Citation: Hou Junjun, Li Lianshan, Huang Jin, Tang Zhiyong. Progress in the Syntheses of Covalent Organic Frameworks and Their Applications in Separation[J]. Chemistry, ;2019, 82(3): 195-201. shu

Progress in the Syntheses of Covalent Organic Frameworks and Their Applications in Separation

Hou Junjun ^1,3 ,
Li Lianshan ^3,, ,
Huang Jin ^1,2,, ,
Tang Zhiyong ³

1.
School of Chemistry, Chemical Engineering and Life Sciences, Wuhan University of Technology, Wuhan 430070
2.
School of Chemistry and Chemical Engineering, Southwest University, Chongqing 400715
3.
CAS Key Laboratory of Nanosystem and Hierarchical Fabrication, CAS Center for Excellence in Nanoscience, National Center for Nanoscienceand Technology, Beijing 100190

Corresponding author: Li Lianshan, lils@nanoctr.cn Huang Jin, huangjin2015@swu.edu.cn
Received Date: 31 October 2018
Accepted Date: 6 December 2018

Figures(3)

Covalent organic frameworks (COFs) are crystalline porous polymers formed by covalent bonding of small organic molecules. Unlike typical linear polymers, COFs offer fine control over their skeletons in two and three dimensions, which enables the synthesis of rigid porous structures with high regularity and tunable chemical and physical properties. The nanoscale channels and voids in COFs provide an ideal environment for molecular storage, release and separation, endowing them great potential in energy adsorption, separation, and catalysis. This article reviews the progress in COFs, including the synthesis strategies, the applications in separation field as well as outlook of their future developments.
- Covalent organic frameworks,
- Synthesis,
- Separations,
- Porous materials
1. [1]
  X Feng, X Ding, D Jiang. Chem. Soc. Rev., 2012, 41 (18):6010~6022.
2. [2]
  N Huang, P Wang, D Jiang. Nat. Rev. Mater., 2016, 1 (10):16068.
3. [3]
  J L Segura, M J Mancheno, F Zamora. Chem. Soc. Rev., 2016, 45 (20):5635~5671.
4. [4]
  M S Lohse, T Bein. Adv. Funct. Mater., 2018, 28 (33):1705553.
5. [5]
  A P Cote, A I Benin, N W Ockwig et al. Science, 2005, 310 (5751):1166~1170.
6. [6]
  H Furukawa, O M Yaghi. J. Am. Chem. Soc., 2009, 131 (25):8875~8883.
7. [7]
  J F Dienstmaier, D D Medina, M Dogru et al. ACS Nano, 2012, 6 (8):7234~7242.
8. [8]
  C Z Guan, D Wang, L J Wan. Chem. Commun., 2012, 48 (24):2943~2945.
9. [9]
  S Spitzer, A R Lahrood, K Macknapp et al. Chem. Commun., 2017, 53 (37):5147~5150.
10. [10]
  R W Tilford, S J Mugavero, P J Pellechia et al. Adv. Mater., 2008, 20 (14):2741~2746.
11. [11]
  G H Bertrand, V K Michaelis, T C Ong et al. PNAS, 2013, 110 (13):4923~4928.
12. [12]
  F J Uribe-Romo, J R Hunt, H Furukawa et al. J. Am. Chem. Soc., 2009, 131 (13):4570~4571.
13. [13]
  S Wan, F Gándara, A Asano et al. Chem. Mater., 2011, 23 (18):4094~4097.
14. [14]
  Y B Zhang, J Su, H Furukawa et al. J. Am. Chem. Soc., 2013, 135 (44):16336~16339.
15. [15]
  S Kandambeth, A Mallick, B Lukose et al. J. Am. Chem. Soc., 2012, 134 (48):19524~19527.
16. [16]
  S Kandambeth, D B Shinde, M K Panda et al. Angew. Chem. Int. Ed., 2013, 52 (49):13052~13056.
17. [17]
  X Chen, M Addicoat, E Jin et al. J. Am. Chem. Soc., 2015, 137 (9):3241~3247.
18. [18]
  H S Xu, S Y Ding, W K An et al. J. Am. Chem. Soc., 2016, 138 (36):11489~11492.
19. [19]
  P Kuhn, M Antonietti, A Thomas. Angew. Chem. Int. Ed., 2008, 47 (18):3450~3453.
20. [20]
  M J Bojdys, J Jeromenok, A Thomas et al. Adv. Mater., 2010, 22 (19):2202~2205.
21. [21]
  S Ren, M J Bojdys, R Dawson et al. Adv. Mater., 2012, 24 (17):2357~2361.
22. [22]
  X Zhu, C Tian, S M Mahurin et al. J. Am. Chem. Soc., 2012, 134 (25):10478~10484.
23. [23]
  F J Uribe-Romo, C J Doonan, H Furukawa et al. J. Am. Chem. Soc., 2011, 133 (30):11478~11481.
24. [24]
  G Das, D B Shinde, S Kandambeth et al. Chem. Commun., 2014, 50 (84):12615~12618.
25. [25]
  S Dalapati, S Jin, J Gao et al. J. Am. Chem. Soc., 2013, 135 (46):17310~17313.
26. [26]
  S B Alahakoon, C M Thompson, A X Nguyen et al. Chem. Commun., 2016, 52 (13):2843~2845.
27. [27]
  Q Fang, Z Zhuang, S Gu et al. Nat. Commun., 2014, 5:4503.
28. [28]
  Y Zeng, R Zou, Z Luo et al. J. Am. Chem. Soc., 2015, 137 (3):1020~1023.
29. [29]
  B Zhang, M Wei, H Mao et al. J. Am. Chem. Soc., 2018, 140 (40):12715~12719.
30. [30]
  M G Rabbani, A K Sekizkardes, Z Kahveci et al. Chem. Eur. J., 2013, 19 (10):3324~3328.
31. [31]
  Z Li, X Feng, Y Zou et al. Chem. Commun., 2014, 50 (89):13825~13828.
32. [32]
  Z Li, Y Zhi, X Feng et al. Chem. Eur. J., 2015, 21 (34):12079~12084.
33. [33]
  D Cao, J Lan, W Wang et al. Angew. Chem. Int. Ed., 2009, 48 (26):4730~4733.
34. [34]
  Y Li, R T Yang. AIChE J., 2008, 54 (1):269~279.
35. [35]
  J Dong, Y Wang, G Liu et al. CrystEngComm., 2017, 19 (33):4899~4904.
36. [36]
  M S Lohse, T Stassin, G Naudin et al. Chem. Mater., 2016, 28 (2):626~631.
37. [37]
  X Zhu, S An, Y Liu et al. AIChE J., 2017, 63 (8):3470~3478.
38. [38]
  S Kandambeth, B P Biswal, H D Chaudhari et al. Adv. Mater., 2017, 29 (2):1603945.
39. [39]
  K Dey, M Pal, K C Rout et al. J. Am. Chem. Soc., 2017, 139 (37):13083~13091.
40. [40]
  N Huang, L Zhai, H Xu et al. J. Am. Chem. Soc., 2017, 139 (6):2428~2434.
41. [41]
  Q Sun, B Aguila, J Perman et al. J. Am. Chem. Soc., 2017, 139 (7):2786~2793.
42. [42]
  Z Li, H Li, X Guan et al. J. Am. Chem. Soc., 2017, 139 (49):17771~17774.
43. [43]
  H Wang, F Jiao, F Gao et al. Talanta, 2017, 166:133~140.
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