Citation: XIAO Zhu-qian, SHA Ru-yi, JI Jian-bing, MAO Jian-wei. Mordenite supported Ni-W self-reducing bifunctional catalyst for cellulose hydrogenolysis into ethylene glycol[J]. Journal of Fuel Chemistry and Technology, ;2016, 44(10): 1225-1232. shu

Mordenite supported Ni-W self-reducing bifunctional catalyst for cellulose hydrogenolysis into ethylene glycol

XIAO Zhu-qian ^1,2,3,4 ,
SHA Ru-yi ^1,2,3,*,, ,
JI Jian-bing ⁴ ,
MAO Jian-wei ^1,2,3

1.
School of Biological and Chemical Engineering, Zhejiang University of Science & Technology, Hangzhou 310023, China
2.
Zhejiang Provincial Key Laboratory of Chemical and Biological Processing Technology of Farm Products, Hangzhou 310023, China
3.
Collaborative Innovation Center of Agricultural Biological Resources Biochemical Manufacturing of Zhejiang Province, Hangzhou 310023, China
4.
College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China

Corresponding author: SHA Ru-yi, zjhzxzq@yeah.net
Received Date: 6 June 2016
Revised Date: 10 July 2016

Figures(6)

Based on the reducing gases (H₂ and CO) generated from biomass-based carbon at high clacination temperature, self-reducing bifunctional catalyst Ni-W/MOR was prepared by incipient impregnation. This series of catalysts were directly applied to cellulose hydrogenolysis to low carbon polyols in aqueous solution, omitting the catalysts reduction step. The effects of catalysts temperature of the catalyst and weight ratio of active components on conversion of cellulose and yield of target products were investigated. The optimal calcination temperature was 773 K through experimental results. XRD analysis showed that the crystallinity and species of metallic alloys were related to different weight ratios of nickel and tungsten. It was intuitively observed that the active metals showed good dispersion on the surface of MOR through TEM characterization, with particles sizes less than 20 nm. The total yield of low carbon polyols was up to 56.92%, including 52.30% of EG under the reaction condition of 5.0 MPa of H₂ for 2 h reaction time and the calcination temperature of catalysts was 773 K.
- mordenite,
- self-reducing catalysts,
- sugar polyols,
- hydrogenolysis,
- ethylene glycol
1. [1]
  ROSELINDE O, MICHIEL D, JAN A G, BEAU O B, RICK V, ELENA G, JOHAN A M, ANDREAS R, BERT F S. Conversion of sugar to ethylene glycol with nickel tungsten carbide in a fed-batch reactor:High productivity and reaction network elucidation[J]. Green Chem, 2014,16(2):695-707. doi: 10.1039/C3GC41431K
2. [2]
  BEAK I G, YOU S J, PARK E D. Direct conversion of cellulose into polyols over Ni/W/SiO₂-Al₂O₃[J]. Bioresouce Technol, 2012,114:684-690. doi: 10.1016/j.biortech.2012.03.059
3. [3]
  FUKUOKA A, DHEPE P L. Catalytic conversion of cellulose into sugar alcohols[J]. Angew Chem Int Ed, 2006(31):5161-5163.
4. [4]
  LUO C, WANG S, LIU H. Cellulose conversion into polyols catalyzed by reversibly formed acids and supported Ruthenium clusters in hot water[J]. Angew Chem Int Ed, 2007,46(40):7636-7639. doi: 10.1002/(ISSN)1521-3773
5. [5]
  DENG W P, TAN X, FANG W, ZHANG Q, WANG Y. Converison of cellulose into sorbitol over carbon nanotube-supported Ruthenium catalyst[J]. Catal Lett, 2009,133:167-174. doi: 10.1007/s10562-009-0136-3
6. [6]
  NIU Y F, WANG H, ZHU X L, SONG Z Q, XIE X N, LIU X, HAN J Y, GE Q F. Ru supported on zirconia-modified SBA-15 for selective converison of cellulose to hexitol[J]. Microporous Mesoporous Mater, 2014,198:215-222. doi: 10.1016/j.micromeso.2014.07.030
