Citation: Wei Chenggang, Chen Shiqqing, Dong Ning, Cui Hongfu, Qiu Bao, Liu Zhaoping. Synthesis and Electrochemical Properties of xLiF-(Ni_1/6Co_1/6Mn_4/6)₃O₄ Composite as a Novel Cathode Material for Li-Ion Batteries[J]. Chemistry, ;2019, 82(5): 424-430. shu

Synthesis and Electrochemical Properties of xLiF-(Ni_1/6Co_1/6Mn_4/6)₃O₄ Composite as a Novel Cathode Material for Li-Ion Batteries

Wei Chenggang ^1,2 ,
Chen Shiqqing ^1,2 ,
Dong Ning ² ,
Cui Hongfu ² ,
Qiu Bao ² ,
Liu Zhaoping ^2,,

1.
School of Physical Science and Technology, Ningbo University, Ningbo 315211
2.
Advanced Li-ion Battery Engineering Lab, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201

Corresponding author: Liu Zhaoping, liuzp@nimte.ac.cn
Received Date: 6 February 2019
Accepted Date: 13 March 2019

Figures(6)

A novel cathode material xLiF-(Ni_1/6Co_1/6Mn_4/6)₃O₄ composites are synthesized by the high energy mechanical milling with different time and the as-prepared composites were modified by the graphene to improve electrochemical performance. X-ray diffraction (XRD), scanning electron microscopy (SEM), electrochemical test and X-ray photoelectron spectroscopy (XPS) are employed to further characterize the properties of the composites. The resultant cathode has the highest discharge capacity of 157.3mAh·g^-1 when ball milling 24h. The xLiF-(Ni_1/6Co_1/6Mn_4/6)₃O₄ composites with 20% graphene exhibit a discharge capacity of 235 mAh·g^-1 (1C=250 mAh·g^-1) at 0.05 C from 1.5~4.8 V. The rate capability is also promoted as the discharge specific capacity reaching 151 and 114 mAh·g^-1 at 1 C and 5 C respectively. Moreover, the variation of the discharge capacity of the composite cathode along with the cut-off voltage are analyzed, which confirms the potential of higher discharge capacity of the cathode at higher voltage.
- Cathode materials,
- Lithium-ion battery,
- Mechanical milling
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沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis and Electrochemical Properties of xLiF-(Ni1/6Co1/6Mn4/6)3O4 Composite as a Novel Cathode Material for Li-Ion Batteries

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通讯作者: 陈斌, bchen63@163.com

Synthesis and Electrochemical Properties of xLiF-(Ni_1/6Co_1/6Mn_4/6)₃O₄ Composite as a Novel Cathode Material for Li-Ion Batteries