Citation: GUO Yuan-yuan, HOU Bo, WANG Jun-gang, JIA Li-tao, LI De-bao. Preparation of ZrO₂ modified Al₂O₃ nano-sheets supported cobalt catalyst and its performance in Fischer-Tropsch synthesis[J]. Journal of Fuel Chemistry and Technology, ;2019, 47(5): 540-548. shu

Preparation of ZrO₂ modified Al₂O₃ nano-sheets supported cobalt catalyst and its performance in Fischer-Tropsch synthesis

GUO Yuan-yuan ^1,2 ,
HOU Bo ^1,, ,
WANG Jun-gang ¹ ,
JIA Li-tao ^1,3 ,
LI De-bao ^1,3,,

1.
State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China
2.
University of Chinese Academy of Sciences, Beijing 100049, China
3.
Dalian National Laboratory for Clean Energy, Dalian 116023, China

Corresponding author: HOU Bo, houbo@sxicc.ac.cn LI De-bao, dbli@sxicc.ac.cn
Received Date: 16 January 2019
Revised Date: 3 March 2019

Fund Project: The project was supported by the National Natural Science Foundation of China (21872162, U1710104, 21703273, 21706271), the "Transformational Technologies for Clean Energy and Demonstration" and Strategic Priority Research Program of the Chinese Academy of Sciences (XDA 21020202)Strategic Priority Research Program of the Chinese Academy of Sciences XDA 21020202the National Natural Science Foundation of China 21872162the National Natural Science Foundation of China 21706271the National Natural Science Foundation of China U1710104the National Natural Science Foundation of China 21703273

Figures(9)

