Citation: NIU Yong-jie, ZHAO Qiao-jing, LI Xin. Saturated hydrocarbon characteristics of superhigh-organic-sulfur coals in Heshan Shicun mine, Guangxi[J]. Journal of Fuel Chemistry and Technology, ;2020, 48(4): 395-404. shu

Saturated hydrocarbon characteristics of superhigh-organic-sulfur coals in Heshan Shicun mine, Guangxi

Key Laboratory of Resource Exploration Research of Hebei Province, School of Earth and Engineering, Hebei University of Engineering, Handan 056038, China

Corresponding author: ZHAO Qiao-jing, zhaoqiaojing@163.com
Received Date: 6 January 2020
Revised Date: 22 March 2020

Fund Project: Hebei Natural Science Foundation D2017402121The project was supported by the Hebei Natural Science Foundation (D2017402121)

Figures(9)

A superhigh-organic-sulfur (SHOS) coals were chosen to study the environmental causes of Heshan coal origin. Based on routine analysis such as scanning electron microscope (SEM-EDX) observation, gas chromatograph (GC) and gas chromatograph-mass spectrometry (GC-MS), the composition and molecular geochemical features of organic matter were analyzed to deeply reveal the organic matter sources, sedimentary environments and provenance inputs. The results indicate that the average vitrinite reflectance of the samples is 1.76%, and the average total sulfur is 6.01%, among which the organic sulfur content accounts for 94.3%, belonging to a high-maturation super high organic sulfur coal. Unresolved Complex Mixtures(UCM) bulge is obvious in the saturated hydrocarbon chromatogram, both front and bimodal peaks are found. The main carbon peaks of the front peak type are C₁₆, C₁₈, C₂₁ and the bimodal is C₁₈ and C₂₇. Meanwhile, these compounds norpristane, dehydroabietane, cadalene have been found in samples, and regular sterane C₂₇, C₂₈, C₂₉ show a "V" type distribution, which indicates that sedimentary parent material is affected by the double input of lower aquatic organisms and high plants. The distribution of hopane in C_31-35 decreases stepwise, and the ratio of pristane to phytane shows that there are certain oxidation conditions in the coal-forming zone of marine carbonate platform. Fe (Si, Al)-oxysulfate and cell-filled pyrite observed by SEM indicate that the sedimentary diagenesis is affected by hydrothermal process to some extent in the diagenetic stage of late sedimentary facies.
- Heshan,
- superhigh-organic-sulfur,
- GC-MS,
- biomarker,
- geochemistry
1. [1]
  LIANG Han-dong. Evidence for the complex of elemental sulfur plus iron in organic PHAS of super-high sulfur coal[J]. J Fuel Chem Technol, 2001,29(2):108-110.
2. [2]
  LEI J J, REN D Y, TANG Y G, CHU X L, ZHAO R. Sulfur accumulating model of super high organic sulfur coal from Guiding, China[J]. Chin Sci Bull, 1994,39(21):1817-1821.
3. [3]
  DAI S F, REN D Y, ZHOU Y P, CHOU C L, WANG X B, ZHAO L, ZHU X W. Mineralogy and geochemistry of a superhigh-organic-sulfur coal, Yanshan Coalfield, Yunnan, China:Evidence for a volcanic ash component and influence by submarine exhalation[J]. Chem Geol, 2008,255(1/2):182-194.
4. [4]
  DAI S F, SEREDIN V V, WARD C R, HOWER J C, XING Y W, ZHANG W G, SONG W J, WANG P P. Enrichment of U-Se-M-Re-V in coals preserved within marine carbonate successions:Geochemical and mineralogical data from the Late Permian Guiding Coalfield, Guizhou, China[J]. Miner Deposita, 2015,50:159-186.
5. [5]
  LI Bin, HAN Shou-cheng, HE Xin, MA Tian-peng, TANG Yue-gang. Coal petrology and coal quality characteristics of superhigh organic coal in Ganhe coalmine, Yanshan, Yunnan[J]. Coal Geol China, 2016,28(1):6-12.
6. [6]
  LEI Jia-jin, PU Ying-ying, REN De-yi. Bacterium-like bodies and its significance in high organosulfur coal from Guiding[J]. Acta Pet Sin, 1995,11(4):456-461.
7. [7]
  ZHANG Wei-guo, YANG Jian-ye, SHI Yuan. Characteristics of rare earth elements in super high organic sulfur coal in guangxi[J]. Chin Rare Earth, 2019,40(2):49-56.
8. [8]
  HUANNG Nai-he, WEN Xian-duan. Carbonate briquette group sedimentary environment of Heshan, Guangxi[J]. Coal Geol Explor, 1980,2:1-7.
9. [9]
  SHAO L Y, TIM J, ROD G, DAI S F, LI S S, JIANG Y F, ZHANG P F. Petrology and geochemistry of the high-sulphur coals from the Upper Permian carbonate coal measures in the Heshan coalfield, southern China[J]. Int J Coal Geol, 2003,55(1):1-26.
10. [10]
  ZENG R S, ZHANG X G, KOUKOUZAS N, XU W D. Characterization of trace elements in sulphur-rich Late Permian coals in the Heshan coal field, Guangxi, South China[J]. Int J Coal Geol, 2005,61(1/2):87-95.
11. [11]
