Citation: JING Jie-ying, YANG Zhi-fen, WANG Jiu-zhan, LIU Dao-cheng, FENG Jie, LI Wen-ying. Effect of preparation methods on the structure and naphthalene hydrogenation performance of Ni₂P/SiO₂ catalyst[J]. Journal of Fuel Chemistry and Technology, ;2020, 48(7): 842-851. shu

Effect of preparation methods on the structure and naphthalene hydrogenation performance of Ni₂P/SiO₂ catalyst

Training Base of State Key Laboratory of Coal Science and Technology, Taiyuan University of Technology, Taiyuan 030024, China

Corresponding author: JING Jie-ying, jingjieying@tyut.edu.cn LI Wen-ying, ying@tyut.edu.cn
Received Date: 5 June 2020
Revised Date: 3 July 2020

Fund Project: National Key Research and Development Plan Projects of China 2016YFB0600305National Natural Science Foundation of China 21978190National Natural Science Foundation of China U1610221The project was supported by National Key Research and Development Plan Projects of China (2016YFB0600305), National Natural Science Foundation of China (21978190, U1610221)

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Ni₂P/SiO₂ catalysts were prepared by temperature-programmed reduction method and hypophosphite disproportionation method to investigate their naphthalene hydrogenation performance. The prepared catalysts were characterized by ICP-OES, X-ray diffraction, H₂ temperature-programmed reduction, N₂ adsorption-desorption method and transmission electron microscopy, etc. Results showed that Ni₂P/SiO₂ catalyst with pure Ni₂P crystal phase could be successfully prepared by the temperature-programmed reduction method and hypophosphite disproportionation method. When the naphthalene hydrogenation reaction was performed at 340℃, 4 MPa, H₂/oil volume ratio of 600, and a weight hourly space velocity (WHSV) of 20.8 h^-1, Ni₂P/SiO₂ catalyst prepared by the temperature-programmed reduction method possessed superior hydrogenation activity. This result was ascribed to the advantages of temperature-programmed reduction method. It not only installed the higher number of Ni₂P species (CO adsorption amount 21.6 μmol/g) over SiO₂, but also obtained more weak acid sites on the catalyst surface, which promoted the adsorption of aromatic hydrocarbons and subsequently resulted in the higher hydrogenation activity. Furthermore, when the temperature-programmed reduction method was used to prepare Ni₂P/SiO₂ catalyst, the lower Ni/P molar ratio was more beneficial to enhance the naphthalene hydrogenation activity of the as-prepared catalyst.
- naphthalene hydrogenation,
- Ni₂P/SiO₂,
- temperature-programmed reduction method,
- hypophosphite disproportionation method
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Effect of preparation methods on the structure and naphthalene hydrogenation performance of Ni₂P/SiO₂ catalyst