Citation: Huiquan Yang, Fan Yang, Mingyang Wei, Lichun Liu, Liqiu Zhang. Atomic Platinum Cluster Electrodeposition on Micro-Nano-Scale Carbon Electrode[J]. Chemistry, ;2021, 84(2): 172-177. shu

Atomic Platinum Cluster Electrodeposition on Micro-Nano-Scale Carbon Electrode

College of Biological and Chemical Science and Engineering, Jiaxing University, Jiaxing, 314001

Corresponding author: Liqiu Zhang, liqiu0524@zjxu.edu.cn
Received Date: 18 August 2020
Accepted Date: 2 September 2020

Figures(4)

In this work, micro-nano-scale carbon electrodes were successfully prepared by flame etching and glass capillary tubes encapsulation. Pt clusters of different sizes, such as single atom, 3 atoms, 5 atoms, were obtained on as-prepared carbon electrodes by electrochemical deposition through regulating the parameters, such as electrolyte concentration, deposition strategy and deposition time. The size of Pt clusters was calculated using limiting current of the catalytic hydrogen reduction on as-prepared electrodes in an acidic solution. Meanwhile, the hydrogen evolution characteristics of Pt clusters were compared using linear scanning voltammetry, and the stability of Pt single atom was evaluated by consulting cyclic voltammetry. This study can provide an important reference for the study of the electrodeposition and properties of single-atom and few-atom metal clusters.
- Carbon electrode,
- Catalyst,
- Single atom,
- Pt,
- Electrochemical deposition
1. [1]
  Zhang L, Doyle-Davis K, Sun X. Energy Environ. Sci., 2019, 12(2): 492~517.
2. [2]
  Martins M, Mourato C, Sanches S, et al. Water Res., 2017, 108: 160~168.
3. [3]
  Zhao X, Chen S, Fang Z, et al. J. Am. Chem. Soc., 2015, 137(8): 2804~2807.
4. [4]
  Zhang L, Yu S, Zhang J, et al. Chem. Sci., 2016, 7(6): 3500~3505.
5. [5]
  Zhou Z, Tian N, Li J, et al. Chem. Soc. Rev., 2011, 40(7): 4167~4185.
6. [6]
  Luo Z, Tan C, Lai Z, et al. Sci. Chin. Mater., 2018, 62(1): 115~121.
7. [7]
  Zhang Z, Liu G, Cui X, et al. Adv. Mater., 2018, 30(30): e1801741.
8. [8]
  Han B, Carlton C, Kongkanand A, et al. Energy Environ. Sci., 2015, 8(1): 258~266.
9. [9]
  Tian N, Zhou Z Y, Sun S, et al. Science, 2007, 316: 732~735.
10. [10]
  Qiao B, Wang A, Yang X, et al. Nat. Chem., 2011, 3(8): 634~641.
11. [11]
12. [12]
13. [13]
  Kistler J, Chotigkrai N, Xu P, et al. Angew. Chem. Int. Ed., 2014, 53(34): 8904~8907.
14. [14]
  Xing J, Chen J, Li Y, et al. Chem. Eur. J., 2014, 20(8): 2088~2088.
15. [15]
  Wei S, Li A, Liu J, et al. Nat. Nanotech., 2018, 13(9): 856~861.
16. [16]
  Zhou M, Dick J, Bard A. J. Am. Chem. Soc., 2017, 139(48): 17677~17682.
17. [17]
  Zhou M, Bao S, Bard A. J. Am. Chem. Soc., 2019, 141(18): 7327~7332.
18. [18]
  Ma W, Hu K, Chen Q, et al. Nano Lett., 2017, 17(7): 4354~4358.
1. [1]
  Huirong BAO , Jun YANG , Xiaomiao FENG . Preparation and electrochemical properties of NiCoP/polypyrrole/carbon cloth by electrodeposition. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1083-1093. doi: 10.11862/CJIC.20250008
2. [2]
  Peng YUE , Liyao SHI , Jinglei CUI , Huirong ZHANG , Yanxia GUO . Effects of Ce and Mn promoters on the selective oxidation of ammonia over V₂O₅/TiO₂ catalyst. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 293-307. doi: 10.11862/CJIC.20240210
3. [3]
  Yixuan Gao , Lingxing Zan , Wenlin Zhang , Qingbo Wei . Comprehensive Innovation Experiment: Preparation and Characterization of Carbon-based Perovskite Solar Cells. University Chemistry, 2024, 39(4): 178-183. doi: 10.3866/PKU.DXHX202311091
4. [4]
  Yongwei ZHANG , Chuang ZHU , Wenbin WU , Yongyong MA , Heng YANG . Efficient hydrogen evolution reaction activity induced by ZnSe@nitrogen doped porous carbon heterojunction. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 650-660. doi: 10.11862/CJIC.20240386
5. [5]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201
6. [6]
  Wentao Xu , Xuyan Mo , Yang Zhou , Zuxian Weng , Kunling Mo , Yanhua Wu , Xinlin Jiang , Dan Li , Tangqi Lan , Huan Wen , Fuqin Zheng , Youjun Fan , Wei Chen . Bimetal Leaching Induced Reconstruction of Water Oxidation Electrocatalyst for Enhanced Activity and Stability. Acta Physico-Chimica Sinica, 2024, 40(8): 2308003-0. doi: 10.3866/PKU.WHXB202308003