7. [7]
  YOU S J, BEAK I G, KIM Y T, JEONG K E, CHAE H J, KIM T W, KIM C U, KIM T J, CHUNG Y M, OH S H, PARK E D. Direct converison of cellulose into polyols or H₂ over Pt/Na (H)-ZSM-5[J]. Korean J Chem Eng, 2011,28(3):744-750. doi: 10.1007/s11814-011-0019-3
8. [8]
  Sun J Y, LIU H C. Selective hydrogenolysis of biomass-derived xylitol to ethylene glycol and propylene glycol on Ni/C and basic oxide-promoted Ni/C catalysts[J]. Catal Today, 2014,234:75-82. doi: 10.1016/j.cattod.2013.12.040
9. [9]
  KATERINA F, OLIVER M, MARTIN L, PETER C. Hydrogenolysis of cellulose to valuable chemicals over actived carbon supported mono-and bimetallic nickel/tungsten catalysts[J]. Green Chem, 2014,16:3580-3588. doi: 10.1039/C4GC00664J
10. [10]
  WANG A Q, ZHANG T. One-pot conversion of cellulose to ethylene glycol with multifunctional tungsten-based catalysts[J]. Accounts Chem Res, 2013,46(7):1377-1386. doi: 10.1021/ar3002156
11. [11]
  ZHAO M, CHUECH T L, HARRIS A T. SBA-15 supported Ni-Co bimetallic catalysts for enhanced hydrogen production during cellulose decomposition[J]. Appl Catal B:Environ, 2011,101(3/4):522-530.
12. [12]
  JI N, ZHENG M Y, WANG A Q, ZHANG T, CHEN J G. Nickel-promoted tungsten carbide catalysts for cellulose conversion:effect of preparation methods[J]. ChemSusChem, 2012,5(5):939-944. doi: 10.1002/cssc.201100575
13. [13]
  ZHENG M Y, WANG A Q, JI N, PANG J F, WANG X D, ZHANG T. Transition metal-tungsten bimetallic catalysts for the conversion of cellulose into ethylene glycol[J]. ChemSusChem, 2010,3:63-66. doi: 10.1002/cssc.v3:1
14. [14]
  ZHAO Guan-hong, ZHENG Min-yuan, WANG Ai-qin, ZHANG Tao. Catalytic conversion of cellulose to ethylene glycol over tungsten phosphide catalysts[J]. Chin J Catal, 2010,31(8):928-932. doi: 10.1016/S1872-2067(10)60104-0
15. [15]
  KITCHIN J R, NORSKOV J K, BARTEAU M A, CHEN J G. Modification of the surface electronic and chemical properties of Pt (111) by subsurface 3d transition metals[J]. J Chem Phys, 2004,120(21):10240-10246. doi: 10.1063/1.1737365
16. [16]
  CHEN J G, MENNING C A, ZELLNER M B. Monolayer bimetallic surfaces:Experimental and theoretical studies of trends in electronic and chemical properties[J]. Surf Sci Pep, 2008,63(5):201-254.
1. [1]
  Yiling Wu , Peiyao Jin , Shenyue Tian , Ji Zhang . The Star of Sugar Substitutes: An Interview of Erythritol. University Chemistry, 2024, 39(9): 22-27. doi: 10.12461/PKU.DXHX202404034
2. [2]
  Xinhao Yan , Guoliang Hu , Ruixi Chen , Hongyu Liu , Qizhi Yao , Jiao Li , Lingling Li . Polyethylene Glycol-Ammonium Sulfate-Nitroso R Salt System for the Separation of Cobalt (II). University Chemistry, 2024, 39(6): 287-294. doi: 10.3866/PKU.DXHX202310073
3. [3]
  Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH₂ supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317
4. [4]
  Hailian Tang , Siyuan Chen , Qiaoyun Liu , Guoyi Bai , Botao Qiao , Fei Liu . Stabilized Rh/hydroxyapatite Catalyst for Furfuryl Alcohol Hydrogenation: Application of Oxidative Strong Metal-Support Interactions in Reducing Conditions. Acta Physico-Chimica Sinica, 2025, 41(4): 100036-. doi: 10.3866/PKU.WHXB202408004
5. [5]
  Zhuoming Liang , Ming Chen , Zhiwen Zheng , Kai Chen . Multidimensional Studies on Ketone-Enol Tautomerism of 1,3-Diketones By ¹H NMR. University Chemistry, 2024, 39(7): 361-367. doi: 10.3866/PKU.DXHX202311029
6. [6]
  Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028
