Citation: Wang Yingjin, Sun Jinyu, Shi Yufang, Ren Guangming, Zhao Minggen. Ultrafast Third-Order Nonlinear Optical Response of Ferrocene-Based Chalcone Derivatives[J]. Chemistry, ;2019, 82(7): 636-641. shu

Ultrafast Third-Order Nonlinear Optical Response of Ferrocene-Based Chalcone Derivatives

Key Laboratory of Materials and Computational Chemistry, Department of Chemistry, Xinzhou Teachers University, Xinzhou 034000

Corresponding author: Shi Yufang, yfshi868@163.com
Received Date: 4 January 2019
Accepted Date: 22 February 2019

Figures(5)

Three novel chalcone derivatives of ferrocenyl, 1-ferrocenyl-3-(5-Bromothiophen-2-yl)-2-propen-1-one (1), 1-ferrocenyl-3-(4-bromothiophen-2-yl)-2-propen-1-one (2) and 1-ferrocenyl-3-(5-chlorthiophen-2-yl)-2-propen-1-one (3) were synthesized and characterized by ¹H NMR, ¹³C NMR and HR-MS. The thermal properties of compounds 1~3 were measured. Their molecular orbital energies and polarizabilities were calculated by density functional theory method, and then the electronic cloud figures of the molecular orbitals were obtained. Their linear and nonlinear optical properties were investigated using UV-Vis absorption spectra and Z-scan technique (532 nm, 180 fs), respectively. The maximum absorption wavelength of compounds 1~3 increases significantly, and the nonlinear absorption amplitude, polarizability and molecular hyperpolarizability of compound 1 is the largest one. There is distinct intramolecular charge transfer phenomenon within these compounds, which results to interesting ultrafast third-order nonlinear optical response.
- Ferrocene derivatives,
- Chalcone,
- Z-scan technique,
- Ultrafast third-order nonlinear optical response,
- Synthesis
1. [1]
  S R Prabhu, A Jayarama, K Chandrasekharan et al. J. Mol. Struct., 2017, 1136:244~252.
2. [2]
  J Lin, R Sa, M Zhang et al. J. Phys. Chem. A, 2015, 119(29):8174~8181.
3. [3]
  M H Youssoufi, P K Sahu, P K Sahu et al. Med. Chem. Res., 2015, 24(6):2381~2392.
4. [4]
  X Fu, J Feng, Z Dong et al. Eur. J. Org. Chem., 2011, 27:5233~5236.
5. [5]
  E M Sharshira, N M M Hamada. Am. J. Org. Chem., 2012, 2(2):26~31.
6. [6]
  S Czemmel, S C Heppel, J Bogs. Protoplasma, 2012, 249(2):109~118.
7. [7]
  L R Almeida, M M Anjos, G C Ribeiro et al. New J. Chem., 2017, 41(4):1744~1754.
8. [8]
  A Ekbote, P S Patil, S R Maidur et al. J. Mol. Struct., 2017, 1129:239~247.
9. [9]
  S Kar, K S Adithya, P Shankar et al. J. Mol. Struct., 2017, 1139:294~302.
10. [10]
  T C S Shetty, S Raghavendra, C S C Kumar et al. Opt. Laser Technol., 2016, 77:23~30.
11. [11]
  F Z Henari, D Gaynor, D M Griffith et al. Chem. Phys. Lett., 2012, 552(45):126~129.
12. [12]
  C P Singh, R Sharma, V Shukla et al. Chem. Phys. Lett., 2014, 616-617:189~195.
13. [13]
  S R Maidur, J R Jahagirdar, P S Patil et al. Opt. Mater., 2018, 75:580~594.
14. [14]
  B Pramodh, N K Lokanath, S Naveen et al. J. Mol. Struct., 2018, 1161:9~17.
15. [15]
  M Rausch, M Vogel, H Rosenberg. J. Chem. Edu., 1957, 34(6):268~269.
16. [16]
