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Citation: LAI CHU-GEN, LU JIA-LIN, FANG YAO-REN, BAO FI-YI. THE KINETICS OF POLYESTERIFICATION, ESTERIFICATION, AND HYDROLYSIS OF ESTER[J]. Acta Polymerica Sinica, ;1965, 7(6): 373-385. shu

THE KINETICS OF POLYESTERIFICATION, ESTERIFICATION, AND HYDROLYSIS OF ESTER

Received Date: 20 August 1964

In polyesterification, the action of alcohol as a carrier of H+-ion was supposed to be negligable, in contrast to the result obtained by Tang Au-Ching. A new hypothesis of polyesterification was then suggested.This mechanism can be used to explain some other types of esterification as well. Favourable results were obtained even if p (the percent of the theoretical degree of reaction) is greater than 91%. In the hydrolysis of esters by using strong or weak acid as catalysts, results obtained were found to be better than those obtained by previous authors.
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