Citation: Liu Panpan, Jia Zhenxin, Lv Junjun, Yang Fucheng, Luo Yuxin, Gao Hongyi. An Overview on Organic-Inorganic Composite Aerogels[J]. Chemistry, ;2019, 82(10): 867-877. shu

An Overview on Organic-Inorganic Composite Aerogels

1.
School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083
2.
School of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029

Corresponding author: Gao Hongyi, hygao2009@163.com
Received Date: 16 May 2019
Accepted Date: 22 June 2019

Figures(16)

Aerogels have excellent properties such as low density, low thermal conductivity, high specific surface area and high porosity, which have a good application prospect in the fields of heat insulation, sensing, catalysis, adsorption and energy storage. However, the porous network structure of aerogels also causes low strength and poor toughness, which seriously restricts their practical application. Organic-inorganic composite process is an effective method to enhance the mechanical properties of aerogels. It has been found in recent years that the preparation of aerogels by organic-inorganic composite method can also impart other novel properties to aerogels such as flame retardancy. In this paper the new research progress in organic-inorganic composite aerogels was summerized, and its principle, synthetic methods and related properties were analyzed. Finally, the advantages, problems and the future development direction of organic-inorganic composite aerogels were discussed.
- Organic-inorganic composite,
- Synthesis method,
- Principle,
- Mechanical properties,
- Flame retardancy
1. [1]
  C Lei, Z Hu, Y Zhang et al. Micropor. Mesopor. Mater., 2018, 258:236~243.
2. [2]
  A C Pierre, G M Pajonk. Chem. Rev., 2002, 102(11):4243~4266.
3. [3]
  Q Liu, A W Frazier, X Zhao et al. Nano Energy, 2018, 48:266~274.
4. [4]
  J Kehrle, T K Purkait, S Kaiser et al. Langmuir, 2018, 34(16):4888~4896.
5. [5]
  S Ghasemi, S Karim. Mater. Chem. Phys., 2018, 205:347~358.
6. [6]
  S Salimian, A Zadhoush, A Mohammadi. J. Reinf. Plast. Comp., 2018, 37(7):441~459.
7. [7]
  M Cai, S Shafi, Y Zhao. J. Non-Cryst Solids, 2018, 481:622~626.
8. [8]
  Y Huang, L Gong, Y Pan et al. RSC Adv., 2018, 8(5):2350~2356.
9. [9]
  L A Capadona, M A B Meador, A Alunni et al. Polymer, 2006, 47(16):5754~5761.
10. [10]
  Z Wu, L Zhang, J Li et al. RSC Adv., 2018, 8(11):5695~5701.
11. [11]
  H Maleki, L Durães, A Portugal. J. Non-Cryst Solids, 2014, 385:55~74.
12. [12]
  D A Loy, K J Shea. Chem. Rev., 1995, 95(5):1431~1442.
13. [13]
  J Morell, G Wolter, M Fröba. Chem. Mater., 2005, 17(4):804~808.
14. [14]
  S Yun, H Luo, Y Gao. J. Mater. Chem. A, 2014, 2(35):14542~14549.
15. [15]
  Z D Shao, X Cheng, Y M Zheng. J. Colloid Interf. Sci., 2018, 530:412~423.
16. [16]
  H Maleki, L Durães, A Portugal. Mater. Lett., 2016, 179:206~209.
17. [17]
  P R Aravind, P Niemeyer, L Ratke. Micropor. Mesopor. Mater., 2013, 181:111~115.
18. [18]
  V G Parale, K Y Lee, H Y Nah et al. Ceram. Int., 2018, 44(4):3966~3972.
19. [19]
  S Yun, H Luo, Y Gao. J. Mater. Chem. A, 2015, 3(7):3390~3398.
20. [20]
  Z Wang, Z Dai, J Wu et al. Adv. Mater., 2013, 25(32):4494~4497.
21. [21]
  F Zou, P Yue, X Zheng et al. J. Mater. Chem. A, 2016, 4(28):10801~10805.
22. [22]
  D Chen, H Gao, Z Jin et al. ACS Appl. Nano Mater., 2018, 1(2):933~939.
23. [23]
  D Chen, H Gao, P Liu et al. RSC Adv., 2019, 9(15):8664~8671.
24. [24]
  S Iswar, G M B F Snellings, S Zhao et al. Acta Mater., 2018, 147:322~328.
25. [25]
  D J Boday, R J Stover, B Muriithi et al. J. Mater. Sci., 2011, 46(19):6371~6377.
26. [26]
  M Aghabararpour, M Mohsenpour, S Motahari et al. J. Non-Cryst Solids, 2018, 481:548~555.
27. [27]
  M A B Meador, C M Scherzer, S L Vivod et al. ACS Appl. Mater. Intef., 2010, 2(7):2162~2168.
28. [28]
  H Guo, M A B Meador, L McCorkle et al. ACS Appl. Mater. Intef., 2011, 3(2):546~552.
29. [29]
  B N Nguyen, M A B Meador, M E Tousley et al. ACS Appl. Mater. Intef., 2009, 1(3):621~630.
30. [30]
  T Shimizu, K Kanamori, A Maeno et al. Chem. Mater., 2016, 28(19):6860~6868.
31. [31]
  H Maleki, L Durǎes, A Portugal. J. Phys. Chem. C, 2015, 119(14):7689~7703.
32. [32]
  B N Nguyen, M A B Meador, A Medoro et al. ACS Appl. Mater. Intef., 2010, 2(5):1430~1443.
33. [33]
  G Zu, T Shimizu, K Kanamori et al. ACS Nano, 2018, 12(1):521~532.
34. [34]
  G Zu, K Kanamori, T Shimizu et al. Chem. Mater., 2018, 30(8):2759~2770.
35. [35]
  G Zu, K Kanamori, A Maeno et al. Angew. Chem. Int. Ed., 2018, 57(31):9722~9727.
36. [36]
  J Zhang, Y Cheng, M Tebyetekerwa et al. Adv. Funct. Mater., 2019:1806407.
37. [37]
  Z L Yu, N Yang, V Apostolopoulou-Kalkavoura et al. Angew. Chem. Int. Ed., 2018, 57(17):4538~4542.
38. [38]
  W Fan, L Zuo, Y Zhang et al. Compos. Sci. Technol., 2018, 156:186~191.
39. [39]
  W Guo, J Liu, P Zhang et al. Compos. Sci. Technol., 2018, 158:128~136.
40. [40]
  G Zhu, H Xu, A Dufresne et al. ACS Sustain. Chem. Eng., 2018, 6(5):7168~7180.
41. [41]
  Y Li, X Liu, X Nie et al. Adv. Funct. Mater., 2018:1807624.
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沈阳化工大学材料科学与工程学院沈阳 110142