Al₂O₃ nano-sheet (Al₂O₃-CN) was synthesized under hydrothermal condition. The cobalt-based catalyst of 20% (mass fraction) was prepared by impregnation method and applied to Fischer-Tropsch synthesis. The Al₂O₃-CN (226 m²/g) and commercial alumina (Al₂O₃-C, 249 m²/g) have similar specific surface area, but Al₂O₃-CN has more narrow pore size distribution. Compared with Co/Al₂O₃-C catalyst, Co/Al₂O₃-CN catalyst showed higher reduction degree and more uniform cobalt particle size distribution after impregnation. Thus, Co/Al₂O₃-CN catalyst exhibited higher CO conversion and lower methane selectivity. In order to further improve the catalytic performance of Co/Al₂O₃-CN, Al₂O₃-CN was modified with ZrO₂. The characterization results showed that with the increase of ZrO₂, the specific surface of Al₂O₃-CN did not change significantly, and the pore volume and pore diameter increased. The cobalt particle size decreased and the number of active sites increased. Under the same reaction conditions, the CO conversion rate of catalysts modifield by ZrO₂ was farther improved and selectivity of methane was decreased.
- Fischer-Tropsch synthesis,
- zirconium additives,
- alumina,
- nano-sheets
1. [1]
  MUNNIK P, DE JONGH P E, DE JONG K P. Recent developments in the synthesis of supported catalysts[J]. Chem Rev, 2015,115(4):6687-6718.
2. [2]
  SUN Yu-han, CHEN Jian-gang, WANG Jun-gang, JIA Li-tao, HOU Bo, LI De-bao, ZHANG Juan. The development of cobalt-based catalysts for fischer-tropsch synthesis[J]. Chin J Catal, 2010,31(8):919-927.
3. [3]
  KHODAKOV A Y, CHU W, FONGARLAND P. Advances in the development of novel cobalt fischer-tropsch catalysts for synthesis of long-chain hydrocarbons and clean fuels[J]. Chem Rev, 2007,107(5):1692-1744. doi: 10.1021/cr050972v
4. [4]
  STORSÆTER S, TØTDAL B, WALMSLEY J C, TANEM B S, HOLMEN A. Characterization of alumina-, silica-, and titania-supported cobalt Fischer-Tropsch catalysts[J]. J Catal, 2005,236(1):139-152.
5. [5]
  LI Jin-lin, WAN You-jun, ZHANG Yu-hua, XIONG Hai-feng. Studies on the reduction process of the supported cobalt catalysis for Fischer-Tropsch Synthesis[J]. J South-Cent Univ Nat(Nat Sci Ed), 2007,26(2):1-6. doi: 10.3969/j.issn.1672-4321.2007.02.001
6. [6]
  LI Jia-bo, LIN Quan. Supporter modification of Fischer-Tropsch cobalt catalyst[J]. Clean Coal Technol, 2015,21(1):65-68.
7. [7]
  BAO A, LIEW K Y, LI J L. Fischer-Tropsch synthesis on CaO-promoted Co/Al₂O₃ catalysts[J]. J Mol Catal A:Chem, 2009,304(1/2):47-51.
8. [8]
  YUAN Q, YIN A X, LUO C, SUN L D, ZHANG Y W, DUAN W T, LIU H C, YAN C H. Facile synthesis for ordered mesoporous γ-aluminas with high thermal stability[J]. J Am Chem Soc, 2008,130(11):3465-3472. doi: 10.1021/ja0764308
9. [9]
  LI X, HAN D Z, XU Y Q, LIU X M, YAN Z F. Bimodal mesoporous γ-Al₂O₃:A promising support for CoMo-based catalyst in hydrodesulfurization of 4, 6-DMDBT[J]. Mater Lett, 2011,65(12):1765-1767. doi: 10.1016/j.matlet.2011.03.037
10. [10]
  MARTÍNEZ A, PRIETO G, ROLLAN J. Nanofibrous γ-Al₂O₃ as support for cobased Fischer-Tropsch catalysts:Pondering the relevance of diffusional and dispersion effects on catalytic performance[J]. J Catal, 2009,263(2):292-305.
11. [11]
  LIU C C, LI J L, ZHANG Y H, CHEN S F, ZHU J J, LIEW K Y. Fischer-Tropsch synthesis over cobalt catalysts supported on nanostructured alumina with various morphologies[J]. J Mol Catal A:Chem, 2012,363/364:335-342. doi: 10.1016/j.molcata.2012.07.009
12. [12]
  WANG W W, ZHOU J B, ZHANG Z, YU J G, CAI W Q. Different surfactants-assisted hydrothermal synthesis of hierarchical γ-Al₂O₃ and its adsorption performances for parachlorophenol[J]. Chem Eng J, 2013,233:168-175. doi: 10.1016/j.cej.2013.08.029
13. [13]
  NABAHO D, NIEMANTSVERDRIET J W, CLAEYS M, STEEN E. Hydrogen spillover in the Fischer-Tropsch synthesis:An analysis of platinum as a promoter for cobalt-alumina catalysts[J]. Catal Today, 2016,261:17-27. doi: 10.1016/j.cattod.2015.08.050
14. [14]
  JACOBS G, CHANRY J A, PATTERSON P M, DAS T K, DAVIS B H. Fischer-Tropsch synthesis:Study of the promotion of Re on the reduction property of Co/Al₂O₃ catalysts by in situ EXAFS/XANES of Co K and Re LⅢ edges and XPS[J]. Appl Catal A:Gen, 2004,264(2):203-212. doi: 10.1016/j.apcata.2003.12.049
15. [15]
