Citation: DUAN Ting-ming, XIAO Yong, ZHANG Guo-quan, JIA Li-tao, HOU Bo, LI De-bao. Effect of calcination temperature on the properties of the mixed TiO₂-ZrO₂ oxides and their performance in the dehydration of octadecanol to octadecene[J]. Journal of Fuel Chemistry and Technology, ;2020, 48(5): 626-631. shu

Effect of calcination temperature on the properties of the mixed TiO₂-ZrO₂ oxides and their performance in the dehydration of octadecanol to octadecene

DUAN Ting-ming ^1,2 ,
XIAO Yong ^1,, ,
ZHANG Guo-quan ¹ ,
JIA Li-tao ¹ ,
HOU Bo ¹ ,
LI De-bao ¹

1.
State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China
2.
University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: XIAO Yong, xiaoyong@sxice.ac.cn
Received Date: 17 January 2020
Revised Date: 19 March 2020

Figures(5)

A series of mixed TiO₂-ZrO₂ oxide catalysts used for the dehydration of octadecanol to octadecene were prepared by doping TiO₂ in ZrO₂ and calcining at 350-500 ℃. With the increase of calcination temperature, the amount of Lewis acid sites on the catalyst surface gradually increases. The amount of Lewis acid sites on the catalyst calcined at 450 ℃ is the most, and when the calcination temperature is over 450 ℃, the amount of Lewis acid sites decreases. No Brønsted acid sites are found on the catalysts. The mixed TiO₂-ZrO₂ oxides calcined at temperature below 400 ℃ contain Ti-O-Zr bonds and amorphous structure. The mixed TiO₂-ZrO₂ oxides with calcination temperature above 400 ℃ show monoclinic and tetragonal phases of ZrO₂. The crystalline phase of the metal oxides and amount of the acid sites simultaneously affect the performance of the catalysts. The acid sites on the mixed TiO₂-ZrO₂ oxides with amorphous structure have much higher dehydration activity than those with monoclinic and tetragonal zirconia crystalline phases. The catalyst calcined at 400 ℃ has the highest yield of 1-octadecene.
- fatty alcohol dehydration,
- TiO₂-ZrO₂ mixed oxides,
- α-olefins,
- acid sites
1. [1]
  ECHAROJ S, SANTIKUNAPORN M, CHAVADEJ S. Transformation of bioderived 1-decanol to diesel-like fuel and biobased oil via dehydration and oligomerization reactions[J]. Energy Fuels, 2017,31(9):9465-9476. doi: 10.1021/acs.energyfuels.7b01247
2. [2]
  LI Ying-hui, ZENG Qun-ying, WAN Shu-bao, CHI Ke-bin, DU Hai. Synthesis process and market of α-olefin[J]. Adv Fine Petrochem, 2004,5(11):12-16. doi: 10.3969/j.issn.1009-8348.2004.11.004
3. [3]
  LI Ying-hui, ZENG Qun-ying, XIAO Hai-cheng, WAN Shu-bao, CHI Ke-bin. Progress in alpha olefin synhesis processes[J]. Nat Gas Chem Ind, 2005,30(2):55-58. doi: 10.3969/j.issn.1001-9219.2005.02.013
4. [4]
  ZHAO Hui-ping. Octene-1 manufacturing process[J]. Petrochem Ind Technol, 2006(1):59-64. doi: 10.3969/j.issn.1006-0235.2006.01.017
5. [5]
  ZHENG Lai-chang, WANG Ru-wen, YANG Xiao-hui, YANG Ke. Technical progress of α-olefin production from vegetabe oil[J]. Lubr Oil, 2015,30(4):1-4. doi: 10.3969/j.issn.1002-3119.2015.04.001
6. [6]
  SONG W, LIU Y, BARATH E, WANG L L, ZHAO C, MEI D, LERCHER J A. Dehydration of 1-octadecanol over H-BEA:A combined experimental and computational study[J]. ACS Catal, 2016,6(2):878-889. doi: 10.1021/acscatal.5b01217
7. [7]
  CHOKKARAM S, DAVIS B H. Dehydration of 2-octanol over zirconia catalysts:Influence of crystal structure, sulfate addition and pretreatment[J]. J Mol Catal A:Chem, 1997,118(1):89-99. doi: 10.1016/S1381-1169(96)00380-9
