress in Enantioselective Synthesis of Axial Chiral Compounds. University Chemistry, 2024, 39(11): 158-173. doi: 10.12461/PKU.DXHX202403106
12. [12]
  Ke QIAO , Yanlin LI , Shengli HUANG , Guoyu YANG . Advancements in asymmetric catalysis employing chiral iridium (ruthenium) complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2091-2104. doi: 10.11862/CJIC.20240265
13. [13]
  Ruiying WANG , Hui WANG , Fenglan CHAI , Zhinan ZUO , Benlai WU . Three-dimensional homochiral Eu(Ⅲ) coordination polymer and its amino acid configuration recognition. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 877-884. doi: 10.11862/CJIC.20250052
14. [14]
  Conghao Shi , Ranran Wang , Juli Jiang , Leyong Wang . The Illustration on Stereoisomers of Macrocycles Containing Multiple Chiral Centers via Tröger Base-based Macrocycles. University Chemistry, 2024, 39(7): 394-397. doi: 10.3866/PKU.DXHX202311034
15. [15]
  Tingyu Zhu , Hui Zhang , Wenwei Zhang . Exploration and Practice of Ideological and Political Education in the Course of Experiments on Chemical Functional Molecules: Synthesis and Catalytic Performance Study of Chiral Mn(III)Cl-Salen Complex. University Chemistry, 2024, 39(4): 75-80. doi: 10.3866/PKU.DXHX202311011
16. [16]
  Yan Li , Xinze Wang , Xue Yao , Shouyun Yu . 基于激发态手性铜催化的烯烃E→Z异构的动力学拆分——推荐一个本科生综合化学实验. University Chemistry, 2024, 39(5): 1-10. doi: 10.3866/PKU.DXHX202309053
17. [17]
  Bizhu Shao , Huijun Dong , Yunnan Gong , Jianhua Mei , Fengshi Cai , Jinbiao Liu , Dichang Zhong , Tongbu Lu . Metal-Organic Framework-Derived Nickel Nanoparticles for Efficient CO₂ Electroreduction in Wide Potential Windows. Acta Physico-Chimica Sinica, 2024, 40(4): 2305026-0. doi: 10.3866/PKU.WHXB202305026
18. [18]
  Jie ZHAO , Sen LIU , Qikang YIN , Xiaoqing LU , Zhaojie WANG . Theoretical calculation of selective adsorption and separation of CO₂ by alkali metal modified naphthalene/naphthalenediyne. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 515-522. doi: 10.11862/CJIC.20230385
19. [19]
  Jie ZHAO , Huili ZHANG , Xiaoqing LU , Zhaojie WANG . Theoretical calculations of CO₂ capture and separation by functional groups modified 2D covalent organic framework. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 275-283. doi: 10.11862/CJIC.20240213
20. [20]
  Yanhui Zhong , Ran Wang , Zian Lin . Analysis of Halogenated Quinone Compounds in Environmental Water by Dispersive Solid-Phase Extraction with Liquid Chromatography-Triple Quadrupole Mass Spectrometry. University Chemistry, 2024, 39(11): 296-303. doi: 10.12461/PKU.DXHX202402017

Get Citation

PDF

XML

Metrics

PDF Downloads(7)
Abstract views(1098)
HTML views(308)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return