  DAI S F, ZHANG W G, SEREDIN V V, WARD C R, HOWER J C, SONG W J, WANG X B, LI X, KANG H, ZHENG L C, WANG P P, ZHOU D. Factors controlling geochemical and mineralogical compositions of coals preserved within marine carbonate successions:A case study from the Heshan Coalfield, Southen China[J]. Int J Coal Geol, 2013,109:77-100.
12. [12]
  ZHAO Q J, NIU Y J, XIE Z Z, ZHANG K M, ZHOU J M, ARBUZOV S I. Geochemical characteristics of elements in coal seam 4₁ and 4₂ of Heshan Coalfield, South China[J]. Energy Explor Exploit, 2020,38(1):137-157.
13. [13]
  KONTENSKI J, KOSTOVA I. Occurrence and morphology of pyrite in Bulgarian coals[J]. Int J Coal Geol, 1996,29(4):273-290.
14. [14]
  GE Yun-pei, XIE Guang-qian, ZENG Bai-heng, CHARLES A W. The pyrite in the coal and organic sulfur in its vicinity[J]. J Fuel Chem Technol, 1992,20(1):92-97.
15. [15]
  YUAN Li. Geological genesis of the high sulfur coal from southwestern Guizhou-Analysis of pyrite and sulfur isotope[D]. Xuzhou: China University of Mining and Technology, 2014.
16. [16]
  NI Jian-yu, HONG Ye-tang. Sulfur isotopic composition of late Permian coal from Guizhou province[J]. Geol Geochem, 1999,27(2):63-69.
17. [17]
  XIAO Xian-ming, MAO He-ling. Optical evolution of exinite euring coalification based on the discovery of the an isotropical exinite[J]. Acta Sedimentol Sin, 1991,9(1):87-96.
18. [18]
  LIU Chao-lin, YAO Zhi-wen, WU De-yun. Relationship between organic geochemical characteristics and coal gasification of main coal species in Anhui province[J]. Acta Sedimentol Sin, 1983,1(2):17-30.
19. [19]
  JIA Ji-hong, BAI Yi-jun, WANG Xiao-feng, ZHANG Ping-zhong, SANG Wen-cui, ZHANG De-zhong, ZHANG Hong, WANG Yong-li, MENG Qian-xiang. Geochemical significance of the Saturated Hydrocarbons of Limnological Sediments from Ruoergai Plateau[J]. Acta Sediment Sin, 2012,30(4):755-760.
20. [20]
  ZHANG M, HUANG G H, LI H B, HU G Y, ZHANG S C. Molecular geochemical characteristics of gas source rocks from the upper triassic xujiahe formation indicate transgression events in the sichuan basin[J]. Sci China Ser D:Earth Sci, 2012,55(8):1260-1268.
21. [21]
  LI Wei-wei. Geochemistry of Super-high-organic-sulfur Coals from Chenxi, Hunan and Gelogical Origin of the Sulfur[D]. Beijing: China University of Mining and Technology, 2013.
22. [22]
  HE Yu, ZHANG Min, CHEN Xiao-hui, GONG Jian-ming, LI Yong-hong, WANG Wei-chao, LEI Tian-zhu. Geochemical characteristics of saturated hydrocarbon in coal-measure source rocks from muli permafrost, Qinghai[J]. Sci Technol Eng, 2015,32(15):121-128.
23. [23]
  XIE S C, WANG Z Y, WANG H M, CHEN F H, AN C B. The occurrence of a grassy vegetation over the chinese loess plateau since the last interglacier:The molecular fossil record[J]. Sci China Ser D:Earth Sci, 2002,45(1):53-62.
24. [24]
  DONG Jia-guo. Plant fossils were first discovered in Heshan Coalfield[J]. Coal Geol Explor, 1984(1)2.
25. [25]
  ZHUO Yue. Sedimentary characteristics and coal-forming environment of the Heshan formation in the Middle Perm, Guizhou[J]. Coal Geol Explor, 1980(3):1-7.
26. [26]
  WANG Hui-tong, ZHANG Shui-chang, WENG Na, WEI Xiao-fang, ZHU Guang-you, YU Han, BI Li-na, MA Wen-ling. Insight of unresolved complex mixtures of saturated hydrocarbons in heavy oil via GCxGC-TOF MS analyses[J]. Sci China-Chem, 2012,42(10):1469-1478.
27. [27]
  SANG Shu-xun, LIU Huan-jie, SHI Jian. Study of sulphur and its genesis in mangrove peats of Hainan island[J]. Coal Geol Explor, 1993,21(1):12-17.
28. [28]
  PETERS K E, WALTERS C C, MOLDWAN J M. The Biomarker Guider(2nd Edition)[M]. New York: Cambridge University Press, 2005.
29. [29]
  CHEN Ju-lin. Thermal Effect on Rearranged Hopanes Composition in source rocks and study on its Formation mechanism[D]. Jingzhou: Yangtze University, 2017.
30. [30]
  PETERS K E, MOLDOWAN J M. The Biomarker Guide: Interpreting Molecular Fossils in Petroleum and Ancient Sediments[M]. New Jersey: Prentice Hall, 1993.
31. [31]
  ZHANG Li-ping, HUANG Di-fan, LIAO Zhi-qin. Gammacerane-geochemical indicator of water column stratification[J]. Acta Sediment Sin, 1999,17(1):136-140.
32. [32]
  VOLKMAN J K. Biological marker compounds as indicators of the depositional environments of petroleum source rocks[J]. Geol Soc London Spe Pub, 1988,40(1):103-122.
33. [33]
  PETERS K E, MOLDWAN J M, SUNDARARAMAN P. Effects of hydrous pyrolysis on biomarker thermal maturity parameters:Monterey phosphatic and siliceous members[J]. Org Geochem, 1990,15(3):249-265.
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