Citation: Wen Xin GU, An Xin WU, Xin Fu PAN. The Novel Selective Reduction of the C-C Triple Bond[J]. Chinese Chemical Letters, ;2000, 11(10): 847-848. shu

The Novel Selective Reduction of the C-C Triple Bond

Department of Chemistry, National Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000

Received Date: 6 April 2000

Fund Project: We are grateful to the National Natural Science Foundation of China (No. 29772012) for financial support.

A novel reduction system is reported here in which the compounds with terminal C-C triple bond and disubstituted C-C triple bond react with NaBH₄/Pd(PPh₃)₄, in a base condition and only terminal C-C triple bond is reduced.
- Selective reduction,
- C-C triple bond,
- Pd(PPh₃)₄
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3. [3]
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9. [9]
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12. [12]
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14. [14]
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15. [15]
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16. [16]
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17. [17]
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19. [19]
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