Citation: YU Jie, WANG Jing-yun, WANG Zhen, ZHOU Ming-dong, WANG Hai-yan. Synthesis of composite zeolites and their performance in hydrolysis of cellulose[J]. Journal of Fuel Chemistry and Technology, ;2018, 46(4): 419-426. shu

Synthesis of composite zeolites and their performance in hydrolysis of cellulose

YU Jie ^1,2,3 ,
WANG Jing-yun ² ,
WANG Zhen ² ,
ZHOU Ming-dong ^2,, ,
WANG Hai-yan ^1,2,,

1.
College of Chemical Engineering, China University of Petroleum, Qingdao 266580, China
2.
School of Chemistry and Materials Science, Liaoning Shihua University, Fushun 113001, China
3.
Shenyang Paraffin Chemical Co Ltd, Shenyang 110141, China

Corresponding author: ZHOU Ming-dong, mingdong.zhou@lnpu.edu.cn WANG Hai-yan, haiyan.wang@lnpu.edu.cn
Received Date: 25 December 2017
Revised Date: 26 February 2018

Fund Project: Talent Scientific Research Fund of LSHU 2016XJJ-063Natural Science Foundation of Liaoning Province 2015020196the National Science Foundation of China 21101085Natural Science Foundation of Liaoning Province 20170540590The project was supported by the National Science Foundation of China (21101085), Natural Science Foundation of Liaoning Province (2015020196, 20170540590), the Fushun Science & Technology Program (FSKJHT 201423), the Liaoning Excellent Talents Program in University (LJQ2012031), Talent Scientific Research Fund of LSHU (2016XJJ-063)the Fushun Science & Technology Program FSKJHT 201423the Liaoning Excellent Talents Program in University LJQ2012031

Figures(7)

In this paper, core-shell composite zeolites (HUSY@MFI) were prepared by hydrothermal method. The composite zeolites were characterized by XRD, SEM, N₂-adsorption, NH₃-TPD and Py-FTIR. The results indicated that HUSY@MFI has both HUSY and MFI structure. Scanning Electron Microscope (SEM) reflects a core-shell morphology of HUSY@MFI. The particles displayed an elliptical sphere structure with scale-like surface. The growth of MFI shell results in a decrease of external acid density and the total acid sites. When the HUSY@MFI was used as catalyst instead of HUSY in hydrolysis of cellulose to glucose in 1-ethyl-3-methylimidazolium chloride ([Emim]Cl), the glucose yield could be significantly improved from 30.9% to 41.3%.
- HUSY@MFI,
- HUSY,
- cellulose,
- hydrolysis,
- glucose
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