Citation: Niu Jing, Jia Zijian, Sun Wanqi, Zhang Ning. Colorimetric Detection of Ascorbic Acid Based on Co²⁺-mediated Signal Transformation[J]. Chemistry, ;2020, 83(10): 923-928. shu

Colorimetric Detection of Ascorbic Acid Based on Co²⁺-mediated Signal Transformation

Niu Jing ¹ ,
Jia Zijian ² ,
Sun Wanqi ¹ ,
Zhang Ning ^1,,

1.
College of Chemistry and Pharmaceutical Engineering, HuangHuai University, Zhumadian, 463000
2.
Henan Huanghuai Testing Technology Co., Ltd., Zhumadian, 463000

Corresponding author: Zhang Ning, 454555096@qq.com
Received Date: 25 March 2020
Accepted Date: 30 April 2020

Figures(6)

Ascorbic acid (AA) is a significant small biomolecule involved in many biochemical processes. Profiting from the oxidizability of cobalt oxyhydroxide nanoflakes(CNFs) and strong chelating interactions between Co²⁺ and SCN^-, a novel colorimetric assay of AA was reported based on the Co²⁺-mediated signal transformation. In the presence of AA, CNFs were reduced into Co²⁺, then strongly chelated with SCN^- to form a stable blueish anion complex ([Co(NCS)₄]^2-), resulting in a visible absorption signal at 625nm. Under the optimal conditions, the maximum absorbance was linear with AA concentration from 0.03 to 0.45 mmol/L. The regression equation is A_625nm=0.638c(mmol/L) +0.042 with a correlation coefficient of 0.993 and a limit of detection of 1.5 μmol/L (3S/N).
- Cobalt oxyhydroxide,
- Co²⁺-mediated Signal Transformation,
- Colorimetric assay,
- Ascorbic acid
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Colorimetric Detection of Ascorbic Acid Based on Co2+-mediated Signal Transformation

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通讯作者: 陈斌, bchen63@163.com

Colorimetric Detection of Ascorbic Acid Based on Co²⁺-mediated Signal Transformation