Citation: Heng JIANG, Yun XU, Shi Jian LIAO, Dao Rong YU, Hua CHEN, Xian Jun LI. Carbonylation of Allyl Chloride Catalyzed by PdCl₂(TPPTS)₂ in Two-phase Medium[J]. Chinese Chemical Letters, ;1996, 7(9): 847-848. shu

Carbonylation of Allyl Chloride Catalyzed by PdCl₂(TPPTS)₂ in Two-phase Medium

a Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023;
b Department of Chemistry, Sichuan University, Chengdu 610064

Received Date: 2 April 1996

Fund Project: This work was supported by the National Natural Science Foundation of China and the Laboratory of Organometallic Chemistry,Shanghai Institute of Organic Chemistry,Chinese Academy of Sciences.

PdCl₂ (TPPTS) ₂ exhibits very high catalytic activity for carbonylation of allyl chloride in aq. NaOH/toluene two-phase medium under atmospheric pressure. The average turnover frequency (TOFav, mol substrate/mol Pd·min) reaches 31 min^-1.
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