Citation: Ke Wu YANG, Xuan Zhen JIANG, Wei Chao ZHANGD. One-step Synthesis of n-Butanol from Ethanol Condensation over Alumina-supported Metal Catalysts[J]. Chinese Chemical Letters, ;2004, 15(12): 1497-1480. shu

One-step Synthesis of n-Butanol from Ethanol Condensation over Alumina-supported Metal Catalysts

Department of Chemistry, Zhejiang University, HangZhou 310027

Received Date: 20 October 2003

One-step synthesis of n-butanol from bimolecular condensation of ethanol was firstly achieved over nickel supported gamma alumina catalyst. A mechanism of dehydration path for the growth of carbon chain by eliminating a hydroxy group from one ethanol molecule with a α-H of other ethanol molecule rather than aldol condensation was verified.
- Ethanol condensation,
- n-butanol,
- nickel supported on gamma alumina,
- dehydration
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