  B Fabre. Acc. Chem. Res., 2010, 43(12):1509~1518.
17. [17]
  H Zhao, Y Zhu, C Chen et al. Carbon, 2012, 50(13):4894~4902.
18. [18]
  P Kaur, M Kaur, G Depotter et al. J. Mater. Chem., 2012, 22(21):10597~10608.
19. [19]
  G Li, Y L Song, H W Hou et al. Inorg. Chem., 2003, 42(3):913~920.
20. [20]
  Y C Liu, Y H Kan, S X Wu et al. J. Phys. Chem. A, 2008, 112(35):8086~8092.
21. [21]
  V Shettigar, P S Patil, S Naveen et al. J. Cryst. Growth, 2006, 295:44~49.
22. [22]
  S R Maidur, P S Patil. Opt. Mater., 2018, 84:28~37.
23. [23]
  Y F Shi, Z G Li, M G Zhao et al. Opt. Laser Technol., 2017, 90:18~21.
24. [24]
  J Y Sun, G L Wang, Y F Shi et al. Opt. Laser Technol., 2019, 109:600~607.
25. [25]
26. [26]
27. [27]
  M J Frisch, G W Trucks, H B Schlegel et al. Gaussian 09, Revision B. 02, Gaussian, Inc., Wallingford CT, 2010.
1. [1]
  Bin SUN , Heyan JIANG . Glucose-modified bis-Schiff bases: Synthesis and bio-activities in Alzheimer′s disease therapy. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1338-1350. doi: 10.11862/CJIC.20240428
2. [2]
  Lifang HE , Wenjie TANG , Yaoze LUO , Mingsheng LIANG , Jianxin TANG , Yuxuan WU , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two dialkyltin complexes constructed based on 2, 2′-bipyridin-6, 6′-dicarboxylic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1601-1609. doi: 10.11862/CJIC.20250012
3. [3]
  Chunling Qin , Shuang Chen , Hassanien Gomaa , Mohamed A. Shenashen , Sherif A. El-Safty , Qian Liu , Cuihua An , Xijun Liu , Qibo Deng , Ning Hu . Regulating HER and OER Performances of 2D Materials by the External Physical Fields. Acta Physico-Chimica Sinica, 2024, 40(9): 2307059-0. doi: 10.3866/PKU.WHXB202307059
4. [4]
  Jing WU , Puzhen HUI , Huilin ZHENG , Pingchuan YUAN , Chunfei WANG , Hui WANG , Xiaoxia GU . Synthesis, crystal structures, and antitumor activities of transition metal complexes incorporating a naphthol-aldehyde Schiff base ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2422-2428. doi: 10.11862/CJIC.20240278
5. [5]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
6. [6]
  Jiaming Xu , Yu Xiang , Weisheng Lin , Zhiwei Miao . Research Progress in the Synthesis of Cyclic Organic Compounds Using Bimetallic Relay Catalytic Strategies. University Chemistry, 2024, 39(3): 239-257. doi: 10.3866/PKU.DXHX202309093
7. [7]
  Xinyi Zhang , Kai Ren , Yanning Liu , Zhenyi Gu , Zhixiong Huang , Shuohang Zheng , Xiaotong Wang , Jinzhi Guo , Igor V. Zatovsky , Junming Cao , Xinglong Wu . Progress on Entropy Production Engineering for Electrochemical Catalysis. Acta Physico-Chimica Sinica, 2024, 40(7): 2307057-0. doi: 10.3866/PKU.WHXB202307057
8. [8]
  Lei Feng , Ze-Min Zhu , Ying Yang , Zongbin He , Jiafeng Zou , Man-Bo Li , Yan Zhao , Zhikun Wu . Long-Pursued Structure of Au₂₃(S-Adm)₁₆ and the Unexpected Doping Effects. Acta Physico-Chimica Sinica, 2024, 40(5): 2305029-0. doi: 10.3866/PKU.WHXB202305029
9. [9]
