Citation: Lv Meijiao. Research Progress in Graphene-Based Composites for the Removal and Detection of Heavy Metal Ions[J]. Chemistry, ;2017, 80(2): 164-172, 163. shu

Research Progress in Graphene-Based Composites for the Removal and Detection of Heavy Metal Ions

Lv Meijiao

Key Laboratory of Green Synthesis and Applications, College of Chemistry, Chongqing Normal University, Chongqing 401331

Received Date: 11 May 2016
Accepted Date: 20 July 2016

Figures(5)

Graphene was applied widely in environmental protection and detection due to its unique physicochemical properties, including larger specific surface area, high-speed electron mobility and excellent electrocatalytic activity. In the past few years, many efficient adsorbents and sensors based on graphene have been constructed for the treatment of heavy metal ions. In this article, recent research achievements are reviewed on the application of graphene-based materials for the removal and detection of heavy metal ions, the advantages and disadvantages of different methods are compared. Finally, a perspective on the future challenge and research focus is discussed.
- Graphene,
- Composites,
- Heavy metal ions,
- Removal,
- Detection
1. [1]
  H Needleman. Ann. Rev. Med., 2004, 55:209~222. doi: 10.1146/annurev.med.55.091902.103653
2. [2]
  S Stankovich, D A Dikin, G H B Dommett et al. Nature, 2006, 442:282~286. doi: 10.1038/nature04969
3. [3]
  A A Balandin, S Ghosh, W Bao et al. Nano Lett., 2008, 8:902~907. doi: 10.1021/nl0731872
4. [4]
  K S Novoselov, A K Geim, S V Morozov et al. Science, 2004, 306:666~669. doi: 10.1126/science.1102896
5. [5]
  C Lee, X Wei, J W Kysar et al. Science, 2008, 321:385~388. doi: 10.1126/science.1157996
6. [6]
  G L Liu, C L Yu, C C Chen et al. Sci. China Chem., 2012, 55:1622~1626.
7. [7]
  J T Liu, X Ge, X X Ye et al. J. Mater. Chem. A, 2016, 4:1970~1979. doi: 10.1039/C5TA08106H
8. [8]
  Z P Chen, Y R Li, M Guo et al. J. Hazard. Mater., 2016, 310:188~198. doi: 10.1016/j.jhazmat.2016.02.034
9. [9]
  P J J Huang, C V Ballegooiea, J W Liu. Analyst, 2016, 141:3788~3793. doi: 10.1039/C5AN02031J
10. [10]
  S Kumar, G Bhanjana, N Dilbaghi et al. Sensor. Actuat. B, 2016, 227:29~34. doi: 10.1016/j.snb.2015.11.101
11. [11]
  C F Chang, Q D Truong, J R Chen. Appl. Surf. Sci., 2013, 264:329~334. doi: 10.1016/j.apsusc.2012.10.022
12. [12]
  Y Q Leng, W L Guo, S N Su et al. Chem. Eng. J., 2012, 211~212:406~411.
13. [13]
  Y L Lei, F Chen, Y J Guo et al. Chem. Phys. Lett., 2014, 593:122~127. doi: 10.1016/j.cplett.2013.12.066
14. [14]
  L Q Zhao, B W Yu, F M Xue et al. J. Hazard. Mater., 2015, 286:449~456. doi: 10.1016/j.jhazmat.2015.01.021
15. [15]
  S B Wu, K S Zhang, X L Wang et al. Chem. Eng. J., 2015, 262:1292~1302. doi: 10.1016/j.cej.2014.10.092
16. [16]
  M Xing, L J Xu, J L Wang. J. Hazard. Mater., 2016, 301:286~296. doi: 10.1016/j.jhazmat.2015.09.004
17. [17]
  L M Cui, Y G Wang, L Gao et al. Chem. Eng. J., 2015, 281:1~10. doi: 10.1016/j.cej.2015.06.043
18. [18]
  H M Xu, Z Qu, C X Zong et al. Environ. Sci. Technol., 2015, 49(11):6823~6830. doi: 10.1021/es505978n
19. [19]
  L L Li, H M Duan, X J Wang et al. New J. Chem., 2014, 38:6008~6016. doi: 10.1039/C4NJ00782D
20. [20]
  Y N Zhang, C Zhong, Q Y Zhang et al. RSC Adv., 2015, 5:5996~6005. doi: 10.1039/C4RA13333A
21. [21]
  G Gollavelli, C C Chang, Y C Ling. ACS Sustain. Chem. Eng., 2013, 1(5):462~472. doi: 10.1021/sc300112z
22. [22]
  G Zhou, X Y Xu, W C Zhu et al. New J. Chem., 2015, 39, 7355~7362. doi: 10.1039/C5NJ00897B
23. [23]
  M L Chen, Y Sun, C B Huo et al. Chemosphere, 2015, 130:52~58. doi: 10.1016/j.chemosphere.2015.02.046
24. [24]
  S Kumar, R R Nair, P B Pillai et al. ACS Appl. Mater. Int., 2014, 6:17426~17436. doi: 10.1021/am504826q
25. [25]