8. [8]
  KOSTESTKYY P, YU J, GORTE R J, MPOURMPAKIS G. Structure-activity relationships on metal-oxides:Alcohol dehydration[J]. Catal Sci Technol, 2014,4:3861-3869. doi: 10.1039/C4CY00632A
9. [9]
  SATO S, TAKAHASHI R, SODESAWA T, YAMAMOTO N. Dehydration of 1, 4-butanediol into 3-buten-1-ol catalyzed by ceria[J]. Catal Commun, 2004,5(8):397-400. doi: 10.1016/j.catcom.2004.05.006
10. [10]
  CHEN B H, LU J Z, WU L P, CHAO Z S. Dehydration of bio-ethanol to ethylene over iron exchanged HZSM-5[J]. Chin J Catal, 2016,37(11):1941-1948. doi: 10.1016/S1872-2067(16)62524-X
11. [11]
  TAKAHASHI N, SUDA A, HACHISUKA I, SUGIURA M, SOBUKAWA H, SHINJOH H. Sulfur durability of NO_x storage and reduction catalyst with supports of TiO₂, ZrO₂ and ZrO₂-TiO₂ mixed oxides[J]. Appl Catal B:Environ, 2007,72(1/2):187-195.
12. [12]
  MAITY S, RANA M, BEJ S, ANCHEYTA-JUAREZ J, DHAR G M, RAO T P. TiO₂-ZrO₂ mixed oxide as a support for hydrotreating catalyst[J]. Catal lett, 2001,72:115-119.
13. [13]
  LI K T, WANG I, WU J C. Surface and catalytic properties of TiO₂-ZrO₂ mixed oxides[J]. Catal Surv Asia, 2012,16(4):240-248. doi: 10.1007/s10563-012-9147-y
14. [14]
  MANRIQUEZ M, LOPEZ T, GOMEZ R, NAVARRETE J. Preparation of TiO₂-ZrO₂ mixed oxides with controlled acid-basic properties[J]. J Mol Catal A:Chem, 2004,220(2):229-237. doi: 10.1016/j.molcata.2004.06.003
15. [15]
  AN M, LI L, CAO Y, MA F, LIU D, GU F. Coral reef-like Pt/TiO₂-ZrO₂ porous composites for enhanced photocatalytic hydrogen production performance[J]. Mol Catal, 2019,475110482. doi: 10.1016/j.mcat.2019.110482
16. [16]
  FAN M, SI Z, SUN W, ZHANG P. Sulfonated ZrO₂-TiO₂ nanorods as efficient solid acid catalysts for heterogeneous esterification of palmitic acid[J]. Fuel, 2019,252:254-261. doi: 10.1016/j.fuel.2019.04.121
17. [17]
  LIANG Xiao-feng, YANG Shi-yuan, WANG Jun-xia. X-ray and raman studies of ZrO₂ particles synthesized by alcohol-thermal method[J]. J Synth Cryst, 2008,37(4):1037-1041. doi: 10.3969/j.issn.1000-985X.2008.04.054
18. [18]
  POWERS D, GRAY H B. Characterization of the thermal dehydration of zirconium oxide halide octahydrates[J]. Inorg Chem, 1973,12(11):2721-2726. doi: 10.1021/ic50129a045
19. [19]
  KILO M, SCHILD C, WOKAUN A, BAIKER A. Surface oxidic phases of binary and ternary zirconia-supported metal catalysts investigated by raman spectroscopy[J]. J Chem Soc, Faraday Trans, 1992,88:1453-1457. doi: 10.1039/ft9928801453
20. [20]
  MICIUKIEWICZ J, MANG T, KNOZINGER H. Raman spectroscopy characterization of molybdena supported on titania-zirconia mixed oxide[J]. Appl Catal A:Gen, 1995,122(2):151-159. doi: 10.1016/0926-860X(94)00236-3
21. [21]
  SUN Chuan-zhi. Synthesis and Characterization of Titanium Oxide Based Catalysts and Their Application in the Environmental Catalysis[M]. Nanjing:Nanjing University, 2011.
22. [22]
  REDDY B M, CHOWDHURY B, SMIRNIOTIS P G. An XPS study of the dispersion of MoO₃ on TiO₂-ZrO₂, TiO₂-SiO₂, TiO₂-Al₂O₃, SiO₂-ZrO₂, and SiO₂-TiO₂-ZrO₂ mixed oxides[J]. Appl Catal A:Gen, 2001,211(1):19-30. doi: 10.1016/S0926-860X(00)00834-6
23. [23]
  MULLINS W, AVERBACH B. Bias-reference X-Ray photoelectron spectroscopy of sapphire and yttrium aluminum garnet crystals[J]. Surf Sci, 1988,206(1/2):29-40.
24. [24]
