Citation: HUANG Jin-ming, ZHANG Jun-ying, TIAN Chong, ZHANG Shi-bo, ZHAO Yong-chun, ZHENG Chu-guang. Investigation on the transfer-transformation behavior of beryllium during coal combustion[J]. Journal of Fuel Chemistry and Technology, ;2016, 44(6): 648-653. shu

Investigation on the transfer-transformation behavior of beryllium during coal combustion

State Key Laboratory of Coal Combustion, Huazhong University of Science and Technology, Wuhan 430074, China

Corresponding author: ZHANG Jun-ying, jyzhang@hust.edu.cn
Received Date: 31 December 2015
Revised Date: 15 March 2016

Figures(7)

The thermodynamic equilibrium calculation was conducted to estimate the beryllium conversion in the combustion process of coal, and the high temperature vacuum tube furnace was used to research the beryllium compounds reaction with other solid substances and the coal combustion experiments by adding sorbents. X-ray diffraction (XRD), X-ray fluorescence probe (XRF) and inductively coupled plasma-mass spectrometry (ICP-MS) were used to reveal the transformation behavior of beryllium during coal combustion. The results indicate that the beryllium only reacts with aluminum compounds and the reaction resultants are BeAl₂O₄ and BeAl₆O₁₀, the solid-solid reaction experiments are in agreement with thermodynamic calculation results, but the actual reaction temperature is about 1000℃, far above the thermodynamic calculation temperature 650℃. Because beryllium reacts with Al₂O₃ in combustion, the release rate of beryllium in the coal sample added with Al₂O₃ reduces greatly by up to 33%. Moreover, the inhibition of illite to beryllium release for coal combustion with addition of illite is weaker owing to a higher reaction temperature of illite with beryllium than that of Al₂O₃. Kaolinite, because its reaction temperature with beryllium is too high, has the lowest inhibition effect.
- :beryllium,
- coal combustion,
- transformation,
- inhibition
1. [1]
  LIU Hai-bin, YAO Jian-jun. The research progress of beryllium disease pathogenesis and diagnosis[J]. Ind Health Occup Dis, 1997,23(4):241-244.
2. [2]
  PROFUMO A, SPINI G, CUCCA L, PESAVENTO M. Determination of inorganic beryllium species in the particulate matter of emissions and working areas[J]. Talanta, 2002,57:929-934. doi: 10.1016/S0039-9140(02)00134-0
3. [3]
  BEI Wei. Environmental Chemistry and Environmental Protection[M]. Changsha:Hunan People's Press, 1976.
4. [4]
  ZEVENHOVEN R, KILPINEN P. Control of Pollutants in Flue Gases and Fuel Gases[M]. Espoo:Turku, 2004.
5. [5]
  NODELMAN I G, PISUPATI S V, MILLER S F, SCARONI A W. Partitioning behavior of trace elements during pilot-scale combustion of pulverized coal and coal-water slurry fuel[J]. J Hazard Mater, 2000,74:47-59. doi: 10.1016/S0304-3894(99)00198-3
6. [6]
  SWAINE D J. Trace Elements in Coal[M]. London:Butter words, 1990.
7. [7]
  U.S.National Committee for Geochemistry. Panel on the Trace Elements Geochemistry of Coal Resource Development Related to Health, Trace Elements Geochemistry of Coal Resource Development Related to Environmental Quality and Health[M]. Washington D C:National Academy Press, 1990.
8. [8]
  GB 16297-1996, Integrated emission standard of air pollutants[S].
9. [9]
  National Bureau of Statistics of China. China Energy Statistical Yearbook[M]. Beijing:China Statistics Press, 2010-2014.
10. [10]
  NRIAGU J O, PACYNA J M. Quantitative assessment of worldwide contamination of air, water and soils by trace metals[J]. Nature, 1988,333:134-139. doi: 10.1038/333134a0
11. [11]
  SWAINE D J, GOODARZI F. Environmental Aspects of Trace Elements in Coal[M]. Berlin:Springer, 1995.
12. [12]
  ZHENG Chu-guang, XU Ming-hou, ZHANG Jun-ying, LIU Jing. Emissions and Control of Trace Elements from Coal Combustion[M]. Hubei:Hubei Science and Technology Press, 2002.
13. [13]
  DAI S F, VLADIMIR V S, COLIN R W, JIANG J H, JAMES C H, SONG X L, JIANG Y F, WANG X B, TATIANA G, LI X, LIU H D, ZHAO L X. Composition and modes of occurrence of minerals and elements in coal combustion products derived from high-Ge coals[J]. Int J Coal Geol, 2014,121:79-97. doi: 10.1016/j.coal.2013.11.004
14. [14]
  BAI Xiang-fei, LI Wen-hua, CHEN Wen-min. Distribution and modes of occurrence of beryllium in chinese coal[J]. J Fuel Chem Technol, 2004,32(2):155-159.
15. [15]
  TANG Xiu-yi, HUANG Wen-hui. Trace elements of coal and its significances on research[J]. Coal Geol Chin, 2002,14:1-4.
16. [16]
  MOU Bao-lei. Element Geochemistry[M]. Beijing:Peking University Press, 1999.
17. [17]
  WANG J, TOMITA A. A chemistry on the volatility of some trace elements during coal combustion and pyrolysis[J]. Energy Fuels, 2003,17(4):954-960. doi: 10.1021/ef020251o
18. [18]
  GIBBS B M, THOMPAON D, ARGENT B B. Mobilisation of trace elements from as-supplied and additionally cleaned coal:Predictions for Ba, Be, Cd, Co, Mo, Nb, Sb, V and W[J]. Fuel, 2008,87:1217-1229. doi: 10.1016/j.fuel.2007.06.015
19. [19]
  GEORGE A, LARRION M, DUGWELL D, FENNELL P S, KANDIYOTI R. Co-firing of single, binary, and ternary fuel blends:Comparing synergies within trace element partitioning arrived at by thermodynamic equilibrium modeling and experimental measurements[J]. Energy Fuels, 2010,24:2918-2923. doi: 10.1021/ef100001h
20. [20]
  SHAO Jing-bang, SHAO Xu-xin, WANG Zu-ne. The influence of mineral composition on the properties of coal ash[J]. Coal Process Compr Util, 1996,6:37-41.
21. [21]
  FINKELMAN R B. Models of occurrence of potentially hazardous elements in coal:Levels of confidence[J]. Fuel Process Technol, 1994,39(1):21-34.
22. [22]
  QUEROL X, LASTUEY A, PLANA F. Trace elements in high-S subbituminous coals from the teruel mining district[J]. Appl Geochem, 1992,7(5):547-561.
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