Citation: SHI Min, FAN Ming-ming, ZHANG Ping-bo, JIANG Ping-ping. Preparation of nano-solid based catalyst CaO@SiO₂ for the transesterification of soybean oil to biodiesel[J]. Journal of Fuel Chemistry and Technology, ;2016, 44(8): 921-927. shu

Preparation of nano-solid based catalyst CaO@SiO₂ for the transesterification of soybean oil to biodiesel

School of Chemical and Material Engineering, Jiangnan University, Wuxi 214122, China

Corresponding author: ZHANG Ping-bo, pingbozhang@126.com
Received Date: 24 March 2016
Revised Date: 6 May 2016

Figures(10)

The CaO@SiO₂ alkaline catalyst was prepared by sol-gel method that chooses polystyrene as hard template and P123 as soft template to control the microstructure. Furthermore, the prepared catalyst was applied to the transesterification of soybean and methanol. Also, the nano-solid based catalyst was characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), CO₂-TPD and N₂ absorption-desorption (BET). The results show that the catalyst possesses an ordered morphology and core-shell structure. In addition, the effect of the ratio of SiO₂/CaO (mass ratio), reaction temperatures, catalyst dosages and the ratio of oil/methanol (mol ratio) on the yield of biodiesel was examined. Under the best reaction condition, the yield of biodiesel can reach 95.6%.
- CaO,
- transesterification,
- biodiesel,
- nano-catalyst
1. [1]
  LI H, XIA S Q, LUO H J, MA P S. Experimental and computational study on the compatibility of biodiesel/diesel/methanol blended fuel[J]. Fuel, 2016,173:52-59. doi: 10.1016/j.fuel.2016.01.036
2. [2]
  TANMAY B, MANAS K K, SUDIP B. Palladium nanoparticle-graphitic carbon nitride porous synergistic catalyst for hydrogen evolution/oxidation reactions over a broad range of pH and correlation of its catalytic activity with measured hydrogen binding energy[J]. ACS Catal, 2016,6(3):1929-1941. doi: 10.1021/acscatal.5b02485
3. [3]
  ABDERRAHIM B, RODRIGO V, MERCEDES M, JOSE A. Effect of free fatty acids contents on biodiesel quality.Pilot plant studies[J]. Fuel, 2016,174:54-62. doi: 10.1016/j.fuel.2016.01.018
4. [4]
  AHMAD M, ASADOLAH A, SHAHIN R, ELNAZ B K. Energy and cost analyses of biodiesel production from waste cooking oil[J]. Renewable Sustainable Energy Rev, 2014,33:44-49. doi: 10.1016/j.rser.2014.01.067
5. [5]
  LI Xiao-hong, JIN Fu-quan. Preparation of CaO/(Mg-Fe-O) solid base and its catalytic activity in transesterification[J]. China Oils Fats, 2015,40(7):55-59.
6. [6]
  ZHANG Chuan-feng, ZHAO Jing, FANG Wen-jun, GUO Yong-sheng. Application of nanocatalyst in the fields of hydrocarbon fuel and biodiesel[J]. Acta Pet Sin, 2015,31(2):418-425.
7. [7]
  NAVOT K, AMJAD A. Biodiesel production via ethanolysis of jatropha oil using molybdenum impregnated calcium oxide as solid catalyst[J]. RSC Adv, 2015,5(18):13285-13295. doi: 10.1039/C4RA14786C
8. [8]
  ZHENG Hua-yan, LI Xi-qian, CUI Li-ping, LI Zhong. Synthesis of biodiesel from rapeseed oil catalyzed by Ca/Al solid base[J]. J Fuel Chem Technol, 2012,40(3):331-336.
9. [9]
  JOSHI G, RAWAT D S, LAMBA B Y, BISHT K K, KUMAR P, KUMAR N, KUMAR S. Transesterification of Jatropha and Karanja oils by using waste egg shell derived calcium based mixed metal oxides[J]. Energy Convers Manage, 2015,96:258-267. doi: 10.1016/j.enconman.2015.02.061
10. [10]
  SIOW H T, AMINUL I, TALAL Y, YUN H T. Transesterification of nannochloropsis oculata microalga's oil to biodiesel using calcium methoxide catalyst[J]. Energy, 2014,78:63-71. doi: 10.1016/j.energy.2014.07.045
11. [11]
  NEZAHAT B, NEBAHAT D, DIHAN M K. Transesterification of canola oil to biodiesel using calcium bentonite functionalized with K compounds[J]. Appl Catal B:Environ, 2013,138-139:236-242. doi: 10.1016/j.apcatb.2013.02.043
12. [12]
  SUN Yan-rong, FAN Tao, LIU Feng, MA Li-guo, WANG Chang-an. influence of templates on morphology of nano-hydroxyapatite synthesized by Co-precipitation method[J]. J Chin Ceram Soc, 2012,40(1):90-94.