  STEPHENSON D, BINKOWSKI N. X-ray photoelectron spectroscopy of silica in theory and experiment[J]. J Non-Cryst Solids, 1976,22(2):399-421. doi: 10.1016/0022-3093(76)90069-7
25. [25]
  BARTHOS R, LONYI F, ENGELHARDT J, VALYON J. A study of the acidic and catalytic properties of pure and sulfated zirconia-titania and zirconia-silica mixed oxides[J]. Top Catal, 2000,10:79-87. doi: 10.1023/A:1019112017065
26. [26]
  GOTT T, OYAMA S T. A general method for determining the role of spectroscopically observed species in reaction mechanisms:Analysis of coverage transients(ACT)[J]. J Catal, 2009,263(2):359-371. doi: 10.1016/j.jcat.2009.02.028
27. [27]
  HONG E, BAEK S W, SHIN M, SUH Y W, SHIN C H. Effect of aging temperature during refluxing on the textural and surface acidic properties of zirconia catalysts[J]. J Ind Eng Chem, 2017,54:137-145. doi: 10.1016/j.jiec.2017.05.026
28. [28]
  EMEIS C. Determination of integrated molar extinction coefficients for infrared absorption bands of pyridine adsorbed on solid acid catalysts[J]. J Catal, 1993,141:347-354. doi: 10.1006/jcat.1993.1145
29. [29]
  TANABE K, SUMIYOSHI T, SHIBATA K, KIYOURA T, KITAGAWA J. A new hypothesis regarding the surface acidity of binary metal oxides[J]. Bull Chem Soc Jpn, 1974,47:1064-1066. doi: 10.1246/bcsj.47.1064
30. [30]
  DAS D, MISHRA H K, PARIDA K M. Preparation, physico-chemical characterization and catalytic activity of sulphated ZrO₂-TiO₂ mixed oxides[J]. J Mol Catal A:Chem, 2002,189:271-282. doi: 10.1016/S1381-1169(02)00363-1
1. [1]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
2. [2]
  Zhenxing Liu , Jiaen Hu , Zishi Cheng , Xinqi Hao . 基础有机化学教学中烯烃的氧化反应. University Chemistry, 2025, 40(6): 139-144. doi: 10.12461/PKU.DXHX202408107
3. [3]
  Hongling Yuan , Jialin Xie , Jiawei Wang , Jixiang Zhao , Jiayan Liu , Qing Feng , Wei Qi , Min Liu . Cyclic Olefin Copolymer (COC): The Agile Vanguard in the Realm of Materials. University Chemistry, 2024, 39(7): 294-298. doi: 10.12461/PKU.DXHX202311041
4. [4]
  Jiaxun Wu , Mingde Li , Li Dang . The R eaction of Metal Selenium Complexes with Olefins as a Tutorial Case Study for Analyzing Molecular Orbital Interaction Modes. University Chemistry, 2025, 40(3): 108-115. doi: 10.12461/PKU.DXHX202405098
5. [5]
  Jingyi Xie , Qianxi Lü , Weizhen Qiao , Chenyu Bu , Yusheng Zhang , Xuejun Zhai , Renqing Lü , Yongming Chai , Bin Dong . Enhancing Cobalt―Oxygen Bond to Stabilize Defective Co₂MnO₄ in Acidic Oxygen Evolution. Acta Physico-Chimica Sinica, 2024, 40(3): 2305021-0. doi: 10.3866/PKU.WHXB202305021
6. [6]
  Yaping ZHANG , Tongchen WU , Yun ZHENG , Bizhou LIN . Z-scheme heterojunction β-Bi₂O₃ pillared CoAl layered double hydroxide nanohybrid: Fabrication and photocatalytic degradation property. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 531-539. doi: 10.11862/CJIC.20240256
7. [7]
  Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH₂ supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317
8. [8]
  Wenke ZHENG , Ce LIU , Wei CHEN , Hongshan KE , Fanlong ZENG , Yibo LEI , Anyang LI , Wenyuan WANG . Synthesis and bonding analysis of low-coordinate Fe and Cr complexes with ultra-bulky silylamino groups. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1285-1293. doi: 10.11862/CJIC.20250095
9. [9]
