Citation: Yin Jianghui, Xu Ya, Xiang Yunjie, Zhang Dengqing, Li Xianying, Jin Wusong. Syntheses of Rectangle Type Polycyclic Aromatic Hydrocarbons[J]. Chemistry, ;2017, 80(8): 772-776. shu

Syntheses of Rectangle Type Polycyclic Aromatic Hydrocarbons

1.
College of Chemistry, Chemical Engineering and Biotechnology, Donghua University, Shanghai 201620
2.
College of Environmental Science and Engineering, Donghua University, Shanghai 201620

Corresponding author: Jin Wusong, wsjin@dhu.edu.cn
Received Date: 16 January 2017
Accepted Date: 18 April 2017

Figures(6)

1, 2, 4, 5-tetraphenyl-3, 6-di(3, 5-dibromophenyl)benzene (6a) was synthesized by Diels-Alder cycloaddition reaction of 2, 5-bis(3, 5-dibromophenyl)-3, 4-diphenylcyclopenta-2, 4-dienone (4a) with 1, 2-diphenylethyne (5a). 1, 2, 4, 5-tetraphenyl-3, 6-di(3, 5-di(4-dodecylthiophene))phenylbenzene (8a) was obtained from 6a by classical Suzuki coupling reaction, then the target compound 1a was obtained for 8a by Scholl cyclodehydrogenation using FeCl₃ as catalyst. The similar synthesis method was used to obtain the target compound 1b. The structures of these compounds were characterized by ¹H NMR and MALDI-TOF MS, and their spectral characteristics, thermal and electrical properties were investigated.
- Rectangle type,
- Polycyclic aromatic hydrocarbon,
- Scholl cyclodehydrogenation,
- Thiophene
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沈阳化工大学材料科学与工程学院沈阳 110142