Citation: Ke Jian DENG, Fei HUANG, Duo Yuan WANG, Zheng He PENG, Yun Hong ZHOU. Green Oxygenation Degradation of Rhodamine B by Using Activated Molecule Oxygen[J]. Chinese Chemical Letters, ;2004, 15(10): 1223-1226. shu

Green Oxygenation Degradation of Rhodamine B by Using Activated Molecule Oxygen

1.
Department of Chemistry, Wuhan University, Wuhan 430072;
2.
College of Chemistry and Life Science, South-Central University of Nationalities, Wuhan 430074

Received Date: 25 August 2003

Fund Project: The work was supported by the NNSFC (No.29771025) and (No.20377053) and The Nine-five National Key Project of China (29833090) and The Hubei Province Foundation of China (No.2003AB A071).

Iron(Ⅱ) tetra-(1,4-dithin)-porphyrazine, (FePz(dtn)₄) is able to activate molecule oxygen for oxygenation degradation of rhodamine B (RhB) in an extensive pH region without light excitation. Experiments indicate that the RhB can be degraded nearly 52% in alkaline aqueous solution, bubbling with dioxygen for seven hours in the presence of FePz(dtn)₄ and the hydrogen peroxides as an actve intermediate were determined by DPD method. The catalyst is recyclable and the catalyst activity was maintained after l0 recycles.
- Activation of molecule oxygen,
- iron (Ⅱ) tetra (1,4-dithin) porphyrazine,
- oxidative degradation of pollutants,
- rhodamine B
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14. [14]
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