Citation: Zi Qiang LEI, Qiao Xiang KANG, Xiang Zhen BAI, Zhi Wang YANG, Qing Hua ZHANG. Oxidation of Alcohols Catalyzed by Ruthenium Complexes with Iodosylbenzene as Oxidant[J]. Chinese Chemical Letters, ;2005, 16(6): 846-848. shu

Oxidation of Alcohols Catalyzed by Ruthenium Complexes with Iodosylbenzene as Oxidant

Key Laboratory of Polymer Materials of Gansu Province, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070

Received Date: 12 July 2004

Fund Project: This work was financially supported by the National Natural Science Foundation of China (No. 20174031).

Five ruthenium complexes such as Phen-Ru-Phen, Phen-Ru-Bipy, Phen-Ru-Quin,Quin-Ru-Quin and Bipy-Ru-Quin (where Phen=1, 10-phenanthroline, Quin=8-hydroxyquinoline,Bipy=2, 2'-bipyridine) were synthesized and used as catalysts for the oxidation of benzylic and primary aliphatic alcohols with iodosylbenzene as oxidant. The oxidations were carried out at room temperature, affording the corresponding aldehydes and ketones with high selectivity.
- Alcohols,
- catalytic oxidation,
- ruthenium complexes,
- iodosylbenzene
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