Citation: CHEN Mao-sen, SONG Hua, LI Feng, CHEN Yan-guang, ZHANG Jian. Effect of preparation method on the structure of rare earth metal Y modified Ni₂P catalysts and its HDS performance[J]. Journal of Fuel Chemistry and Technology, ;2017, 45(2): 213-219. shu

Effect of preparation method on the structure of rare earth metal Y modified Ni₂P catalysts and its HDS performance

CHEN Mao-sen ¹ ,
SONG Hua ^1,2,*,, ,
LI Feng ^1,2 ,
CHEN Yan-guang ^1,2 ,
ZHANG Jian ^1,2

1.
College of Chemistry & Chemical Engineering, Northeast Petroleum University, Daqing 163318, China
2.
Provincial Key Laboratory of Oil & Gas Chemical Technology, Northeast Petroleum University, Daqing 163318, China

Corresponding author: SONG Hua, songhua2004@sina.com
Received Date: 27 September 2016
Revised Date: 7 November 2016

Fund Project: the General Program of Education Department of Heilongjiang Province 12541060the Natural Science Foundation of Heilongjiang Province of China ZD201201National Natural Science Foundation of China 21276048

Figures(5)

The yttrium (Y) modified unsupported Y_x-Ni₂P catalysts were prepared by one step method and stepwise method (x refers to mol ratio of Y to Ni), respectively.The catalysts were characterized by X-ray diffraction (XRD), N₂adsorption specific surface area measurements (BET), CO uptake and X-ray photoelectron spectroscopy (XPS).The effects of preparation methods on thehydrodesulfurization (HDS) property of the catalysts were investigated by using dibenzothiophene (DBT) as the model compound.The results show that the addition of Y can suppress the formation of Ni₅P₄ phase and thus promote the formation of active Ni₂P phase.The addition of Y can dramatically increase the surface area and pore volume, effectively improve the HDS activity of nickel phosphide catalyst.The Y_x-Ni₂P catalysts prepared by these two methods with Y/Ni mol ratio of 0.10 exhibited the highest HDS activity.As compared to the stepwise method, the one step method which obtained catalysts possessed a larger specific surface area with high pore volume, a lower surface P/Ni mol ratio, a larger CO uptake and more exposed active Ni sites as compared to stepwise method.As a result, it showed a higher HDS activity.At a temperature of 340℃, a pressure of 3.0 MPa, a H₂/oil volume ratio of 700 and a weight hourly space velocity (WHSV) of 1.5 h^-1, the conversion of DBT over Y_0.10-Ni₂P catalyst prepared by one step method reached 97.7%, which was an increase of 5.4% comparing with the Y_0.10-Ni₂P catalyst prepared by stepwise method (92.3%).
- one step method,
- stepwise method,
- hydrodesulfurization,
- nickel phosphide,
- yttrium,
- dibenzothiophene
1. [1]
  YU Qi, SONG Hua, SONG Hua-lin, WANG Jian, JIANG Nan, LI Feng, CHEN Yan-guang. Effect of reduction temperature on the performance of Ni₂P/Ti-MCM-41 catalyst in hydrodesulfurization[J]. J Fuel Chem Technol, 2016,44(8):970-976.
2. [2]
  SONG Hua, DAI Min, SONG Hua-lin. Ni₂P catalyst for hydrodesulfurization[J]. Prog Chem, 2012,24(5):43-47.
3. [3]
  WANG X, CLARK P, OYAMA S T. Synthesis, characterization and hydrotreating activity of several iron group transition metal phosphides[J]. J Catal, 2002,208(2):321-331. doi: 10.1006/jcat.2002.3604
4. [4]
  OYAMA S T. Novel catalysts for advanced hydroprocessing:Transition metal phosphides[J]. J Catal, 2003,216(1/2):343-352.
5. [5]
  KORANYI T I, VIT Z, NAGY J B. Support and pretreatment effects on the hydrotreating activity of SBA-15 and CMK-5 supported nickel phosphide catalysts[J]. Catal Today, 2008,130(1):80-85. doi: 10.1016/j.cattod.2007.09.004
6. [6]
  SAWHILL S J, PHILLIPS D C, BUSSELL M E. Thiophene hydrodesulfurization over supported nickel phosphide catalysts[J]. J Catal, 2003,215(2):208-219. doi: 10.1016/S0021-9517(03)00018-6
7. [7]
  ZHAO H Y, OYAMA S T, FREUND H J, WLODARCZYK R, SIERKA M. Nature of active sites in Ni₂P hydrotreating catalysts as probed by iron substitution[J]. Appl Catal B:Environ, 2015,164:204-216. doi: 10.1016/j.apcatb.2014.09.010
8. [8]
  KORANYI T I. Phosphorus promotion of Ni(Co)-containing Mo-free catalysts in thiophene hydrodesulfurization[J]. Appl Catal A:Gen, 2003,239(1/2):253-267.
