Citation: Jian Hua DONG, Kun Yuan QIU, Xin De FENG. STUDIES ON THE KINETICS AND INITIATION MECHANISM OF ACRYLAMIDE POLYMERIZATION USING CERIC/ACETOACETANILIDE SYSTEM AS INITIATOR[J]. Chinese Chemical Letters, ;1992, 3(2): 103-106. shu

STUDIES ON THE KINETICS AND INITIATION MECHANISM OF ACRYLAMIDE POLYMERIZATION USING CERIC/ACETOACETANILIDE SYSTEM AS INITIATOR

Department of Chemistry, Peking University, Beijing 100871

Received Date: 11 October 1991

Fund Project: Project Supported by National Science Foundation of China.

It is found that acetoacetanilide possesses very high promoting reactivity towards ceric ion in initiating polymerization of vinyl monomer. The kinetics of acrylamide polymerization and the activation energies were studied. The initiation mechanism of ceric/acetoacetanilide is proposed on the basis of experimental results of FT-IR and ESR.
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