Citation: DUAN Ting-ming, XIAO Yong, ZHANG Guo-quan, JIA Li-tao, HOU Bo, LI De-bao. Effect of calcination temperature on the properties of the mixed TiO₂-ZrO₂ oxides and their performance in the dehydration of octadecanol to octadecene[J]. Journal of Fuel Chemistry and Technology, ;2020, 48(5): 626-631. shu

Effect of calcination temperature on the properties of the mixed TiO₂-ZrO₂ oxides and their performance in the dehydration of octadecanol to octadecene

DUAN Ting-ming ^1,2 ,
XIAO Yong ^1,, ,
ZHANG Guo-quan ¹ ,
JIA Li-tao ¹ ,
HOU Bo ¹ ,
LI De-bao ¹

1.
State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China
2.
University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: XIAO Yong, xiaoyong@sxice.ac.cn
Received Date: 17 January 2020
Revised Date: 19 March 2020

Figures(5)

A series of mixed TiO₂-ZrO₂ oxide catalysts used for the dehydration of octadecanol to octadecene were prepared by doping TiO₂ in ZrO₂ and calcining at 350-500 ℃. With the increase of calcination temperature, the amount of Lewis acid sites on the catalyst surface gradually increases. The amount of Lewis acid sites on the catalyst calcined at 450 ℃ is the most, and when the calcination temperature is over 450 ℃, the amount of Lewis acid sites decreases. No Brønsted acid sites are found on the catalysts. The mixed TiO₂-ZrO₂ oxides calcined at temperature below 400 ℃ contain Ti-O-Zr bonds and amorphous structure. The mixed TiO₂-ZrO₂ oxides with calcination temperature above 400 ℃ show monoclinic and tetragonal phases of ZrO₂. The crystalline phase of the metal oxides and amount of the acid sites simultaneously affect the performance of the catalysts. The acid sites on the mixed TiO₂-ZrO₂ oxides with amorphous structure have much higher dehydration activity than those with monoclinic and tetragonal zirconia crystalline phases. The catalyst calcined at 400 ℃ has the highest yield of 1-octadecene.
- fatty alcohol dehydration,
- TiO₂-ZrO₂ mixed oxides,
- α-olefins,
- acid sites
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沈阳化工大学材料科学与工程学院沈阳 110142

Effect of calcination temperature on the properties of the mixed TiO2-ZrO2 oxides and their performance in the dehydration of octadecanol to octadecene

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

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通讯作者: 陈斌, bchen63@163.com

Effect of calcination temperature on the properties of the mixed TiO₂-ZrO₂ oxides and their performance in the dehydration of octadecanol to octadecene