9. [9]
  HAYAO I, AKIRA O, EITETSU H, SUSUMU T. Rare earth metals as hydrogenation catalysts of unsaturated hydrocarbons[J]. J Catal, 1985,96:139-145. doi: 10.1016/0021-9517(85)90367-7
10. [10]
  MAZZOCCHIA C, GRONCHI P, KADDOURI A, TEMPESTI E, ZANDERIGHI L, KIENNEMANN A. Hydrogenation of CO over Rh/SiO₂-CeO₂ catalysts:Kinetic evidences[J]. J Mol Catal A:Chem, 2001,165(1/2):219-230.
11. [11]
  HUO Xiao-min, LU Qing-jie, SONG wei, SHI Lei. The promoter function of rare earth compounds in catalytic reactions[J]. Chem Online, 2006,69(1)w51.
12. [12]
  PHONTHAMMACHAI N, RUMRUANGWONG M, GULARI E, JAMIESON A M, JITKARNKA S, WONGKASEMJIT S. Synthesis and rheological properties of mesoporous nanocrystalline CeO₂ via sol-gel process[J]. Colloids Surf A, 2004,247:61-68. doi: 10.1016/j.colsurfa.2004.08.030
13. [13]
  WEI Ni, ZENG Peng-hui, JI Sheng-fu, ZHAO Peng-fei, LIU Hui, LI Cheng-yue. Effect of lanthanum promoter on structure and hydrodesulfurization performance of La-Ni₂P/SBA-15 catalysts[J]. J Rare Earths, 2011,29(3):310-315.
14. [14]
  SUN Z C, XIANG L, WANG A J, YAO W, YONG Y C. The effect of CeO₂ on the hydrodenitrogenation performance of bulk Ni₂P[J]. Top Catal, 2012,55(14):1010-1021.
15. [15]
  SONG Hua, ZHANG Fu-yong, XU Xiao-wei, SONG Hua-lin, LI Feng. Effect of Pr and Ce on the activity of Ni₂P catalyst prepared by low temperature reduction in hydrodesulphurization[J]. J Fuel Chem Technol, 2015,43(9):1128-1133.
16. [16]
  SONG H, XU X W, SONG H L, JIANG N, ZHANG F Y. The effect of neodymium content on dibenzothiophene HDS performance over a bulk Ni₂P catalyst[J]. Catal Commun, 2015,63:52-55.
17. [17]
  LAYMAN K A, BUSSELL M E. Infrared spectroscopic investigation of CO adsorption on silica-supported nickel phosphide catalysts[J]. J Phys Chem B, 2004,108(30):10930-10941. doi: 10.1021/jp037101e
18. [18]
  OYAMA S T, WANG X, LEE Y K, BANDO K, REQUEJO F G. Effect of phosphorus content in nickel phosphide catalysts studied by XAFS and other techniques[J]. J Catal, 2002,210(1):207-217. doi: 10.1006/jcat.2002.3681
19. [19]
  CHEN T, YANG B L, LI S S, WANG K L, JIANG X D, ZHANG Y, HE G W. Ni₂P catalysts supported on titania-modified alumina for the hydrodesulfurization of dibenzothiophene[J]. Ind Eng Chem Res, 2011,50:11043-11048. doi: 10.1021/ie201188v
20. [20]
  ELICHE-QUESADA D, MERIDA-ROBLES J, MAIRELES-TORRES P, RODRIGUEZ-CASTELLON E, BUSCA G, FINOCCHIO E, JIMENEZ-LOPEZ A. Effects of preparation method and sulfur poisoning on the hydrogenation and ring opening of tetralin on NiW/zirconium-dopedmesoporous silica catalysts[J]. J Catal, 2003,220(2):457-467. doi: 10.1016/S0021-9517(03)00271-9
21. [21]
  KUHN J N, LAKSHMINARAYANAN N, OZKAN U S. Effect of hydrogen sulfide on the catalytic activity of Ni-YSZ cermets[J]. J Mol Catal A:Chem, 2008,282(1/2):9-21.
22. [22]
  GUO Ya-nan, ZENG Peng-hui, JI Sheng-fu, WEI Ni, LIU Hui, LI Cheng-yue. Effect of Mo promoter content on performance of Mo-Ni₂P/SBA-15/cordierite monolithic catalyst for hydrodesulfurization[J]. Chin J Catal, 2010,31(3):329-334.
23. [23]
  SONG H, WANG J, WANG Z D, SONG H L, LI F, JIN Z S. Effect of titanium content on dibenzothiophene HDS performance over Ni₂P/Ti-MCM-41 catalyst[J]. J Catal, 2014,311:257-265. doi: 10.1016/j.jcat.2013.11.021
24. [24]
  CECILIA J A, INFANTES-MOLINA A, RODRIGUEZ-CASTELLON E, JIMENEZ-LOPEZ A. A novel method for preparing an active nickel phosphide catalyst for HDS of dibenzothiophene[J]. J Catal, 2009,263(1):4-15. doi: 10.1016/j.jcat.2009.02.013
25. [25]
  OYAMA S T, LEE Y K. The active site of nickel phosphide catalysts for the hydrodesulfurization of 4,6-DMDBT[J]. J Catal, 2008,258(2):393-400. doi: 10.1016/j.jcat.2008.06.023
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Effect of preparation method on the structure of rare earth metal Y modified Ni2P catalysts and its HDS performance

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通讯作者: 陈斌, bchen63@163.com

Effect of preparation method on the structure of rare earth metal Y modified Ni₂P catalysts and its HDS performance