Citation: ZHANG Lu-lu, ZHAN Jin-you, SUN Yao, SHEN Jian. Preparation of WO₃-TiO₂/SBA-15 catalyst and its photocatalytic performance in oxidative desulfurization[J]. Journal of Fuel Chemistry and Technology, ;2016, 44(6): 754-762. shu

Preparation of WO₃-TiO₂/SBA-15 catalyst and its photocatalytic performance in oxidative desulfurization

College of Petrochemical Engineering, Liaoning Shihua University, Fushun 113001, China

Corresponding author: SHEN Jian, lnshenjian@126.com
Received Date: 28 October 2015
Revised Date: 16 December 2015

Figures(15)

WO₃-TiO₂/SBA-15 catalyst was prepared by inner-pore hydrolysis method; it was characterized by XRD, SEM, EDS, N₂ sorption, FT-IR, TG-DTA and UV-vis and used in the photocatalytic oxidative desulfurization of diesel oil. The effects of WO₃ and TiO₂ loading and calcination temperature and time on the performance of the WO₃-TiO₂/SBA-15 catalyst in its photocatalytic oxidative desulfurization were investigated. The results indicated that the optimum loadings of WO₃ and TiO₂ were 1.6% and 15%, respectively, and corresponding calcination temperature and time were 500℃ and 3h, respectively. Over the WO₃-TiO₂/SBA-15 catalyst prepared under the optimum conditions, in which the hexagonal mesoporous structure was well retained, the desulfurization rate of model diesel oil reached 87.9%. Moreover, the WO₃-TiO₂/SBA-15 catalyst also exhibited excellent reusability after regeneration.
- WO₃-TiO₂/SBA-15,
- photocatalysis,
- oxidative desulfurization,
- diesel oil
1. [1]
  ACHMANN S, HAGEN G, HÄMMERLE M, MALKOWSKY I M, KIENER C, MOOS R. Sulfur removal from low-sulfur gasoline and diesel fuel by metal-organic frameworks[J]. Chem Eng Technol, 2010,33(2):275-280. doi: 10.1002/ceat.v33:2
2. [2]
  XIE D, HE Q H, SU YY, WANG T W, XU R F, HU B X. Oxidative desulfurization of dibenzothiophene catalyzed by peroxotungstate on functionalized MCM-41 materials using hydrogen peroxide as oxidant[J]. Chin J Catal, 2015,36(8):1205-1213. doi: 10.1016/S1872-2067(15)60897-X
3. [3]
  ZHANG Wen-ling, WAN Kun, YU Guo-xian, ZHOU Xiao-long, LI Cheng-lie. Preparation of adsorbent for desulfurlzation of diesel fuel through activating rice hull by phosphoric acid[J]. Acta Pet Sin (Pet Proc Sect), 2010,26(4):588-593.
4. [4]
  FANG X A, GUO R A, YANG C M. The development and application of catalysts for ultra-deep hydrodesulfurization of diesel[J]. Chin J Catal, 2013,34(1):130-139. doi: 10.1016/S1872-2067(11)60506-8
5. [5]
  WANG C, ZHU W S, XU Y H, XU H, ZHANG M, CHAO Y H, YIN S, LI H M, WANG J G. Preparation of TiO₂/g-C₃N₄ composites and their application in photocatalytic oxidative desulfurization[J]. Ceram Int, 2014,40(8):11627-11635. doi: 10.1016/j.ceramint.2014.03.156
6. [6]
  ZHANG J, ZHAO D S, WANG J L, YANG L Y. Photocatalytic oxidation of dibenzothiophene using TiO₂/bamboo charcoal[J]. J Mater Sci, 2009,44(12):3112-3117. doi: 10.1007/s10853-009-3413-z
7. [7]