  JONGSOMJIT B, PANPRANOT J, GOODWIN JR J G. Effect of zirconia-modified alumina on the properties of Co/γ-Al₂O₃ catalysts[J]. J Catal, 2003,215(1):66-77.
16. [16]
  ZHANG Y H, XIONG H F, LIEW K Y, LI J L. Effect of magnesia on alumina-supported cobalt Fischer-Tropsch synthesis catalysts[J]. J Mol Catal A:Chem, 2005,237(1/2):172-181.
17. [17]
  DAI X P, YU C C, SHEN S K. Promotion effect of ceria on Fischer-Tropsch synthesis performance over Co/Al₂O₃ catalyst[J]. Chin J Catal, 2001,22:104-108.
18. [18]
  MA C L, CHANG Y L, YE W C, DUAN L Y, WANG C M. Hexagon γ-alumina nanosheets produced with the assistance of supercritical ethanol drying[J]. J Supercrit Fluids, 2008,45:112-120. doi: 10.1016/j.supflu.2008.01.001
19. [19]
  LI G C, GUAN L L, LIU Y Q, LIU C G. Template-free solvothermal synthesis of 3D hierarchical nanostructured boehmite assembled by nanosheets[J]. J Phys Chem Solids, 2012,73:1055-1060. doi: 10.1016/j.jpcs.2012.04.014
20. [20]
  YANG Y F, JIA L T, MENG Y, HOU B, LI D B, SUN Y H. Fischer-Tropsch synthesis over ordered mesoporous carbon supported cobalt catalysts:The role of amount of carbon precursor in catalytic performance[J]. Catal Lett, 2012,142(2):195-204.
21. [21]
  KOGELBAUER A, GOODWIN J G, QUKACI R. Ruthenium promotion of Co/Al₂O₃ Fischer-Tropsch catalysts[J]. J Catal, 1996,160(1):125-133.
22. [22]
  SEXTON B A, HUGHES A E, TURNEY T W. An XPS and TPR study of the reduction of promoted cobalt-kieselguhr Fischer-Tropsch catalysts[J]. J Catal, 1986,97(2):390-406.
23. [23]
  XIONG H F, ZHANG Y H, LIEW K Y, LI J L. Catalytic performance of zirconium-modified Co/Al₂O₃for Fischer-Tropsch synthesis[J]. J Mol Catal A:Chem, 2005,231(1/2):145-151.
24. [24]
  CHU W, CHERNAVSKⅡ P A, GENGEMBRE L, PANKINA G A, FONGARLAND P, KHODAKOV A Y. Cobalt species in promoted cobalt alumina-supported Fischer-Tropsch catalysts[J]. J Catal, 2007,252(2):215-230. doi: 10.1016/j.jcat.2007.09.018
25. [25]
  BEZEMER G L, BITTER J H, KUIPERS H P C E, OOSTERBEEK H, HOLEWIJN J E, XU X D, KAPTEIJN F, JOS VAN DILEN A, DE JONG K P. Cobalt particle size effects in the fischer-tropsch reaction studied with carbon nanofiber supported catalysts[J]. J Am Chem Soc, 2006,128(12):3956-3964. doi: 10.1021/ja058282w
26. [26]
  DEN BREEJEN J P, RADSTAKE P B, BEZEMER G L, BITTER J H, FRØSRTH V, HOLMEN A, DE JONG K P. On the origin of the cobalt particle size effects in Fischer-Tropsch catalysis[J]. J Am Chem Soc, 2009,131(20):7197-7203. doi: 10.1021/ja901006x
27. [27]
  JOHNSON G R, BELL A T. Role of ZrO₂ in promoting the activity and selectivity of Co-based Fischer-Tropsch synthesis catalysts[J]. ACS Catal, 2016,6(1):100-114.
1. [1]
  Guoqiang Chen , Zixuan Zheng , Wei Zhong , Guohong Wang , Xinhe Wu . Molten Intermediate Transportation-Oriented Synthesis of Amino-Rich g-C₃N₄ Nanosheets for Efficient Photocatalytic H₂O₂ Production. Acta Physico-Chimica Sinica, 2024, 40(11): 2406021-0. doi: 10.3866/PKU.WHXB202406021
2. [2]
  Peng YUE , Liyao SHI , Jinglei CUI , Huirong ZHANG , Yanxia GUO . Effects of Ce and Mn promoters on the selective oxidation of ammonia over V₂O₅/TiO₂ catalyst. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 293-307. doi: 10.11862/CJIC.20240210
3. [3]
  Wenjie SHI , Fan LU , Mengwei CHEN , Jin WANG , Yingfeng HAN . Synthesis and host-guest properties of imidazolium-functionalized zirconium metal-organic cage. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 105-113. doi: 10.11862/CJIC.20240360
4. [4]
  Zhuoya WANG , Le HE , Zhiquan LIN , Yingxi WANG , Ling LI . Multifunctional nanozyme Prussian blue modified copper peroxide: Synthesis and photothermal enhanced catalytic therapy of self-provided hydrogen peroxide. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2445-2454. doi: 10.11862/CJIC.20240194
5. [5]
  Gaopeng Liu , Lina Li , Bin Wang , Ningjie Shan , Jintao Dong , Mengxia Ji , Wenshuai Zhu , Paul K. Chu , Jiexiang Xia , Huaming Li . Construction of Bi Nanoparticles Loaded BiOCl Nanosheets Ohmic Junction for Photocatalytic CO₂ Reduction. Acta Physico-Chimica Sinica, 2024, 40(7): 2306041-0. doi: 10.3866/PKU.WHXB202306041
6. [6]
  Jiao CHEN , Yi LI , Yi XIE , Dandan DIAO , Qiang XIAO . Vapor-phase transport of MFI nanosheets for the fabrication of ultrathin b-axis oriented zeolite membranes. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 507-514. doi: 10.11862/CJIC.20230403
7. [7]
