Citation: WANG Jian-gang, ZHANG Yun-yun, WANG Yong, ZHU Li-wei, CUI Hong-you, YI Wei-ming. Catalytic fructose dehydration to 5-hydroxymethylfurfural over sulfonated carbons with hierarchically ordered pores[J]. Journal of Fuel Chemistry and Technology, ;2016, 44(11): 1341-1348. shu

Catalytic fructose dehydration to 5-hydroxymethylfurfural over sulfonated carbons with hierarchically ordered pores

WANG Jian-gang ¹ ,
ZHANG Yun-yun ¹ ,
WANG Yong ¹ ,
ZHU Li-wei ¹ ,
CUI Hong-you ^1,*,, ,
YI Wei-ming ^2,*,,

1.
School of Chemical Engineering, Shandong University of Technology, Zibo 255049, China
2.
School of Agricultural Engineering and Food Science, Shandong University of Technology, Zibo 255049, China

Corresponding author: CUI Hong-you, cuihy@sdut.edu.cn YI Wei-ming, yiweiming@sdut.edu.cn
Received Date: 4 July 2016
Revised Date: 26 July 2016

Fund Project: The project was supported by the National Natural Science Foundations of China 21476132The project was supported by the National Natural Science Foundations of China 51536009The project was supported by the National Natural Science Foundations of China 51276103

Figures(7)

Sulfonated carbons with hierarchically ordered pores (SCHOP) were prepared by means of dual template self-assembly, carbonization, HF etching, and sulfonation. The effect of carbonization temperature on microstructure of the prepared carbons as well as the SCHOPs were surveyed at 500-700℃. Using fructose dehydration to 5-hydroxymethylfurfural as a probe reaction, catalytic performance of SCHOPs was examined. The results show that SCHOP-500 carbonized at 500℃ exhibits the highest catalytic activity. SEM and TEM characterization as well as N₂ adsorption desorption show that all of the SCHOPs possess hierarchically ordered macropores and mesopores, but high carbonization temperature damages the regularity of carbon materials slightly. FT-IR, EDS and -SO₃H determination confirm that sulfonic acid group could be successfully introduced to carbon materials by sulfonation. However, high carbonization temperature lowers aromaticity of the carbon materials, and as a result leading to low sulfonation degree. Under the catalysis of SCHOP-500, as high as 93.4% of 5-HMF yield with 96.1% fructose conversion rate is achieved after reacting at 130℃ for 20 min, indicating that SCHOP-500 is a highly effective and efficient solid acid catalyst.
- hierarchically ordered,
- sulfonated carbon,
- fructose,
- 5-HMF,
- porous
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沈阳化工大学材料科学与工程学院沈阳 110142

Catalytic fructose dehydration to 5-hydroxymethylfurfural over sulfonated carbons with hierarchically ordered pores

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

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通讯作者: 陈斌, bchen63@163.com