7. [7]
  Jiali CHEN , Guoxiang ZHAO , Yayu YAN , Wanting XIA , Qiaohong LI , Jian ZHANG . Machine learning exploring the adsorption of electronic gases on zeolite molecular sieves. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 155-164. doi: 10.11862/CJIC.20240408
8. [8]
  Aili Feng , Xin Lu , Peng Liu , Dongju Zhang . Computational Chemistry Study of Acid-Catalyzed Esterification Reactions between Carboxylic Acids and Alcohols. University Chemistry, 2025, 40(3): 92-99. doi: 10.12461/PKU.DXHX202405072
9. [9]
  Yufang GAO , Nan HOU , Yaning LIANG , Ning LI , Yanting ZHANG , Zelong LI , Xiaofeng LI . Nano-thin layer MCM-22 zeolite: Synthesis and catalytic properties of trimethylbenzene isomerization reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1079-1087. doi: 10.11862/CJIC.20240036
10. [10]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201
11. [11]
  Yifeng TAN , Ping CAO , Kai MA , Jingtong LI , Yuheng WANG . Synthesis of pentaerythritol tetra(2-ethylthylhexoate) catalyzed by h-MoO₃/SiO₂. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2155-2162. doi: 10.11862/CJIC.20240147
12. [12]
  Xuejie Wang , Guoqing Cui , Congkai Wang , Yang Yang , Guiyuan Jiang , Chunming Xu . 碳基催化剂催化有机液体氢载体脱氢研究进展. Acta Physico-Chimica Sinica, 2025, 41(5): 100044-. doi: 10.1016/j.actphy.2024.100044
13. [13]
  Haodong JIN , Qingqing LIU , Chaoyang SHI , Danyang WEI , Jie YU , Xuhui XU , Mingli XU . NiCu/ZnO heterostructure photothermal electrocatalyst for efficient hydrogen evolution reaction. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1068-1082. doi: 10.11862/CJIC.20250048
14. [14]
  Juan WANG , Zhongqiu WANG , Qin SHANG , Guohong WANG , Jinmao LI . NiS and Pt as dual co-catalysts for the enhanced photocatalytic H₂ production activity of BaTiO₃ nanofibers. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1719-1730. doi: 10.11862/CJIC.20240102
15. [15]
  Juntao Yan , Liang Wei . 2D S-Scheme Heterojunction Photocatalyst. Acta Physico-Chimica Sinica, 2024, 40(10): 2312024-. doi: 10.3866/PKU.WHXB202312024
16. [16]
  Jun Huang , Pengfei Nie , Yongchao Lu , Jiayang Li , Yiwen Wang , Jianyun Liu . 丝光沸石负载自支撑氮掺杂多孔碳纳米纤维电容器及高效选择性去除硬度离子. Acta Physico-Chimica Sinica, 2025, 41(7): 100066-. doi: 10.1016/j.actphy.2025.100066
17. [17]
  Asif Hassan Raza , Shumail Farhan , Zhixian Yu , Yan Wu . 用于高效制氢的双S型ZnS/ZnO/CdS异质结构光催化剂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406020-. doi: 10.3866/PKU.WHXB202406020
18. [18]
  Shuang Yang , Qun Wang , Caiqin Miao , Ziqi Geng , Xinran Li , Yang Li , Xiaohong Wu . Ideological and Political Education Design for Research-Oriented Experimental Course of Highly Efficient Hydrogen Production from Water Electrolysis in Aerospace Perspective. University Chemistry, 2024, 39(11): 269-277. doi: 10.12461/PKU.DXHX202403044
19. [19]
  Xue Liu , Lipeng Wang , Luling Li , Kai Wang , Wenju Liu , Biao Hu , Daofan Cao , Fenghao Jiang , Junguo Li , Ke Liu . Cu基和Pt基甲醇水蒸气重整制氢催化剂研究进展. Acta Physico-Chimica Sinica, 2025, 41(5): 100049-. doi: 10.1016/j.actphy.2025.100049
20. [20]
  Yuhao SUN , Qingzhe DONG , Lei ZHAO , Xiaodan JIANG , Hailing GUO , Xianglong MENG , Yongmei GUO . Synthesis and antibacterial properties of silver-loaded sod-based zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 761-770. doi: 10.11862/CJIC.20230169

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(948)
HTML views(147)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142