  Xiaohang JIN , Qi LIU , Jianping LANG . Room‑temperature solid‑state synthesis, structure, and third‑order nonlinear optical properties of phosphine‑ligand‑protected silver thiolate clusters. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1505-1512. doi: 10.11862/CJIC.20250125
10. [10]
  Zhiwen HUANG , Qi LIU , Jianping LANG . W/Cu/S cluster-based supramolecular macrocycles and their third-order nonlinear optical responses. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 79-87. doi: 10.11862/CJIC.20240184
11. [11]
  Jianfeng Yan , Yating Xiao , Xin Zuo , Caixia Lin , Yaofeng Yuan . Comprehensive Chemistry Experimental Design of Ferrocenylphenyl Derivatives. University Chemistry, 2024, 39(4): 329-337. doi: 10.3866/PKU.DXHX202310005
12. [12]
  Kexin Feng , Jie Zhang , Yujia Sun , Qiong Ai , Longchun Li . 乙酰二茂铁和二茂铁甲酰丙酮的合成、纯化及表征. University Chemistry, 2025, 40(8): 307-314. doi: 10.12461/PKU.DXHX202409045
13. [13]
  Guilan He , Yaofeng Yuan . 手性二茂铁双膦配体Xyliphos的合成及应用. University Chemistry, 2025, 40(8): 130-137. doi: 10.12461/PKU.DXHX202409122
14. [14]
  Yonghui ZHOU , Rujun HUANG , Dongchao YAO , Aiwei ZHANG , Yuhang SUN , Zhujun CHEN , Baisong ZHU , Youxuan ZHENG . Synthesis and photoelectric properties of fluorescence materials with electron donor-acceptor structures based on quinoxaline and pyridinopyrazine, carbazole, and diphenylamine derivatives. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 701-712. doi: 10.11862/CJIC.20230373
15. [15]
  Jia-He Li , Yu-Ze Liu , Jia-Hui Ma , Qing-Xiao Tong , Jian-Ji Zhong , Jing-Xin Jian . 洛芬碱衍生物的合成、化学发光与重金属离子检测. University Chemistry, 2025, 40(6): 230-237. doi: 10.12461/PKU.DXHX202407080
16. [16]
  Liangzhen Hu , Li Ni , Ziyi Liu , Xiaohui Zhang , Bo Qin , Yan Xiong . A Green Chemistry Experiment on Electrochemical Synthesis of Benzophenone. University Chemistry, 2024, 39(6): 350-356. doi: 10.3866/PKU.DXHX202312001
17. [17]
  Liping GUO . Synthesis and crystal structure characterization of yttrium imido complex: The reactivity of 2-substituted-1-amino-o-carborane with yttrium dialkyl complex. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1409-1415. doi: 10.11862/CJIC.20250065
18. [18]
  Yurong Tang , Yunren Shi , Yi Xu , Bo Qin , Yanqin Xu , Yunfei Cai . Innovative Experiment and Course Transformation Practice of Visible-Light-Mediated Photocatalytic Synthesis of Isoquinolinone. University Chemistry, 2024, 39(5): 296-306. doi: 10.3866/PKU.DXHX202311087
19. [19]
  Li'na ZHONG , Jingling CHEN , Qinghua ZHAO . Synthesis of multi-responsive carbon quantum dots from green carbon sources for detection of iron ions and L-ascorbic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 709-718. doi: 10.11862/CJIC.20240280
20. [20]
  Xiaofei Liu , He Wang , Li Tao , Weimin Ren , Xiaobing Lu , Wenzhen Zhang . Electrocarboxylation of Benzylic Phosphates and Phosphinates with Carbon Dioxide. Acta Physico-Chimica Sinica, 2024, 40(9): 2307008-0. doi: 10.3866/PKU.WHXB202307008

Get Citation

PDF

XML

Metrics

PDF Downloads(4)
Abstract views(687)
HTML views(183)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142