Citation: J. Yang, P.H. Geil, T. C. Long, P. Xu. MORPHOLOGY EVOLUTION IN PTFE AS A FUNCTION OF MELT TIME AND TEMPERATURE II. LOW MOLECULAR WEIGHT FOLDED CHAIN SINGLE CRYSTALS AND BAND STRUCTURES[J]. Chinese Journal of Polymer Science, ;2005, 23(2): 137-145. shu

MORPHOLOGY EVOLUTION IN PTFE AS A FUNCTION OF MELT TIME AND TEMPERATURE II. LOW MOLECULAR WEIGHT FOLDED CHAIN SINGLE CRYSTALS AND BAND STRUCTURES

Corresponding author: P.H. Geil,
Received Date: 30 October 2004
Revised Date: 30 October 2004

The effect of sintering dispersed and bulk, low molecular weight (Mn = 50,000 Da), nano-emulsion polytetrafluoroethylene (PTFE) particles near their melting point is described. With the nascent particles consisting of ca. 75 nm diameter, hexagonal, single crystals, sintering at, e.g., 350℃, results, initially, in merger of neighboring particles, followed by individual molecular motion on the substrate and the formation of folded chain, lamellar single crystals and spherulites, and on-edge ribbons. It is suggested these structures develop, with time, in the mesomorphic “melt”. Sintering of the bulk resin yields extended chain, band structures, as well as folded chain lamellae; end-surface to end-surface merger, possibly by end-to-end polymerization, occurs with increasing time.
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