13. [13]
  SHEN Shao-chun, YUAN Zhi-qing, YANG Wei-min, LI Ying-cheng. Preparation of nano-sized ZSM-5 zeolite based on the novel template gemini quaternary ammonium hydroxide[J]. Ind Catal, 2015,23(10):763-766.
14. [14]
  WANG Ya-yun, CHEN Yang, ZHAN Xiao-bing, QIN Jia-wei. Effects of the polishing pressure on the polishing performance of nano-sized PS/CeO₂ composite abrasives[J]. Micronanoelectron Technol, 2015,52(2):129-134.
15. [15]
  RASHAD M M, IBRAHIM I A. Improvement of the magnetic properties of barium hexaferrite nanopowders using modified co-precipitation method[J]. J Mang Magn Mater, 2011,323(16):2158-2164. doi: 10.1016/j.jmmm.2011.03.023
16. [16]
  OU Yang-mi, HUANG Sen-biao, HAN Yan-gang, LV Xiao-jing, YANG yuan, DAI Yu-yu, LU Yao-kang, ZHANG Cheng. Enhanced electrochromic performance of ordered porous monolayer PBTB film using amine-modified polystyrene spheres as a template[J]. Acta Phys-Chim Sin, 2015,31(3):476-482.
17. [17]
  XIE W L, YANG X L, FAN M L. Novel solid base catalyst for biodiesel production:Mesoporous SBA-15 silica immobilized with 1, 3-dicyclohexyl-2-octylguanidine[J]. Renewable Energy, 2015,80:230-237. doi: 10.1016/j.renene.2015.02.014
18. [18]
  HOU Qian-fen, ZHANG Qian-qian, GUO Hua-rong, LI Ling. Synthesis and characterization of Ca/SBA-15 solid base catalyst and its application in biodiesel production via waste cooking oil[J]. Chem Bioeng, 2015,32(8):28-34.
19. [19]
  HOU Li-wei, YI Yu-feng, DING Fu-chen. Study on affecting factors of determining glycerol content with periodic acid oxidation[J]. Cereal Oil, 2010(1):36-40.
20. [20]
  GUO Ping-mei, HUANG Qing. Study on analytical method of free glycerin and total glycerin in biodiesel[J]. Cereal Oil, 2003(8):41-42.
21. [21]
  PUNNAMA S, SHIGEO H, ATSUO Y, KYIOSHI O. Preparation and sintering of CaSiO₃ from coprecipitated powder using NaOH as precipitant and its apatite formation in simulated body fluid solution[J]. J Mater Res, 1999,14(2):529-536. doi: 10.1557/JMR.1999.0076
22. [22]
  JIANG W, NIU X Y, YUAN F L, ZHU Y J, FU H G. Preparation of KF-La₂O₂CO₃ solid base catalysts and their excellent catalytic activities for transesterification of tributyrin with methanol[J]. Catal Sci Technol, 2014,4:2957-2968. doi: 10.1039/C4CY00167B
23. [23]
  FAN Ming-ming, LIU Yan-lei, ZHANG Ping-bo, JIANG Ping-ping. Preparation of magnetic core-shell CaO-MgO@CoFe₂O₄ solid base and its catalytic performance in the transesterification of soybean oil to biodiesel[J]. J Fuel Chem Technol, 2016,44(4):422-427.
1. [1]
  Lei Shu , Zhengqing Hao , Kai Yan , Hong Wang , Lihua Zhu , Fang Chen , Nan Wang . Development of a Double-Carbon Related Experiment: Preparation, Characterization and Carbon-Capture Ability of Eggshell-Derived CaO. University Chemistry, 2024, 39(4): 149-156. doi: 10.3866/PKU.DXHX202310134
2. [2]
  Jinghan ZHANG , Guanying CHEN . Progress in the application of rare-earth-doped upconversion nanoprobes in biological detection. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2335-2355. doi: 10.11862/CJIC.20240249
3. [3]
  Meiqing Yang , Lu Wang , Haozi Lu , Yaocheng Yang , Song Liu . Recent Advances of Functional Nanomaterials for Screen-Printed Photoelectrochemical Biosensors. Acta Physico-Chimica Sinica, 2025, 41(2): 100018-. doi: 10.3866/PKU.WHXB202310046
4. [4]
  Yu Dai , Xueting Sun , Haoyu Wu , Naizhu Li , Guoe Cheng , Xiaojin Zhang , Fan Xia . Determination of the Michaelis Constant for Gold Nanozyme-Catalyzed Decomposition of Hydrogen Peroxide. University Chemistry, 2025, 40(5): 351-356. doi: 10.12461/PKU.DXHX202407052
5. [5]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
6. [6]
  Fanpeng Meng , Fei Zhao , Jingkai Lin , Jinsheng Zhao , Huayang Zhang , Shaobin Wang . 优化氮化碳纳米片/球形共轭聚合物S型异质结界面电场以促进析氢反应. Acta Physico-Chimica Sinica, 2025, 41(8): 100095-. doi: 10.1016/j.actphy.2025.100095
