Citation: WANG Hai-yan, GUAN Zong-chi, KANG Lei, HAO Ming-yang. Study on adsorption desulfurization performance of porous microsphere nickel zinc composite adsorbent[J]. Journal of Fuel Chemistry and Technology, ;2017, 45(10): 1236-1243. shu

Study on adsorption desulfurization performance of porous microsphere nickel zinc composite adsorbent

Liaoning Shihua University, Fushun 113001, China

Corresponding author: WANG Hai-yan, fswhy@126.com
Received Date: 10 May 2017
Revised Date: 3 August 2017

Figures(8)

The effects of glucose on the morphology of the microspheres of zinc oxide were first studied, and then 5% NiO/ZnO microspheric adsorbents were prepared by impregnation method and hydrothermal synthesis. The morphology and structure of NiO/ZnO microspheres were analyzed by N₂ adsorption, scanning electron microscopy (SEM), X-ray diffraction (XRD) methods, and the effects of the preparation method of NiO/ZnO microspheric adsorbents on the physicochemical properties were examined. Furthermore, Ni/ZnO microsphere adsorbent was prepared by reduction with H₂, over which the performance of adsorption desulfurization was tested in a fixed bed reactor by using thiophene as the sulfur compounds in model gasoline.The results show that the specific surface area and pore volume of the NiO-ZnO microspheric adsorbents prepared by hydrothermal method are as high as 40.45 m²/g and 0.096 cm³/g, respectively, in contrast to the ones prepared by the impregnation method, and the composite Ni-ZnO microspheric adsorbents exhibit a favorable desulfurization activity. Under the conditions including a temperature of 350℃, a pressure of 1.0 MPa, a volume space velocity of 6 h^-1, and a hydrogen to simulated oil volume ratio of 60, the sulphur contents in simulated oil decrease from 1.5×10^-4 to less than 10^-5. Also, the adsorbents boast a good regeneration capacity and a potential application value in industry.
- composites,
- microsphere,
- adsorbent,
- adsorption desulfurization,
- zincoxide,
- mesoporous structure
1. [1]
  BABICH I V, MOULIJN J A. Science and technology of novel processes for deep desulfurization of oil refinery streams:a review[J]. Fuel, 2003,82(6):607-631. doi: 10.1016/S0016-2361(02)00324-1
2. [2]
  BEALE A M, GIBSON E K, O'BRIEN M G, JACQUES S D M. Chemical imaging of the sulfur-induced deactivation of Cu/ZnO catalyst bodies[J]. J Catal, 2014,314(20):94-100.
3. [3]
  BABE C, TAYAKOUT-FAYOLLE M, GEANTET C, VRINAT M, BERGERET G, HUARD T, BAZER-BACHI D. Crystallite size effect in the sulfidation of ZnO by H₂S:Geometric and kinetic modelling of the transformation[J]. Chem Eng Sci, 2012,82:73-83. doi: 10.1016/j.ces.2012.07.026
4. [4]
  HE W, LI Y, CHEN Z, W YANG, ZHANG R. One-step solution synthesis of monodispersed ZnO nanowhiskers at low-temperature[J]. Mater Lett, 2006,60(s17-18):2299-2301.
5. [5]
  FANG Z, TANG K, SHEN G, CHEN D, KONG R. Self-assembled ZnO 3D flowerlike nanostructures[J]. Mater Lett, 2006,60(20):2530-2533. doi: 10.1016/j.matlet.2006.01.034
6. [6]
  YANG Y, YAN H, FU Z, YANG B, ZUO J. Enhanced photoluminescence from three-dimensional ZnO photonic crystals[J]. Sol St Comm, 2006,139(5):218-221. doi: 10.1016/j.ssc.2006.06.003