  Y K Zhang, L G Yan, W Y Xu et al. J. Mol. Liq., 2014, 191:177~182. doi: 10.1016/j.molliq.2013.12.015
26. [26]
  L L Fan, C N Luo, M Sun et al. J. Mater. Chem., 2012, 22:24577~24583. doi: 10.1039/c2jm35378d
27. [27]
  L L Fan, C N Luo, M Sun et al. Colloid Surf. B, 2013, 103:523~529. doi: 10.1016/j.colsurfb.2012.11.006
28. [28]
  L L Li, L L Fan, M Sun et al. Colloid Surf. B, 2013, 107:76~83. doi: 10.1016/j.colsurfb.2013.01.074
29. [29]
  F Zhang, B Wang, S F He et al. J. Chem. Eng., 2014, 59:1719~1726.
30. [30]
  G Y Zhou, C B Liu, Y H Tang et al. Chem. Eng. J., 2015, 280:275~282. doi: 10.1016/j.cej.2015.06.041
31. [31]
  Y H Zhang, Z Chen, S Q Liu et al. Appl. Catal. B-Environ., 2013, 140~141:598~607.
32. [32]
  Y Zhao, D L Zhao, C L Chen et al. J. Colloid Interf. Sci., 2013, 405:211~217. doi: 10.1016/j.jcis.2013.05.004
33. [33]
  G H Moon, D H Kim, H Kim et al. Environ. Sci. Technol. Lett., 2014, 1:185~190. doi: 10.1021/ez5000012
34. [34]
  C Wang, M H Cao, P F Wang et al. Appl. Catal. A-Gen., 2014, 473:83~89. doi: 10.1016/j.apcata.2013.12.028
35. [35]
  X J Liu, L K Pan, T Lv et al. J. Colloid Interf. Sci., 2013, 394:441~444. doi: 10.1016/j.jcis.2012.11.047
36. [36]
  F T Johra, W G Jung. Appl. Catal. A-Gen., 2015, 491:52~57. doi: 10.1016/j.apcata.2014.11.036
37. [37]
  Y X Du, Z C Tao, J Guan et al. RSC Adv., 2015, 5:81438~81444. doi: 10.1039/C5RA15561D
38. [38]
  X Q An, J C Yu, F Wang et al. Appl. Catal. B-Environ., 2013, 129:80~88. doi: 10.1016/j.apcatb.2012.09.008
39. [39]
  S Q Liu, M Q Yang, Y J Xu. J. Mater. Chem. A, 2014, 2:430~440. doi: 10.1039/C3TA13892E
40. [40]
  D A Reddy, J Choi, S Lee et al. RSC Adv., 2015, 5:18342~18351. doi: 10.1039/C4RA16494F
41. [41]
  X H Shi, W Gu, W D Peng et al. ACS Appl. Mater. Int., 2014, 6:2568~2575. doi: 10.1021/am405012k
42. [42]
  X Cui, L Zhu, J Wu et al. Biosens. Bioelectron., 2015, 63:506~512. doi: 10.1016/j.bios.2014.07.085
43. [43]
  Y L Wei, W J Zhou, Y Y Xu et al. RSC Adv., 2014, 4:39082~39086. doi: 10.1039/C4RA05706F
44. [44]
  D Dinda, B K Shaw, S K Saha. ACS Appl. Mater. Int., 2015, 7:14743~14749. doi: 10.1021/acsami.5b02603
45. [45]
  Z S Qian, X Y Shan, L J Chai et al. Biosens. Bioelectron., 2015, 68:225~231. doi: 10.1016/j.bios.2014.12.057
46. [46]
  T V Tam, N B Trung, H R Kim et al. Sensor. Actuat. B, 2014, 202:568~573. doi: 10.1016/j.snb.2014.05.045
47. [47]
  F Z Xu, H Shi, X X He et al. Analyst, 2015, 140:3925~3928. doi: 10.1039/C5AN00468C
48. [48]
  G H Zhou, J B Chang, S M Cui et al. ACS Appl. Mater. Int., 2014, 6:19235~19241. doi: 10.1021/am505275a
49. [49]
  J B Chang, G H Zhou, X F Gao et al. Sensing. Bio-Sensing Res., 2015, 5:97~104. doi: 10.1016/j.sbsr.2015.07.009
50. [50]
  A I Ayesh, Z Karam, F Awwad et al. Sensor. Actuat. B, 2015, 221:201~206. doi: 10.1016/j.snb.2015.06.075
51. [51]
  J W Park, S J Park, O S Kwon et al. Analyst, 2014, 139:3852~3855. doi: 10.1039/C4AN00403E
52. [52]
  C M Willemse, K Tlhomelang, N Jahed et al. Sensors, 2011, 11(4):3970~3987.
53. [53]
  S Lee, S Bong, J Ha et al. Sensor. Actuat. B, 2015, 215:62~69. doi: 10.1016/j.snb.2015.03.032
54. [54]
  N Wang, M Lin, H X Dai et al. Biosens. Bioelectron., 2016, 79:320~326. doi: 10.1016/j.bios.2015.12.056
55. [55]
  S L Ting, S J Ee, A Ananthanarayanan et al. Electrochim. Acta., 2015, 172:7~11. doi: 10.1016/j.electacta.2015.01.026
56. [56]
  M J Lv, X B Wang, J Li et al. Electrochim. Acta, 2013, 108:412~420. doi: 10.1016/j.electacta.2013.06.099
57. [57]
  S Q Xiong, B Y Yang, D Q Cai et al. Electrochim. Acta, 2015, 185:52~61. doi: 10.1016/j.electacta.2015.10.114
58. [58]
  M G Motlagh, M A Taher, A Heydari et al. Mat. Sci. Eng. C-Mater., 2016, 63:367~375. doi: 10.1016/j.msec.2016.03.005
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