  KACHINA A, PREIS S, KALLAS J. Catalytic TiO₂ oxidation of ethanethiol for environmentally begnin air pollution control of sulphur compounds[J]. Environ Chem Lett, 2006,4(2):107-110. doi: 10.1007/s10311-006-0042-5
8. [8]
  TACHIKAWA T, FUJITSUKA M, MAJIMA T. Mechanistic insight into the TiO₂ photocatalytic reactions:65 design of new photocatalysts[J]. J Phys Chem C, 2007,111(14):5259-5275. doi: 10.1021/jp069005u
9. [9]
  FENG Xiang, SHI Fei, LIU Jing-xiao, DONG Xiao-li, BAI Lu-nan, WANG Xiao-ka, ZHANG Xiu-fang. Hydrothermal synthesis and photocatalytic activity of WO₃-TiO₂ composite photocatalysts[J]. Mater Rev, 2013,27(22):37-40.
10. [10]
  LU Cheng, YANG Ping, DU Yu-kou, HUA Nan-ping, SONG Hai-yan. Effects of supports on photocatalytic performance of supported TiO₂ catalysts[J]. Chin J Catal, 2003,24(4):248-252.
11. [11]
  JI Gui-jie, ZHANG Yao-bing, FU Ning-ning, TANG Lei, LIU Peng, SHEN Jian. Preparation and adsorption desulfurization performance of Mn/Al-SBA-15[J]. J Fuel Chem Technol, 2015,43(4):449-455.
12. [12]
  WANG Zhe, JI Gui-jie, SHEN Jian. Study of photocatalytic oxidative desulfurization of gasoline with TiO₂/SBA-15[J]. Pet Process Petrochem, 2015,46(4):51-54.
13. [13]
  ZHAO D Y, FENG J L, HUO Q S, MELOSH N, FREDRICKSON G H, CHMELKA B F, STUCKY G D. Triblock copolymer syntheses of mesoporous silica with periodic 50 to 300 angstrom pores[J]. Science, 1998,279(5350):548-552. doi: 10.1126/science.279.5350.548
14. [14]
  MA Jing, QIANG Liang-sheng, TANG Xiang-bo, TANG Dong-yan. TiO₂/SBA-15:Rapid synthesis and photocatalytic performance[J]. Chin J Inorg Chem, 2010,26(6):963-969.
15. [15]
  WANG X J, LI F T, LIU J X, KOU C G, ZHAO Y, HAO Y J, ZHAO D S. Preparation of TiO₂ in ionic liquid via microwave radiation and in situ photocatalytic oxidative desulfurization of diesel oil[J]. Energy Fuels, 2012,26(11):6777-6782.
16. [16]
  LIU Yang, WANG Sheng, WANG Tao, XU Zhang-lian, CHEN Wen-xing, JIANG Jie, WEI Jian-hong. Preparation of WO₃/TiO₂nanorod composites and its photocatalytic activity[J]. Chin J Catal, 2010,31(4):485-489.
17. [17]
  WU Shu-jie, HUANG Jia-hui, WU Tong-hao, SONG Ke, WANG Hong-su, XING Li-hong, XU Hai-yan, XU Ling, GUAN Jing-qi, KAN Qiu-bin. Synthesis, characterization, and catalytic performance of mesoporous Al-SBA-15 for Tert-butylation of phenol[J]. Chin J Catal, 2006,27(1):9-14. doi: 10.1016/S1872-2067(06)60004-1
18. [18]
  BUSUIOC A M, MEYNEN V, BEYERS E, MERTENS M, COOL P, BILBA N, VANSANT E F. Structural features and photocatalytic behaviour of titania deposited within the pores of SBA-15[J]. Appl Catal A:Gen, 2006,312(9):153-164.
19. [19]
  WANG Z H, CHEN B, QUAN G L, LI F, WU Q L, DIAN L H, DONG Y X, LI G, WU C B. Increasing the oral bioavailability of poorly water-soluble carbamazepine using immediate-release pellets supported on SBA-15 mesoporous silica[J]. Int J Nanomed, 2013,7(11):5807-5818.
20. [20]
  CHEN Yang-ying, HAN Xiu-wen, BAO Xin-he. Direct synthesis of W-SBA-15 mesoporous molecular sieves and their catalytic performance for epoxidation of cyclohexene[J]. Chin J Catal, 2005,26(5):412-416.
21. [21]
