Citation: Bi Haoyu, Li Yan, Zhou Dan, Zhang Ya, Gao Huizhi, Yang Weiwei. Preparation of Fe₃O₄@Hydrotalcite-like Compound and Its Adsorption Capacity for Methyl Orange[J]. Chemistry, ;2018, 81(2): 175-181. shu

Preparation of Fe₃O₄@Hydrotalcite-like Compound and Its Adsorption Capacity for Methyl Orange

Bi Haoyu ¹ ,
Li Yan ^2,, ,
Zhou Dan ² ,
Zhang Ya ² ,
Gao Huizhi ² ,
Yang Weiwei ²

1.
Department of Biomedical Engineering, Changzhi Medical College, Changzhi 046011
2.
Department of Chemistry, Changzhi University, Changzhi 046011

Corresponding author: Li Yan, liyan_china@126.com
Received Date: 7 September 2017
Accepted Date: 6 November 2017

Figures(9)

Mg-Al hydrotalcite-like compound (HTlc) and Fe₃O₄@HTlc were prepared by coprecipitation method. The phase identification and morphology of the HTlc and Fe₃O₄@HTlc were characterized by TEM, XRD, FTIR, VSM, N₂ adsorption-desorption, and microiontophoresis apparatus. The adsorption performance of Fe₃O₄@HTlc and HTlc toward methyl orange(MO) was compared. The results showed that Fe₃O₄@HTlc particles were near spherical particles with paramagnetism, core-shell structures, larger specific surface areas and positive charges. The adsorption kinetics and adsorption isotherms of Fe₃O₄@HTlc and HTlc can be well described by the pseudo-first order kinetic and Langmuir isotherm. The saturated adsorption quantity of Fe₃O₄@HTlc and HTlc toward MO were 138.89 mg/g and 147.06 mg/g, respectively, and Fe₃O₄@HTlc had a strong driving force toward MO and a shorter adsorption equilibrium time. The adsorption amounts of MO on both Fe₃O₄@HTlc and HTlc decreased gradually with increasing temperature and increasing initial pH in the range of 5~11.
- Hydrotalcite-like compound,
- Magnetite,
- Methyl orange,
- Adsorption
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沈阳化工大学材料科学与工程学院沈阳 110142

Preparation of Fe3O4@Hydrotalcite-like Compound and Its Adsorption Capacity for Methyl Orange

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通讯作者: 陈斌, bchen63@163.com

Preparation of Fe₃O₄@Hydrotalcite-like Compound and Its Adsorption Capacity for Methyl Orange