7. [7]
  Zhongyan Cao , Shengnan Jin , Yuxia Wang , Yiyi Chen , Xianqiang Kong , Yuanqing Xu . Advances in Highly Selective Reactions Involving Phenol Derivatives as Aryl Radical Precursors. University Chemistry, 2025, 40(4): 245-252. doi: 10.12461/PKU.DXHX202405186
8. [8]
  Gaofeng Zeng , Shuyu Liu , Manle Jiang , Yu Wang , Ping Xu , Lei Wang . Micro/Nanorobots for Pollution Detection and Toxic Removal. University Chemistry, 2024, 39(9): 229-234. doi: 10.12461/PKU.DXHX202311055
9. [9]
  Jiao CHEN , Yi LI , Yi XIE , Dandan DIAO , Qiang XIAO . Vapor-phase transport of MFI nanosheets for the fabrication of ultrathin b-axis oriented zeolite membranes. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 507-514. doi: 10.11862/CJIC.20230403
10. [10]
  Hong LI , Xiaoying DING , Cihang LIU , Jinghan ZHANG , Yanying RAO . Detection of iron and copper ions based on gold nanorod etching colorimetry. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 953-962. doi: 10.11862/CJIC.20230370
11. [11]
  Guimin ZHANG , Wenjuan MA , Wenqiang DING , Zhengyi FU . Synthesis and catalytic properties of hollow AgPd bimetallic nanospheres. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 963-971. doi: 10.11862/CJIC.20230293
12. [12]
  Yuhao SUN , Qingzhe DONG , Lei ZHAO , Xiaodan JIANG , Hailing GUO , Xianglong MENG , Yongmei GUO . Synthesis and antibacterial properties of silver-loaded sod-based zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 761-770. doi: 10.11862/CJIC.20230169
13. [13]
  Jingke LIU , Jia CHEN , Yingchao HAN . Nano hydroxyapatite stable suspension system: Preparation and cobalt adsorption performance. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1763-1774. doi: 10.11862/CJIC.20240060
14. [14]
  Weihan Zhang , Menglu Wang , Ankang Jia , Wei Deng , Shuxing Bai . 表面硫物种对钯-硫纳米片加氢性能的影响. Acta Physico-Chimica Sinica, 2024, 40(11): 2309043-. doi: 10.3866/PKU.WHXB202309043
15. [15]
  Haiyu Nie , Chenhui Zhang , Fengpei Du . Ideological and Political Design for the Preparation, Characterization and Particle Size Control Experiment of Nanoemulsion. University Chemistry, 2024, 39(2): 41-46. doi: 10.3866/PKU.DXHX202306055
16. [16]
  Yongming Guo , Jie Li , Chaoyong Liu . Green Improvement and Educational Design in the Synthesis and Characterization of Silver Nanoparticles. University Chemistry, 2024, 39(3): 258-265. doi: 10.3866/PKU.DXHX202309057
17. [17]
  Zijian Jiang , Yuang Liu , Yijian Zong , Yong Fan , Wanchun Zhu , Yupeng Guo . Preparation of Nano Zinc Oxide by Microemulsion Method and Study on Its Photocatalytic Activity. University Chemistry, 2024, 39(5): 266-273. doi: 10.3866/PKU.DXHX202311101
18. [18]
  Zhengli Hu , Jia Wang , Yi-Lun Ying , Shaochuang Liu , Hui Ma , Wenwei Zhang , Jianrong Zhang , Yi-Tao Long . Exploration of Ideological and Political Elements in the Development History of Nanopore Electrochemistry. University Chemistry, 2024, 39(8): 344-350. doi: 10.3866/PKU.DXHX202401072
19. [19]
  Xiaxue Chen , Yuxuan Yang , Ruolin Yang , Yizhu Wang , Hongyun Liu . Adjustable Polychromatic Fluorescence: Investigating the Photoluminescent Properties of Copper Nanoclusters. University Chemistry, 2024, 39(9): 328-337. doi: 10.3866/PKU.DXHX202308019
20. [20]
  Yanting HUANG , Hua XIANG , Mei PAN . Construction and application of multi-component systems based on luminous copper nanoclusters. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2075-2090. doi: 10.11862/CJIC.20240196

Get Citation

PDF

XML

Metrics

PDF Downloads(23)
Abstract views(2535)
HTML views(519)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation of nano-solid based catalyst CaO@SiO2 for the transesterification of soybean oil to biodiesel

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation of nano-solid based catalyst CaO@SiO₂ for the transesterification of soybean oil to biodiesel