7. [7]
  YU J, YU X. Hydrothermal synthesis and photocatalytic activity of zinc oxide hollow spheres[J]. Environ Sci Technol, 2008,42(13):4902-7. doi: 10.1021/es800036n
8. [8]
  GUO Ting-ting, LIU Yan-ping, YE Ling-juan, LIU Dong. Synthesis and characterization of monodispersed ZnO microsphere[J]. Sci Technol Eng, 2011(25):6141-6144. doi: 10.3969/j.issn.1671-1815.2011.25.032
9. [9]
  KUANG Q, JIANG Z Y, XIE Z X. LIN S C. Tailoring the optical property by a three-dimensional epitaxial heterostructure:a case of ZnO/SnO₂[J]. J Am Chem Soc, 2005,127(33):11777-84. doi: 10.1021/ja052259t
10. [10]
  ZHAO A, LUO T, CHEN L, LIU Y, LI X G. T G. Synthesis of ordered ZnO nanorods film on zinc-coated Si substrate and their photoluminescence property[J]. Mater Chem Phy, 2006,99(1):50-53. doi: 10.1016/j.matchemphys.2005.10.013
11. [11]
  VAFAEE M, GHAMSARI M S. Preparation and characterization of ZnO nanoparticles by a novel sol-gel route[J]. Mater Lett, 2007,61(14/15):3265-3268.
12. [12]
  SUN X M, LIU J F, LI Y D. Use of carbonaceous polysaccharide microspheres as templates for fabricating metal oxide hollow spheres[J]. Chem Eur J, 2006,12:2039-20477. doi: 10.1002/(ISSN)1521-3765
13. [13]
  JING Mao-xiang. Study on New Technology, Structure and Properties of Alumina/Nickel Composites[D]. Jiangsu University, 2007.
14. [14]
  LI W J, SHI E W, ZHONG W Z, YIN Z W. Growth mechanism and growth habit of oxide crystals[J]. J. Cryst Growth, 1999,203(1/2):186-196.
15. [15]
  SONG P, WANG Q, YANG Z. Acetone sensing characteristics of ZnO hollow spheres prepared by one-pot hydrothermal reaction[J]. Mater Lett, 2012,86(11):168-170.
16. [16]
  XU Zhi-bing, YAN Jia-ping, WU Liang. Preparation and photocatalytic activity of zinc oxide hollow spheres[J]. J Synth Cryst, 2012,41(6):1722-1725.
17. [17]
  DENG Wen-ya, ZHAO Zong-bin, SHEN Lin, QIU Jie-shan. Preparation and photoluminescence characteristics of zinc oxide hollow spheres[J]. Fun Mat, 2007,38(9):1559-1562.
18. [18]
  ROUQUEROL F, ROUQUEML J, SING K. Adsorption by Powders and Porous Solides:Principles Methodology And Applications, Academic Press:Harcourt Brace & Company, 1999.
19. [19]
  Jing Z H, Zhan J H. Fabrication and gas-sensing properties of porous ZnO nanoplates[J]. Ad Mat, 2008,20:4547-4551. doi: 10.1002/adma.v20:23
20. [20]
  Xu L, Huang W Q, Wang L L, Tian Z A, Hu W Y. Insights into enhanced visible-light photocatalytic hydrogen evolution of g-C₃N₄ and highly reduced graphene oxide composite:The role of oxygen[J]. Chem Mat, 2015,27(5).
21. [21]
  Lai Li-fang, Yang Qian, JI Yun-zhaou, Wang Li-juan, Rong Hong-ren. Preparation and photocatalytic performance of irregular ZnO nanorods[J]. Chem Res Application, 2012,24(6):866-872.
22. [22]
  ZHOU Guang-lin, SUN Wen-yan, JIANG Wei-li. Deep hydrogen adsorption desulfurization of hydrogenated gasoline on Ni/ZnO-SiO₂-Al₂O₃ adsorbent[J]. Petroleum Process Petrochemicals, 2013,44(7):17-21.
23. [23]
  JIRATOVA K, JANACEK L. Effect of peptizing on the physical and chemical properties of extruded alumina[J]. Int Chem Eng, 1983,23(1):167-174.
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