Home

Citation: LIU KE-CHING, LIU HSIN-YEH, KAO CHIEH, CHI CH'ING-HUI, TSUI SHUNG-HU. THE GRAFT COPOLYMERIZATION OF ACRYLONITRILE ONTO CELLULOSE WITH CERIC AMMONIUM NITRATE AS INITIATOR[J]. Acta Polymerica Sinica, ;1964, 6(3): 186-192. shu

THE GRAFT COPOLYMERIZATION OF ACRYLONITRILE ONTO CELLULOSE WITH CERIC AMMONIUM NITRATE AS INITIATOR

The graft copolymerization of acrylonitrile onto cotton yarn and viscose rayon with ceric。ammonium nitrate as initiator has been studied． It was shown that the grafting occured readily．and the homopolymerization could be inhibited under proper experimental conditions．The grafting is believed to take place principally through the active centers which are formed on the cellulose substract by the action of ceric ion．It was also shown that the grafting was controlled by the diffusion of the solution tO cellulose．The graf-ting proceeded very rapidly at the begining and then leveled off tO a limiting value，depending on the fine structure of the cellulosic material，as a result of the retar- dation of diffusion by the formation of polyacrylonitrile on the surface of the cellulose．A preliminary estimation was made on the properties of the grafted products．
1. [1]
  Lisha LEI , Wei YONG , Yiting CHENG , Yibo WANG , Wenchao HUANG , Junhuan ZHAO , Zhongjie ZHAI , Yangbin DING . Application of regenerated cellulose and reduced graphene oxide film in synergistic power generation from moisture electricity generation and Mg-air batteries. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1151-1161. doi: 10.11862/CJIC.20240202
2. [2]
  Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO₂/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189
3. [3]
  Xiaoning TANG , Junnan LIU , Xingfu YANG , Jie LEI , Qiuyang LUO , Shu XIA , An XUE . Effect of sodium alginate-sodium carboxymethylcellulose gel layer on the stability of Zn anodes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1452-1460. doi: 10.11862/CJIC.20240191
4. [4]
  Wanqun Hu , Pingping Zhu , Yuan Zheng , Wanqun Zhang , Wei Shao , Hong Wu , Qiang Zhou , Kaiping Yang , Xiang Sheng . Design and Practice of Ideological and Political Case Study in Instrumental Analysis Experiment Course: the Extraction and Structural Identification of Artemisinin. University Chemistry, 2024, 39(2): 203-207. doi: 10.3866/PKU.DXHX202310062
5. [5]
  Shui Hu , Houjin Li , Zhenming Zang , Lianyun Li , Rong Lai . Integration of Science and Education Promotes the Construction of Undergraduate-to-Master’s Integration Experimental Courses: A Case Study on the Extraction, Separation and Identification of Artemisinin from Artemisia annua. University Chemistry, 2024, 39(4): 314-321. doi: 10.3866/PKU.DXHX202310063
6. [6]
  Huicheng Yang , Qianhong Sun . Practice of Ideological and Political Education in Organic Chemistry Laboratory Courses under the OBE Framework: A Case Study of Berberine Extraction. University Chemistry, 2025, 40(5): 276-282. doi: 10.12461/PKU.DXHX202410091
7. [7]
  Xinghai Liu , Hongke Wu . Exploration and Practice of Ideological and Political Education in Heterocyclic Chemistry Based on "Fentanyl" Event. University Chemistry, 2024, 39(8): 359-364. doi: 10.3866/PKU.DXHX202312100
8. [8]
  Yaqing Zhou , Jialin Liu , Jili Wang , Xin Zhou , Yong Sun , Wenhai Wu . Reform and Exploration of Assessment Models for Elective Courses in Local Universities: A Case Study of Hanjiang Normal University. University Chemistry, 2024, 39(4): 244-250. doi: 10.3866/PKU.DXHX202309056
9. [9]