  Xunzhang Fan , Yuanjin Zhao , Shufang Luo , Aihua He . Karl Ziegler: A Pioneer in the Polyolefin Industry – Commemorating the 50th Anniversary of the German Chemist’s Passing. University Chemistry, 2024, 39(8): 389-394. doi: 10.3866/PKU.DXHX202312065
10. [10]
  Lilong Gao , Yuhao Zhai , Dongdong Zhang , Linjun Huang , Kunyan Sui . Exploration of Thiol-Ene Click Polymerization in Polymer Chemistry Experiment Teaching. University Chemistry, 2025, 40(4): 87-93. doi: 10.12461/PKU.DXHX202405143
11. [11]
  Zihao Guo , Shichen Ma , Kin Shing Chan . 烯烃环化反应中6电子试剂的等瓣相似性和等电子关系. University Chemistry, 2025, 40(6): 160-166. doi: 10.12461/PKU.DXHX202408038
12. [12]
  Jiamin Li , Wenyue Zhong , Kin Shing Chan . “烯”君入瓮又入学——据元素周期表与酸碱理论谈烯烃教学. University Chemistry, 2025, 40(6): 177-182. doi: 10.12461/PKU.DXHX202408040
13. [13]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
14. [14]
  Yajin Li , Huimin Liu , Lan Ma , Jiaxiong Liu , Dehua He . Photothermal Synthesis of Glycerol Carbonate via Glycerol Carbonylation with CO₂ over Au/Co₃O₄-ZnO Catalyst. Acta Physico-Chimica Sinica, 2024, 40(9): 2308005-0. doi: 10.3866/PKU.WHXB202308005
15. [15]
  Jianan Hong , Chenyu Xu , Yan Liu , Changqi Li , Menglin Wang , Yanwei Zhang . Decoding the interfacial competition between hydrogen evolution and CO₂ reduction via edge-active-site modulation in photothermal catalysis. Acta Physico-Chimica Sinica, 2025, 41(9): 100099-0. doi: 10.1016/j.actphy.2025.100099
16. [16]
  Xinyu Yin , Haiyang Shi , Yu Wang , Xuefei Wang , Ping Wang , Huogen Yu . Spontaneously Improved Adsorption of H₂O and Its Intermediates on Electron-Deficient Mn^(3+δ)+ for Efficient Photocatalytic H₂O₂ Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312007-0. doi: 10.3866/PKU.WHXB202312007
17. [17]
  Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . Effect of Interlayer Anions in Layered Double Hydroxides on the Photothermocatalytic CO₂ Methanation of Derived Ni-Al₂O₃ Catalysts. Acta Physico-Chimica Sinica, 2025, 41(1): 100002-0. doi: 10.3866/PKU.WHXB202309002
18. [18]
  Danqing Wu , Jiajun Liu , Tianyu Li , Dazhen Xu , Zhiwei Miao . Research Progress on the Simultaneous Construction of C—O and C—X Bonds via 1,2-Difunctionalization of Olefins through Radical Pathways. University Chemistry, 2024, 39(11): 146-157. doi: 10.12461/PKU.DXHX202403087
19. [19]
  Weina Wang , Lixia Feng , Fengyi Liu , Wenliang Wang . Computational Chemistry Experiments in Facilitating the Study of Organic Reaction Mechanism: A Case Study of Electrophilic Addition of HCl to Asymmetric Alkenes. University Chemistry, 2025, 40(3): 206-214. doi: 10.12461/PKU.DXHX202407022
20. [20]
  Xudong Liu , Huili Fan , Junping Xiao , Min Yang , Yan Li . Teaching Approaches to the A_E + A_N Mechanism of Electrophilic Addition Reactions between Olefins and Inorganic Acids in Organic Chemistry. University Chemistry, 2025, 40(7): 367-372. doi: 10.12461/PKU.DXHX202409041

Get Citation

PDF

XML

Metrics

PDF Downloads(7)
Abstract views(729)
HTML views(131)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Effect of calcination temperature on the properties of the mixed TiO2-ZrO2 oxides and their performance in the dehydration of octadecanol to octadecene

Metrics

通讯作者: 陈斌, bchen63@163.com

Effect of calcination temperature on the properties of the mixed TiO₂-ZrO₂ oxides and their performance in the dehydration of octadecanol to octadecene