7. [7]
  Zhaoyu Wen , Na Han , Yanguang Li . Recent Progress towards the Production of H₂O₂ by Electrochemical Two-Electron Oxygen Reduction Reaction. Acta Physico-Chimica Sinica, 2024, 40(2): 2304001-0. doi: 10.3866/PKU.WHXB202304001
8. [8]
  Xueting Feng , Ziang Shang , Rong Qin , Yunhu Han . Advances in Single-Atom Catalysts for Electrocatalytic CO₂ Reduction. Acta Physico-Chimica Sinica, 2024, 40(4): 2305005-0. doi: 10.3866/PKU.WHXB202305005
9. [9]
  Lele Feng , Xueying Bai , Jifeng Pang , Hongchen Cao , Xiaoyan Liu , Wenhao Luo , Xiaofeng Yang , Pengfei Wu , Mingyuan Zheng . Single-atom Pd boosted Cu catalysts for ethanol dehydrogenation. Acta Physico-Chimica Sinica, 2025, 41(9): 100100-0. doi: 10.1016/j.actphy.2025.100100
10. [10]
  Yang WANG , Xiaoqin ZHENG , Yang LIU , Kai ZHANG , Jiahui KOU , Linbing SUN . Mn single-atom catalysts based on confined space: Fabrication and the electrocatalytic oxygen evolution reaction performance. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2175-2185. doi: 10.11862/CJIC.20240165
11. [11]
  Chunmei GUO , Weihan YIN , Jingyi SHI , Jianhang ZHAO , Ying CHEN , Quli FAN . Facile construction and peroxidase-like activity of single-atom platinum nanozyme. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1633-1639. doi: 10.11862/CJIC.20240162
12. [12]
  Jingkun Yu , Xue Yong , Ang Cao , Siyu Lu . Bi-Layer Single Atom Catalysts Boosted Nitrate-to-Ammonia Electroreduction with High Activity and Selectivity. Acta Physico-Chimica Sinica, 2024, 40(6): 2307015-0. doi: 10.3866/PKU.WHXB202307015
13. [13]
  Shiyang He , Dandan Chu , Zhixin Pang , Yuhang Du , Jiayi Wang , Yuhong Chen , Yumeng Su , Jianhua Qin , Xiangrong Pan , Zhan Zhou , Jingguo Li , Lufang Ma , Chaoliang Tan . Pt Single-Atom-Functionalized 2D Al-TCPP MOF Nanosheets for Enhanced Photodynamic Antimicrobial Therapy. Acta Physico-Chimica Sinica, 2025, 41(5): 100046-0. doi: 10.1016/j.actphy.2025.100046
14. [14]
  Yuchen Zhou , Huanmin Liu , Hongxing Li , Xinyu Song , Yonghua Tang , Peng Zhou . Designing thermodynamically stable noble metal single-atom photocatalysts for highly efficient non-oxidative conversion of ethanol into high-purity hydrogen and value-added acetaldehyde. Acta Physico-Chimica Sinica, 2025, 41(6): 100067-0. doi: 10.1016/j.actphy.2025.100067
15. [15]
  Xuejie Wang , Guoqing Cui , Congkai Wang , Yang Yang , Guiyuan Jiang , Chunming Xu . Research Progress on Carbon-based Catalysts for Catalytic Dehydrogenation of Liquid Organic Hydrogen Carriers. Acta Physico-Chimica Sinica, 2025, 41(5): 100044-0. doi: 10.1016/j.actphy.2024.100044
16. [16]
  Qing Li , Guangxun Zhang , Yuxia Xu , Yangyang Sun , Huan Pang . P-Regulated Hierarchical Structure Ni₂P Assemblies toward Efficient Electrochemical Urea Oxidation. Acta Physico-Chimica Sinica, 2024, 40(9): 2308045-0. doi: 10.3866/PKU.WHXB202308045
17. [17]
  Xiaomei Ning , Liang Zhan , Xiaosong Zhou , Jin Luo , Xunfu Zhou , Cuifen Luo . Preparation and Electro-Oxidation Performance of PtBi Supported on Carbon Cloth: A Recommended Comprehensive Chemical Experiment. University Chemistry, 2024, 39(11): 217-224. doi: 10.3866/PKU.DXHX202401085
18. [18]
  Wang Wang , Yucheng Liu , Shengli Chen . Use of NiFe Layered Double Hydroxide as Electrocatalyst in Oxygen Evolution Reaction: Catalytic Mechanisms, Electrode Design, and Durability. Acta Physico-Chimica Sinica, 2024, 40(2): 2303059-0. doi: 10.3866/PKU.WHXB202303059
19. [19]
  Wei Zhong , Dan Zheng , Yuanxin Ou , Aiyun Meng , Yaorong Su . Simultaneously Improving Inter-Plane Crystallization and Incorporating K Atoms in g-C₃N₄ Photocatalyst for Highly-Efficient H₂O₂ Photosynthesis. Acta Physico-Chimica Sinica, 2024, 40(11): 2406005-0. doi: 10.3866/PKU.WHXB202406005
20. [20]
  Jun LI , Huipeng LI , Hua ZHAO , Qinlong LIU . Preparation and photocatalytic performance of AgNi bimetallic modified polyhedral bismuth vanadate. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 601-612. doi: 10.11862/CJIC.20230401

Get Citation

PDF

XML

Metrics

PDF Downloads(11)
Abstract views(976)
HTML views(350)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142