  Duo Yang , Xiangchun Li , Wenyong Lai . Reform and Practice of a Diversified Teaching Model for Inorganic Chemistry Laboratory Focused on Innovation Ability Cultivation. University Chemistry, 2025, 40(4): 208-214. doi: 10.12461/PKU.DXHX202406006
10. [10]
  Jiapei Zou , Junyang Zhang , Xuming Wu , Cong Wei , Simin Fang , Yuxi Wang . A Comprehensive Experiment Based on Electrocatalytic Nitrate Reduction into Ammonia: Synthesis, Characterization, Performance Exploration, and Applicable Design of Copper-based Catalysts. University Chemistry, 2024, 39(6): 373-382. doi: 10.3866/PKU.DXHX202312081
11. [11]
  Zhenhua Wang , Haoyang Feng , Xiaoyang Shao , Wenru Fan . Vitamins in Solid Propellants: Controlled Synthesis of Neutral Macromolecular Bonding Agents. University Chemistry, 2025, 40(4): 1-9. doi: 10.3866/PKU.DXHX202401007
12. [12]
  Weihua Jiang , Yongsheng Zhou , Qiaoqiao Teng . Progressive Teaching Model in the Practice and Exploration of Ideological and Political Education in Laboratory Courses: Taking the Organic Chemistry Experiment “Synthesis of Aspirin” as an Example. University Chemistry, 2024, 39(2): 99-104. doi: 10.3866/PKU.DXHX202306028
13. [13]
  Cheng Rong , Jiang Jiang , Xinyu Zheng . Constructivism and Deconstructivism in General Chemistry Teaching: Taking the Teaching of Colloidal Solutions as an Example. University Chemistry, 2024, 39(2): 292-297. doi: 10.3866/PKU.DXHX202308035
14. [14]
  Yanhui Sun , Junmin Nan , Guozheng Ma , Xiaoxi Zuo , Guoliang Li , Xiaoming Lin . Exploration and Teaching Practice of Ideological and Political Elements in Interface Physical Chemistry: Taking “Additional Pressure on Curved Surfaces” as an Teaching Example. University Chemistry, 2024, 39(11): 20-27. doi: 10.3866/PKU.DXHX202402023
15. [15]
  Ling Li , Guocheng Wang . 知识图谱与AI助教在无机化学混合式教学中的初步探索——以“沉淀溶解平衡”的教学为例. University Chemistry, 2025, 40(6): 1-8. doi: 10.12461/PKU.DXHX202407063
16. [16]
  Yixuan Zhu , Qingtong Wang , Jin Li , Lin Chen , Junlong Zhao . Blog of Oxytocin. University Chemistry, 2024, 39(9): 134-140. doi: 10.12461/PKU.DXHX202310090
17. [17]
  Tao Cao , Fang Fang , Nianguang Li , Yinan Zhang , Qichen Zhan . Green Synthesis of p-Hydroxybenzonitrile Catalyzed by Spinach Extracts under Red-Light Irradiation: Research and Exploration of Innovative Experiments for Pharmacy Undergraduates. University Chemistry, 2024, 39(5): 63-69. doi: 10.3866/PKU.DXHX202309098
18. [18]
  Chuanli Qin , Naiying Fan , Yan Wang , Bin Wang , Guo Zhang , Bing Zheng , Yichun Qu , Zhiyao Sun , Guanghui An . Teaching Design and Exploration of Ideological and Political Education in Chemical Experiment Safety Courses: a Case Study of the “Chemical Experiment Safety” Course at Heilongjiang University. University Chemistry, 2024, 39(2): 234-241. doi: 10.3866/PKU.DXHX202308008
19. [19]
  Jinfeng Chu , Lan Jin , Yu-Fei Song . Exploration and Practice of Flipped Classroom in Inorganic Chemistry Experiment: a Case Study on the Preparation of Inorganic Crystalline Compounds. University Chemistry, 2024, 39(2): 248-254. doi: 10.3866/PKU.DXHX202308016
20. [20]
  Shuang Meng , Haixin Long , Zhou Zhou , Meizhu Rong . Inorganic Chemistry Curriculum Design and Implementation of Based on “Stepped-Task Driven + Multi-Dimensional Output” Model: A Case Study on Intermolecular Forces. University Chemistry, 2024, 39(3): 122-131. doi: 10.3866/PKU.DXHX202309008

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(98)
HTML views(0)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return