  Huanhuan XIE , Yingnan SONG , Lei LI . Two-dimensional single-layer BiOI nanosheets: Lattice thermal conductivity and phonon transport mechanism. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 702-708. doi: 10.11862/CJIC.20240281
8. [8]
  Weihan Zhang , Menglu Wang , Ankang Jia , Wei Deng , Shuxing Bai . Surface Sulfur Species Influence Hydrogenation Performance of Palladium-Sulfur Nanosheets. Acta Physico-Chimica Sinica, 2024, 40(11): 2309043-0. doi: 10.3866/PKU.WHXB202309043
9. [9]
  Yu Wang , Shoulei Zhang , Tianming Lv , Yan Su , Xianyu Liu , Fuping Tian , Changgong Meng . Introduce a Comprehensive Inorganic Synthesis Experiment: Synthesis of Nano Zinc Oxide via Microemulsion Using Waste Soybean Oil. University Chemistry, 2024, 39(7): 316-321. doi: 10.3866/PKU.DXHX202311035
10. [10]
  Pengyu Dong , Yue Jiang , Zhengchi Yang , Licheng Liu , Gu Li , Xinyang Wen , Zhen Wang , Xinbo Shi , Guofu Zhou , Jun-Ming Liu , Jinwei Gao . NbSe₂ Nanosheets Improved the Buried Interface for Perovskite Solar Cells. Acta Physico-Chimica Sinica, 2025, 41(3): 2407025-0. doi: 10.3866/PKU.WHXB202407025
11. [11]
  Yang Li , Jiachen Li , Daidi Fan . 二硫化钼纳米片的制备及其纳米酶性能探究——介绍一个大学化学综合实验. University Chemistry, 2025, 40(8): 233-240. doi: 10.12461/PKU.DXHX202410016
12. [12]
  Junli Liu . Practice and Exploration of Research-Oriented Classroom Teaching in the Integration of Science and Education: a Case Study on the Synthesis of Sub-Nanometer Metal Oxide Materials and Their Application in Battery Energy Storage. University Chemistry, 2024, 39(10): 249-254. doi: 10.12461/PKU.DXHX202404023
13. [13]
  Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
14. [14]
  Fanpeng Meng , Fei Zhao , Jingkai Lin , Jinsheng Zhao , Huayang Zhang , Shaobin Wang . Optimizing interfacial electric fields in carbon nitride nanosheet/spherical conjugated polymer S-scheme heterojunction for hydrogen evolution. Acta Physico-Chimica Sinica, 2025, 41(8): 100095-0. doi: 10.1016/j.actphy.2025.100095
15. [15]
  Shiyang He , Dandan Chu , Zhixin Pang , Yuhang Du , Jiayi Wang , Yuhong Chen , Yumeng Su , Jianhua Qin , Xiangrong Pan , Zhan Zhou , Jingguo Li , Lufang Ma , Chaoliang Tan . Pt Single-Atom-Functionalized 2D Al-TCPP MOF Nanosheets for Enhanced Photodynamic Antimicrobial Therapy. Acta Physico-Chimica Sinica, 2025, 41(5): 100046-0. doi: 10.1016/j.actphy.2025.100046
16. [16]
  Zehao Zhang , Zheng Wang , Haibo Li . Preparation of 2D V₂O₃@Pourous Carbon Nanosheets Derived from V₂CF_x MXene for Capacitive Desalination. Acta Physico-Chimica Sinica, 2024, 40(8): 2308020-0. doi: 10.3866/PKU.WHXB202308020
17. [17]
  Qin Li , Huihui Zhang , Huajun Gu , Yuanyuan Cui , Ruihua Gao , Wei-Lin Dai . In situ Growth of Cd_0.5Zn_0.5S Nanorods on Ti₃C₂ MXene Nanosheet for Efficient Visible-Light-Driven Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2025, 41(4): 2402016-0. doi: 10.3866/PKU.WHXB202402016
18. [18]
  Mengfei He , Chao Chen , Yue Tang , Si Meng , Zunfa Wang , Liyu Wang , Jiabao Xing , Xinyu Zhang , Jiahui Huang , Jiangbo Lu , Hongmei Jing , Xiangyu Liu , Hua Xu . Epitaxial Growth of Nonlayered 2D MnTe Nanosheets with Thickness-Tunable Conduction for p-Type Field Effect Transistor and Superior Contact Electrode. Acta Physico-Chimica Sinica, 2025, 41(2): 2310029-0. doi: 10.3866/PKU.WHXB202310029
19. [19]
  Heng Chen , Longhui Nie , Kai Xu , Yiqiong Yang , Caihong Fang . Remarkable Photocatalytic H₂O₂ Production Efficiency over Ultrathin g-C₃N₄ Nanosheet with Large Surface Area and Enhanced Crystallinity by Two-Step Calcination. Acta Physico-Chimica Sinica, 2024, 40(11): 2406019-0. doi: 10.3866/PKU.WHXB202406019
20. [20]
  Zijian Jiang , Yuang Liu , Yijian Zong , Yong Fan , Wanchun Zhu , Yupeng Guo . Preparation of Nano Zinc Oxide by Microemulsion Method and Study on Its Photocatalytic Activity. University Chemistry, 2024, 39(5): 266-273. doi: 10.3866/PKU.DXHX202311101

Get Citation

PDF

XML

Metrics

PDF Downloads(6)
Abstract views(664)
HTML views(36)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation of ZrO2 modified Al2O3 nano-sheets supported cobalt catalyst and its performance in Fischer-Tropsch synthesis

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation of ZrO₂ modified Al₂O₃ nano-sheets supported cobalt catalyst and its performance in Fischer-Tropsch synthesis