  PALCHEVA R, SPOJAKINA A, DIMITROV L, JIRATOVA K. 12-Tungstophosphoric heteropolyacid supported on modified SBA-15 as catalyst in HDS of thiophene[J]. Microporous Mesoporous Mater, 2009,122(1/3):128-134.
22. [22]
  HUANG Y, LI K X, YAN L S, DAI Y H, HUANG Z M, XUE K P, GUO H Q, XIONG J J. Preparation of 2D hexagonal p6mm ordered mesoporous WO₃-TiO₂ composite materials and their visible-light photocatalytic activity[J]. Chin J Catal, 2012,33(2):308-316.
23. [23]
  VU T H T, NGUYEN T T T, NGUYEN P H T, DO M H, AU H T, NGUYEN T B, NGUYEN D L, PARK J S. Fabrication of photocatalytic composite of multi-walled carbon nanotubes/TiO₂ and its application for desulfurization of diesel[J]. Mater Res Bull, 2012,47(2):308-314. doi: 10.1016/j.materresbull.2011.11.016
1. [1]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
2. [2]
  Yuanqing Wang , Yusong Pan , Hongwu Zhu , Yanlei Xiang , Rong Han , Run Huang , Chao Du , Chengling Pan . Enhanced Catalytic Activity of Bi₂WO₆ for Organic Pollutants Degradation under the Synergism between Advanced Oxidative Processes and Visible Light Irradiation. Acta Physico-Chimica Sinica, 2024, 40(4): 2304050-0. doi: 10.3866/PKU.WHXB202304050
3. [3]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
4. [4]
  Zijian Jiang , Yuang Liu , Yijian Zong , Yong Fan , Wanchun Zhu , Yupeng Guo . Preparation of Nano Zinc Oxide by Microemulsion Method and Study on Its Photocatalytic Activity. University Chemistry, 2024, 39(5): 266-273. doi: 10.3866/PKU.DXHX202311101
5. [5]
  Xuejiao Wang , Suiying Dong , Kezhen Qi , Vadim Popkov , Xianglin Xiang . Photocatalytic CO₂ Reduction by Modified g-C₃N₄. Acta Physico-Chimica Sinica, 2024, 40(12): 2408005-0. doi: 10.3866/PKU.WHXB202408005
6. [6]
  Haitao Wang , Lianglang Yu , Jizhou Jiang , Arramel , Jing Zou . S-Doping of the N-Sites of g-C₃N₄ to Enhance Photocatalytic H₂ Evolution Activity. Acta Physico-Chimica Sinica, 2024, 40(5): 2305047-0. doi: 10.3866/PKU.WHXB202305047
7. [7]
  Jianyin He , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . Construction of ZnCoP/CdLa₂S₄ Schottky Heterojunctions for Enhancing Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2024, 40(11): 2404030-0. doi: 10.3866/PKU.WHXB202404030
8. [8]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-Based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-0. doi: 10.3866/PKU.WHXB202406029
9. [9]
  Ruolin CHENG , Haoran WANG , Jing REN , Yingying MA , Huagen LIANG . Efficient photocatalytic CO₂ cycloaddition over W₁₈O₄₉/NH₂-UiO-66 composite catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 523-532. doi: 10.11862/CJIC.20230349
10. [10]
  Yulian Hu , Xin Zhou , Xiaojun Han . A Virtual Simulation Experiment on the Design and Property Analysis of CO₂ Reduction Photocatalyst. University Chemistry, 2025, 40(3): 30-35. doi: 10.12461/PKU.DXHX202403088
11. [11]
  Ronghui LI . Photocatalysis performance of nitrogen-doped CeO₂ thin films via ion beam-assisted deposition. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1123-1130. doi: 10.11862/CJIC.20240440
