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Citation: Lu Hai, Li Tao, Wang Jinlei, Yi Dawei, Lai Yanqing. Comparative Study on Different Binders used for Sulfur Cathode of Lithium Sulfur Battery[J]. Chemistry, ;2017, 80(10): 948-952. shu

Comparative Study on Different Binders used for Sulfur Cathode of Lithium Sulfur Battery

Lu Hai ^1,, ,
Li Tao ² ,
Wang Jinlei ¹ ,
Yi Dawei ¹ ,
Lai Yanqing ²

1.
School of Materials Science and Engineering, Xi'an University of Science and Technology, Xi'an 710054
2.
School of Metallurgy and Environment, Central South University, Changsha 410083

Corresponding author: Lu Hai, lhxust@126.com
Received Date: 21 May 2017
Accepted Date: 26 June 2017

Figures(6)

Three kinds of binder systems (PVDF, LA133, CMC+SBR with 1:1 mass ratio) were employed for constructing sulfur electrode of Li-S battery.The molecule structures, crystallization properties, thermodynamic properties, electrolyte absorption and binding strength of various materials were characterized.The effects of binder type on the electrochemical properties of Li-S battery were investigated.Low electrolyte uptake, weak peel strength and poor cycle capability appears in the sulfur cathode fabricated by CMC+SBR.Amorphous LA133 favors high binding strength and stable electrode structure.PVDF leads to poor adhesion quality due to its semi crystalline, and the constructed cathode produces high electrolyte absorption but low charge transfer resistance.In contrast, a reversible capacity of 722mAh·g^-1 and capacity retention rate of 82.9% after 100 cycles at 0.2 C is exhibited in the PVDF-based cathode, which is the best performance level among mentioned three binder systems.
- Lithium sulfur battery,
- Sulfur cathode,
- Binder,
- Electrochemical performance
1. [1]
  W Kang, N Deng, J Ju et al. Nanoscale, 2016, 8(37):16541~16588.
2. [2]
  Z W Seh, Y Sun, Q Zhang et al. Chem. Soc. Rev., 2016, 45(20):5605~5634.
3. [3]
4. [4]
  G Ai, Y Dai, Y Ye et al. Nano Energy, 2015, 16:28~37.
5. [5]
6. [6]
7. [7]
  E F C Chauque, A A Adelodun, L N Dlamini et al. Mater. Chem. Phys., 2017, 192:108~124.
8. [8]
9. [9]
10. [10]
11. [11]
  M H El-Newehy, A Alamri, S S Al-Deyab. Arab. J. Chem., 2014, 7(2):235~241.
12. [12]
13. [13]
14. [14]
  J Pan, G Xu, B Ding et al. RSC Adv., 2016, 6(47):40650~40655.
15. [15]
  H Lu, Y Yuan, Q Yang et al. Ionics, 2016, 22:997~1002.
16. [16]
  H Lu, Y Yuan, Z Hou et al. RSC Adv., 2016, 6(22):18186~18190.
1. [1]
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2. [2]
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3. [3]
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16. [16]
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17. [17]
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18. [18]
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