12. [12]
  Jingping Li , Suding Yan , Jiaxi Wu , Qiang Cheng , Kai Wang . Improving hydrogen peroxide photosynthesis over inorganic/organic S-scheme photocatalyst with LiFePO₄. Acta Physico-Chimica Sinica, 2025, 41(9): 100104-0. doi: 10.1016/j.actphy.2025.100104
13. [13]
  Ke Li , Chuang Liu , Jingping Li , Guohong Wang , Kai Wang . Architecting Inorganic/Organic S-Scheme Heterojunction of Bi₄Ti₃O₁₂ Coupling with g-C₃N₄ for Photocatalytic H₂O₂ Production from Pure Water. Acta Physico-Chimica Sinica, 2024, 40(11): 2403009-0. doi: 10.3866/PKU.WHXB202403009
14. [14]
  Jiawei Hu , Kai Xia , Ao Yang , Zhihao Zhang , Wen Xiao , Chao Liu , Qinfang Zhang . Interfacial Engineering of Ultrathin 2D/2D NiPS₃/C₃N₅ Heterojunctions for Boosting Photocatalytic H₂ Evolution. Acta Physico-Chimica Sinica, 2024, 40(5): 2305043-0. doi: 10.3866/PKU.WHXB202305043
15. [15]
  Tong Zhou , Xue Liu , Liang Zhao , Mingtao Qiao , Wanying Lei . Efficient Photocatalytic H₂O₂ Production and Cr(Ⅵ) Reduction over a Hierarchical Ti₃C₂/In₄SnS₈ Schottky Junction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309020-0. doi: 10.3866/PKU.WHXB202309020
16. [16]
  Linfeng Xiao , Wanlu Ren , Shishi Shen , Mengshan Chen , Runhua Liao , Yingtang Zhou , Xibao Li . Enhancing Photocatalytic Hydrogen Evolution through Electronic Structure and Wettability Adjustment of ZnIn₂S₄/Bi₂O₃ S-Scheme Heterojunction. Acta Physico-Chimica Sinica, 2024, 40(8): 2308036-0. doi: 10.3866/PKU.WHXB202308036
17. [17]
  Guoqiang Chen , Zixuan Zheng , Wei Zhong , Guohong Wang , Xinhe Wu . Molten Intermediate Transportation-Oriented Synthesis of Amino-Rich g-C₃N₄ Nanosheets for Efficient Photocatalytic H₂O₂ Production. Acta Physico-Chimica Sinica, 2024, 40(11): 2406021-0. doi: 10.3866/PKU.WHXB202406021
18. [18]
  Yingqi BAI , Hua ZHAO , Huipeng LI , Xinran REN , Jun LI . Perovskite LaCoO₃/g-C₃N₄ heterojunction: Construction and photocatalytic degradation properties. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 480-490. doi: 10.11862/CJIC.20240259
19. [19]
  Yadan Luo , Hao Zheng , Xin Li , Fengmin Li , Hua Tang , Xilin She . Modulating reactive oxygen species in O, S co-doped C₃N₄ to enhance photocatalytic degradation of microplastics. Acta Physico-Chimica Sinica, 2025, 41(6): 100052-0. doi: 10.1016/j.actphy.2025.100052
20. [20]
  Shijie Li , Ke Rong , Xiaoqin Wang , Chuqi Shen , Fang Yang , Qinghong Zhang . Design of Carbon Quantum Dots/CdS/Ta₃N₅ S-scheme Heterojunction Nanofibers for Efficient Photocatalytic Antibiotic Removal. Acta Physico-Chimica Sinica, 2024, 40(12): 2403005-0. doi: 10.3866/PKU.WHXB202403005

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(1928)
HTML views(231)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation of WO3-TiO2/SBA-15 catalyst and its photocatalytic performance in oxidative desulfurization

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation of WO₃-TiO₂/SBA-15 catalyst and its photocatalytic performance in oxidative desulfurization